Carbonylation of zirconocene complexes

Structure and chemistry of bis(cyclopentadienyl)-MLn complexes

1976 • 1,083 citations

The PMO Theory of Organic Chemistry

1975 • 526 citations

Nachweis gehinderter Rotationen und Inversionen durch NMR‐Spektroskopie

1970 • 436 citations

Reactions of diazomethane on transition-metal surfaces and their relationship to the mechanism of the Fischer-Tropsch reaction

1980 • 411 citations

Mechanistic features of catalytic carbon monoxide hydrogenation reactions

1979 • 363 citations

Mechanisms of carbon monoxide reduction with zirconium hydrides

1980 • 302 citations

Thermochemical studies of organo-transition metal carbonyls and related compounds

2006 • 273 citations

Organometallic migration reactions

1978 • 255 citations

Tetracyanoethylene and enol ethers. A model for 2 + 2 cycloadditions via zwitterionic intermediates

1977 • 218 citations

Relationship between olefinic .pi. complexes and three-membered rings

1979 • 214 citations

Carbon dioxide activation. Deoxygenation and disproportionation of carbon dioxide promoted by bis(cyclopentadienyl)titanium and -zirconium derivatives. A novel bonding mode of the carbonato and a trimer of the zirconyl unit

1979 • 192 citations

Primary and secondary orbital effects in dyotropic rearrangements

1973 • 156 citations

Hydrozirconierung: Organische Synthesen mit einem neuen Übergangsmetall‐Reagens

1976 • 155 citations

Mechanism of thermal decomposition of dibutylbis(triphenylphosphine)platinum(II)

1972 • 154 citations

Rational mechanism for homogeneous hydrogenation of carbon monoxide to alcohols, polyols, and esters

1981 • 140 citations

Stoichiometric hydrogen reduction of carbon monoxide to methanol promoted by derivatives of bis(pentamethylcyclopentadienyl)zirconium

1976 • 131 citations

Metal clusters in catalysis. 10. A new Fischer-Tropsch synthesis

1977 • 125 citations

Organometallic models for possible Fischer-Tropsch intermediates. Synthesis, structure, and reactions of a formaldehyde complex of osmium

1979 • 124 citations

Molecular Orbitals for the Protonated Sandwich Compounds.

1961 • 123 citations

Hydrogenation of carbon monoxide to methanol and ethylene glycol by homogeneous ruthenium catalysts

1980 • 119 citations

Ethylene glycol from synthesis gas via ruthenium melt catalysis

1981 • 114 citations

Carbon monoxide activation by organoactinides. Migratory carbon monoxide insertion into metal-hydrogen bonds to produce mononuclear formyls

1981 • 113 citations

Reduction of coordinated carbon monoxide to "zirconoxy" carbenes with permethylzirconocene dihydride

1979 • 112 citations

Shape-selective Fischer-Tropsch synthesis catalyzed by zeolite-entrapped cobalt clusters

1980 • 111 citations

Equilibrium between metallaindans and aryne olefin-metal complexes

1979 • 110 citations

Die Fischer‐Tropsch‐Synthese: Molekulargewichtsverteilung der Primärprodukte und Reaktionsmechanismus

1976 • 109 citations

Carbon monoxide activation by f-element organometallics. An unusually distorted, carbenelike dihaptoacyl and CO tetramerization

1980 • 107 citations

Homogeneous hydrogenation of carbon monoxide

1977 • 104 citations

Metal clusters in catalysis. IV. Catalytic hydrogen reduction of carbon monoxide to alkanes

1976 • 93 citations

Migratory insertