Photochemie von Alkyl‐Übergangsmetallkomplexen
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Abstract
References (223)
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1969 • 77 citations
Photochemical investigations of di-η5-cyclopentadienyldimethyltitanium and deuterated analogs
1977 • 77 citations
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1977 • 77 citations
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1967 • 69 citations
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1979 • 69 citations
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1976 • 69 citations
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1974 • 68 citations
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1977 • 68 citations
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1964 • 66 citations
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1976 • 66 citations
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1976 • 65 citations
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1965 • 61 citations
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1966 • 59 citations
The use of chiral iron complexes in mechanistic studies: The decarbonylation of carbonyl(pentahapto-cyclopentadienyl)triphenylphosphineiron acyls
1974 • 57 citations
The thermal decomposition of dicyclopentadienyldimethyltitanium(IV)
1976 • 57 citations
The transition metal to carbon sigma bond
1972 • 56 citations
Photochemistry of metal carbonyl alkyls. Study of thermal .beta.-hydrogen transfer in photogenerated, 16-valence-electron alkyldicarbonylcyclopentadienylmolybdenum and -tungsten complexes
1982 • 56 citations
Photolysis of dialkyl metallocenes of the titanium group; an ESR study
1977 • 56 citations
Matrix isolation studies of organometallic intermediates
1984 • 56 citations
Stereochemical studies at pseudotetrahedral, chiral metal of the decarbonylation, carbonylation, and sulfur dioxide insertion reactions
1974 • 55 citations
The enthalpies of formation of CH3Mn(CO)5 and of CH3Re(CO)5, and the strengths of the CH3Mn and CH3Re bonds
1974 • 53 citations
Photochemical substitution reactions of some alkylcobaloximes by hydroperoxides and the crystal structure of cumyl peroxide (pyridine) cobaloxime
1976 • 53 citations
Photochemical reactions of metallocyclobutane derivatives of tungsten: evidence for the mechanism of olefin metathesis
1976 • 51 citations
Synthesis and cyclization reactions of alkynyl (.eta.5-cyclopentadienyltricarbonylmolybdenum and -tungsten) complexes
1979 • 51 citations
The photochemistry of organocobalt complexes containing tetraaza macrocyclic ligands. Cobalt-methyl homolysis and the nature of the cobalt-carbon bond
1978 • 51 citations
Reactions between methyl-, acetyl-, and phenyl-pentacarbonylmanganese and acetylenes
1970 • 51 citations
Studies on substitution, insertion and decarbonylation reactions of some cyclopentadienyliron complexes with phosphorus donor ligands
1971 • 50 citations
The crystal structure of dicarbonyldicyclopentadienyltitanium(II), (η5-C5H5)2Ti(CO)2
1977 • 50 citations
The formation and photolysis of bis(fluorenyl)dimethylzirconium
1976 • 50 citations
Cyclopentadienylruthenium phosphine complexes. Part II. Reactions between hydridobis(triphenylphosphine)(π-cyclopentadienyl)ruthenium and acetylenes
1974 • 49 citations
A study of the stereochemistry at iron of electrophilic cleavage of the iron-carbon .sigma. bond in methyl(.eta.5-1-methyl-3-phenylcyclopentadienyl)carbonyl(triphenylphosphine)iron(II)
1979 • 49 citations
Reversible carbonylation of dialkylbiscyclopentadienylzirconium(<scp>IV</scp>): synthesis and structure of π-acyl derivatives of zirconium and X-ray structure of biscyclopentadienyl(π-acetyl)methylzirconium
1976 • 48 citations
Photochemistry of alkyldicarbonyl(.eta.5-cyclopentadienyl)iron and -ruthenium. Ligand substitution and alkene elimination via photogenerated sixteen-valence-electron intermediates
1982 • 47 citations
Cyclopentadienyl-carbonyl-acetylen-methyl-wolfram, eine ausgangsverbindung für neue wolfram—acetylen-komplexe
1977 • 46 citations
Reversible addition of carbon monoxide to tetracarbonylbis(.eta.5-pentamethylcyclopentadienyl)dimolybdenum(I)
1975 • 45 citations
Reactions of low-valent metal complexes with fluorocarbons. Part XXII. Tertiary phosphine gold complexes
1972 • 45 citations
Metall‐π‐Komplexe des Rutheniums und Osmiums mit 6‐und 8‐gliedrigen cyclischen Oligoolefinen
1963 • 45 citations
Synthesis and x-ray crystallographic structural determination of the acetylene complex (η5−C5H5)2W2(CO)4(C2H2)
1978 • 44 citations
Attempts to prepare alkylidene zirconium complexes by α-hydrogen atom abstraction
1981 • 43 citations
Photochemical decomposition and carbon monoxide insertion in organometallic cobalt chelates
1968 • 43 citations
Aspects of Organo-Transition-Metal Photochemistry and their Biological Implications
1976 • 43 citations
Evidence for reversible α-elimination of hydrogen from a tungsten–methyl compound giving a tungsten–methylene–hydride derivative
1974 • 42 citations
Etude de quelques facteurs influencant l'insertion photoinduite d'oxygene dans la liaison cobalt—carbone des alcoylcobaloximes
1974 • 41 citations
Notizen: Über Aromatenkomplexe von Metallen LXVIII1 Cyclohexadien-1.3-Benzol-Eisen (0)
1962 • 41 citations
Photolysis in aprotic solvents of some alkylcobalt(III) complexes; an ESR and spin-trapping technique study
1978 • 41 citations
Silylmethyl and related complexes
1973 • 40 citations
Multiple metal-carbon bonds. 30. Rhenium(VII) neopentylidene and neopentylidyne complexes
1982 • 40 citations
Automated thermal degradation studies on solid σ-organotransition metal complexes: Dimethyl-titanocene, -zirconocene and -hafnocene
1976 • 40 citations
Some phosphine-substituted carbonyl-π-cyclopentadienyl complexes of molybdenum and tungsten
1968 • 40 citations
The photo-catalysed reaction of sulfur with dialkyl-titanocenes
1976 • 39 citations
Carbonylvanadium, -mangan- und -molybdänkomplexe mit den Liganden o-C6H4EPh2(E'Ph2) (E,E' = P, As, Sb, Bi) und cis-Ph2PCH=CHPPh2 / Carbonylvanadium, -manganese and -molybdenum Complexes of the Ligandso-C6H4EPh2(E'Ph2) (E,E' = P, As, Sb, Bi) und cis-Ph2PCH=CHPPh2
1981 • 39 citations
Carbon monoxide insertion into the iron-carbon .sigma.-bond in optically active CpFe(CO)(L)R. Preparations and optical assay
1983 • 39 citations
The synthesis and structure of [CO(η-C5Me5)Et{P(p-tolyl)3}] cation: a model for the β-elimination transition state
1984 • 38 citations
Unexpectedly complex structure and dynamic behavior of bis [(η5-cyclopentadienyl)dicarbonyl molybdenum ]-μ-pent-3-yne (MoMo)
1976 • 37 citations
Metal perfluoro-alkane- and -arene-thiolates. Part IV. The reactions of some manganese, iron, and cobalt derivatives with alkynes
1975 • 37 citations
Photogeneration of intermediates involved in catalytic cycles. .beta.-Hydride elimination from the 16-electron alkyl species generated by irradiation of tricarbonyl(.eta.5-cyclopentadienyl)(n-pentyl)tungsten(II)
1980 • 37 citations
New Types of Organosulfur Derivatives of Metal Carbonyls
1964 • 37 citations
The crystal structure of 1,1-bis(η5-cyclopentadienyl)-2,3,4,5-tetraphenylzirconole
1981 • 37 citations
Photochemische reaktionen an cyclopentadienyl tricarbonyl-methyl-verbindungen des chroms und wolframs
1977 • 35 citations
Photochemistry of (.eta.5-C5H5)W(CO)3CH3 in solution. Mechanism of (.eta.5-C5H5)2W2(CO)6 formation
1981 • 34 citations
Hydrogen exchange during the thermal decomposition of dicyclopentadienyldimethyltitanium(IV)
1979 • 33 citations
Metal-metal multiple bonds. 14. Synthesis, stereochemistry and hydrogenation of protonated alkyne adducts of Cp2Mo2(CO)4
1983 • 33 citations
Photolysis of alkylcobaloximes, methyl-salen, cobalamines and coenzyme B12 in protic solvents: an ESR and spin-trapping technique study
1979 • 33 citations
Photolysis of di-η5-cyclopentadienyldimethyltitanium(IV): application of free-radical polymerization in a study of the mechanism
1978 • 32 citations
Photochemistry of methyl- and n1-benzyl-n5-cyclopentadienyltricarbonyltungstein(II)
1978 • 32 citations
Photolysereaktionen mit Komplexen des Typs CpFe(CO)2R (R = Me, Et, Ph)+ / Photolytic Reactions with Complexes of the Type CpFe(CO)2R (R = Me, Et, Ph)+
1979 • 32 citations
Homolytic photochemical processes in an organo-cobalt complex containing saturated ligands and the nature of the cobalt-carbon bond
1977 • 32 citations
Alkylruthenium(II)‐Verbindungen und ihre β‐H‐Eliminierung zu (η 2 ‐Alken)hydridoruthenium‐Komplexen
1983 • 31 citations
Photogeneration of reactive titanium and zirconium species: a CIDNP study
1981 • 30 citations
The molecular structure and dynamic NMR spectrum of bis[(η5-cyclopentadienyl)dicarbonylmolybdenum]-μ-ethyne(MoMo)
1977 • 30 citations
Stabilities of nickel–alkyl compounds
1970 • 29 citations
Notizen: Optisch aktive Übergangsmetall-Komplexe, XXIV.
1974 • 29 citations
NMR‐Untersuchungen an den η 5 ‐Cyclopentadienyl‐ und 1975 5 ‐Indenylkomplexen C 5 H 5 W(CO) 2 (C 2 H 4 )CH 3 und C 9 H 7 W(CO) 2 (C 2 H 4 )CH 3 Metallacyclopropane oder Ethylen‐π‐Komplexe?
1981 • 28 citations
Photodecomposition of platinum and palladium alkyls: A cidnp study
1977 • 28 citations
Synthese von linearen und verzweigten Cellotetraosen
1982 • 28 citations
Photolysis of η-cyclopentadienylmethyltricarbonyl derivatives of chromium, molybdenum and tungsten: formation of paramagnetic alkyl—metal species by photochemically-induced electron and methyl transfer
1979 • 27 citations
The Reaction of Tolan with Methyl-cyclopentadienyldicarbonyls of Iron and Molybdenum
1963 • 27 citations
Bis‐(1,5‐cyclooctadiene)platinum(0)
1967 • 27 citations
Migration of hydrogen atoms from cyclopentadienyl rings to metal and hydrogen exchange reactions upon thermal decomposition of dicyclopentadienyl compounds of titanium and zirconium
1979 • 27 citations
Low-temperature photochemistry of (.eta.5-C5R5)W(CO)3CH2SiMe2H: loss of carbon monoxide followed by .beta.-hydrogen transfer
1983 • 26 citations
Light-induced anaerobic CoIII–C homolysis of aqueous vitamin B12coenzyme or of ethylcobalamin; spin-trapping of the 5′-deoxyadenosyl or Et radical
1975 • 26 citations
Trimethylphosphan-derivate von cyclopentadienyl- und indenyl-metall-tricarbonyl-methyl-komplexen des typs CpM(CO)3CH3 und IndM(CO)3CH3 (M Cr, Mo, W)
1978 • 26 citations
Photo-induced homolysis of alkyltricyclopentadienyluranium(IV) complexes: an example of a successful UIV → UIII reduction
1980 • 26 citations
Novel Tungsten‐Alkyl and Tungsten‐Acyl Complexes with Acetylene as Four‐Electron Ligand
1982 • 26 citations
The Photochemically-Induced Degradation of (η5-C5H5)M(CO)3CH3 Complexes (M = Cr, Mo, W)
1977 • 25 citations
NMR study of the photochemical reaction of (η5-C5H5)Fe(CO)2Me with P, As, Sb, S and N donor ligands
1977 • 25 citations
Photochemistry of solution and surface-confined alkyl- and benzyltricarbonylcyclopentadienyltungsten complexes
1982 • 25 citations
Photoinduzierte und thermische reaktionen der übergangsmetallethylverbindungen CpM(CO)3Et (Cp = η5-cyclopentadienyl; Et = ethyl; M = Mo, W)
1981 • 25 citations
Die photoinduzierte Carbonylierung von Di(π-cyclopentadienyl)-dimethyl-titan und Di(π-indenyl)-dimethyl-titan / The Photo-induced Carbonylation of Di(π-cyclopentadienyl)-dimethyl-titanium and Di(π-indenyl)-dimethyl-titanium
1975 • 25 citations
Reaction of tetrakis(trifluoromethyl)allene with carbonylate anions. X-ray study of three novel fluoroolefinic complexes
1976 • 25 citations
Insertion of acetylenes into carbon–titanium σ-bonds
1977 • 24 citations
Darstellung und Eigenschaften von metallocyclischen 3‐Oxo‐1‐alkenyl‐Komplexen des Molybdäns und Wolframs
1977 • 24 citations
Tetraneopentyltitanium as a polymerization catalyst
1981 • 24 citations
Metalation of bis(cyclopentadienyl)metal hydrides by n-butyllithium in the presense of pentamethyldiethylenetriamine. Synthesis of bis(cyclopentadienyl)rhenium alkyls and the mixed metal complexes: (.eta.5-C5H5)2M(.mu.-CO)2Re(CO)(.eta.5-C5H5) (M = molybdenum, tungsten)
1979 • 24 citations
The photolysis of η5-cyclopentadienyltrimethylplatinum(IV)
1980 • 23 citations
Bis(cycloocta-1,5-dien)platin(0)
1967 • 23 citations
Photochemically induced reductive elimination of ethane from a binuclear methylplatinum complex
1983 • 23 citations
An e.s.r. study of the photochemistry of zirconocene(IV) alkyls and chlorides
1983 • 23 citations
Photo-degradation studies on Di-η5-Cyclopentadienyldimethylvanadium, Di-η5-Cyclopentadienylmethylvanadium, Di-η5-Cyclopentadienyldimethylniobium, and some deuterated analogs
1980 • 22 citations
Alkyl-, alkenyl, und hydrido-olefin-komplexe des rutheniums
1981 • 22 citations
Photochemistry of tricarbonyl(η5-cyclopentadienyl)hydrido complexes of molybdenum and tungsten and of dicarbonyl(η5-cyclopentadienyl)-(ethylene)hydridotungsten in solution and in frozen gas matrices at 12 K
1984 • 22 citations
The vitamin B12 coenzyme
1963 • 22 citations
Crystal and molecular structure of titanocene dicarbonyl, (h5-C5H5)2Ti(CO)2
1975 • 22 citations
The thermal decomposition of dibutylbis(η5-cyclopentadienyl)titanium, other dialkyl metallocenes, and di(η5-pentamethylcyclopentadienyl)titanium
1981 • 22 citations
Metal-metal bonded organometallic complexes. III. Ligand derivatives of .eta.5-cyclopentadienyltricarbonyl tungsten(I) bonded to group 4 elements
1976 • 22 citations
Preparation and thermal decomposition of some (butane-1,4-diyl)platinum(IV) complexes
1976 • 22 citations
Neue Wolfram‐Alkyl‐ und ‐Acylkomplexe mit Acetylen als Vierelektronenligand
1982 • 21 citations
PHOTOCHEMICAL STUDIES ON ORGANIC DERIVATIVES OF TITANIUM, ZIRCONIUM, AND HAFNIUM*
1977 • 21 citations
Reactions and properties of some trimethyleneplatinum(IV) complexes
1977 • 20 citations
Preparation of an Ethylene(hydrido)tungsten Complex by Photo‐Induced β‐Elimination
1982 • 20 citations
Comparative photochemistry of tricarbonyl(η5-cyclopentadienyl)methyl- and -ethyl-molybdenum and -tungsten in poly(vinyl chloride) film matrices at 12–298 K
1984 • 20 citations
Mechanism of action of coenzyme B12 in dioldehydrase and related enzymes. Synthesis and reactions of postulated organocorrin intermediates
1973 • 20 citations
Cyclopentadienyl-ruthenium and -osmium chemistry. Part 6. Reactions of alkylruthenium complexes with disubstituted acetylenes
1979 • 19 citations
Formation and characterization of a hydrido- tantalacyclopropane complex from the photo-induced β-hydride elimination of di-η5-cyclopentadienyl- ethyl(carbonyl)tantalum
1984 • 19 citations
Photolysis of the cyclopentadienyl(hydrido) Complexes C5H5M(CO)3H(M= Cr, Mo, W) in Matrices and in Solution: Characterization of[C5H5W(CO)2H]2 and[C5Me5W(CO)2H]2
1983 • 19 citations
Photolysis of methyl(triphenylphospine)gold(I)
1976 • 19 citations
Intramolekulare beweglichkeit des ethylen-liganden in den η5-cyclopentadienyl- und η5 -indenyl-komplexen C5H5W(CO)2(C2H4)CH3 und C9H7 W(CO)2(C2H4)CH3
1978 • 19 citations
Photochemically induced transmethylation in transition metal compounds using methyltitanocenes
1981 • 19 citations
The Reaction of acetylenes with bis(η5-cyclopentadienyl)dicarbonylchromium]
1978 • 18 citations
Ueber organische Verbindungen, welche Metalle enthalten
1855 • 18 citations
Infrared spectroscopic evidence for carbon monoxide dissociation and radical pathways in the photochemical reactions on (η-cyclopentadienyl)(methyl)tricarbonyl-molydenum
1981 • 18 citations
A rearrangement in the reaction of o-carboranecarboxylic acid chlorides with NaFe(CO)2C5H5-π
1971 • 18 citations
The photolysis of platinacycloalkanes in solution
1978 • 18 citations
Photochemistry of methyl- and acetyl-dicarbonyl(η-cyclopentadienyl)-iron in frozen gas matrices at 12 K. Infrared spectroscopic evidence for the formation of tricarbonyl(η-cyclopentadienyl)methyliron and acetylmonocarbonyl(η-cyclopentadienyl)iron
1981 • 18 citations
The photo-induced degradations of tetraneopentylchromium and trimesitylchromium tetrahydrofuranate: some applications to catalysis
1979 • 17 citations
Photochemische Umsetzungen von η5-Indenyl-tricarbonyl-methyl-molybdän und -wolfram, C9H7M(CO)3CH3 (M = Mo, W), mit Acetylenen / Photochemical Reactions of Indenyl-tricarbonyl-methyl-molybdenum and -tungsten, C9H7M(CO)3CH3 (M = Mo, W), with Acetylenes
1977 • 17 citations
Photochemische Addition von Acetylen an Tricarbonyl(η-cyclopentadienyl)methylmolybdän und -wolfram
1976 • 17 citations
Photolysis of isopropyltricyclopentadienyluranium(IV): homolysis rather than β-hydride elimination
1982 • 17 citations
Cycloheptatrien-(1.3.5)-eisen(0)-cycloheptadien-(1.3)
1963 • 17 citations
Photochemistry of tricarbonyl(η-cyclopentadienyl)methylmolybdenum in frozen gas matrices at 12 K. Infrared spectroscopic evidence for the formation of dicarbonyl(η-cyclopentadienyl)methylmolybdenum and dicarbonyl(η-cyclopentadienyl)(dinitrogen)methylmolybdenum
1981 • 16 citations
Thermische und Photo-induzierte Substitutionsreaktionen an der Eisen-ethyl-Verbindung CpFe(CO)2Et. Die Molekülstruktur von CpFe(PMe3)2COEt (Cp =η5-C5H5)/ Thermal and Photo-Induced Substitution Reactions of the Iron Ethyl Compound CpFe(CO)2Et. The Molecular Structure of CpFe(PMe3)2COEt (Cp = η5-C5H5)
1982 • 16 citations
The photolysis of methylplatinum(IV) compounds
1979 • 16 citations
The photochemical synthesis of (π-C5H5)Fe(COCH3)(CO)E(C6H5)3 where E is arsenic or antimony
1975 • 15 citations
Photochemical reaction of alkylpentacyanocobaltates with nitroxides. A new biophysical tool
1977 • 15 citations
Thermal decomposition reactions of alkylnickel compounds
1975 • 15 citations
Reactions of titana- and zircona-cyclopentadienes with alkynes
1983 • 15 citations
Photonitrosylation of Carbonylmetal Complexes in Chloroform and Carbon Tetrachloride Solution
1976 • 15 citations
Photochemical studies on η5-cyclopentadienyl(triphenylphosphine)nickelalkyl and -aryl compounds
1980 • 14 citations
Tieftemperatur‐Matrix‐Photolyse von C C‐ und C H‐Bindungen in Tricarbonyleisen‐Komplexen 5,5‐Dialkyl‐substituierter Cyclopentadiene
1980 • 14 citations
Thermolysis and photolysis of (η-C5Me5)Os(CO)2CH2OH: A retro Fischer-Tropsch step
1982 • 14 citations
Reactions of fluorinated ketones with ferrocenes
1974 • 14 citations
Reactions of potassium carbonyl(π-cyclopentadienyl)nickelate with butenyl and cyclopropylmethyl halides
1974 • 13 citations
Die intramolekulare Beweglichkeit von Alkinen in Wolframkomplexen des Typs C5H5W(CO)(L)R (L = Alkin; R = CH3, C6H5) / The Intramolecular Mobility of Alkynes in Tungsten Compounds of the Type C5H5W(CO)(L)R (L = Alkyne; R = CH3, C6H5)
1977 • 13 citations
Ein Ethylen(hydrido)wolfram-Komplex durch photoinduzierte β-Eliminierung
1982 • 13 citations
Thermal decomposition reaction of dicyclopentadienyl derivatives of vanadium
1976 • 12 citations
The Photochemical Addition of Acetylene to Tricarbonyl(η5‐cyclopentadienyl)methylmolybdenum and ‐tungsten
1976 • 12 citations
Photoelectron spectra of some compounds containing transition-metal–carbon σ-bond
1976 • 12 citations
Carbon monoxide insertion reactions of methyl tricarbonylcyclopentadienyl chromium
1973 • 12 citations
Photo‐Induced Reaction of Alcohols with Tricarbonyl(η5‐cyclopentadienyl)ethyltungsten
1982 • 11 citations
The photodecomposition of platinacycloalkanes in solution
1980 • 10 citations
Photolyse der Cyclopentadienyl(hydrido)komplexe C5H5M(CO)3H (M Cr, Mo, W) in Matrix und in Lösung; Charakterisierung von [C5H5W(CO)2H]2 und [C5Me5W(CO)2H]2
1983 • 9 citations
Photochemical Redox Reaction of Aqueous Benzylpentacyanocobaltate(III)
1976 • 9 citations
Carbenoid intermediates from the photolysis of haloalkylcobalamins
1969 • 8 citations
Matrix isolation evidence for reversible α-elimination of hydrogen from a chromium methyl compound to give a chromium methylene hydride species
1983 • 8 citations
Complexes of trivalent phosphorus derivatives
1969 • 8 citations
Synthese von linearen und verzweigten Cellotetraosen
1982 • 8 citations
Matrix isolation studies of hydroformylation intermediates. Infrared spectroscopic evidence for stepwise substitution of ethylene into [5-cyclopentadienyl tricarbonyl(hydrido)-molybdenum and -tungsten complexes followed by insertion into the metal-hydrogen bond
1983 • 7 citations
Photo-degradation studies on di-η5-cyclopentadienyl-dimethyltantalum and some deuterated analogs
1982 • 7 citations
Novel heterolytic cleavage of the carbon-cobalt bond observed for (1,19-dimethyl-AD-bisdehydrocorrinato) cobalt complexes in aqueous media
1979 • 7 citations
Interaction of hexamethyltungsten(VI) with trimethylphosphine; X-ray crystal structure of dimethyltetrakistrimethylphosphinetungsten(II)
1979 • 7 citations
Thermal Decomposition of bis(cyclopentadienyl)hafnium compounds and their deuterated analogues
1982 • 6 citations
Lability of tertiary phosphine groups of tertiary phosphidomethyl derivatives of tungsten
1979 • 4 citations
Photoinduzierte Reaktion von Alkoholen mit Tricarbonyl(η5-cyclopentadienyl)ethylwolfram
2006 • 3 citations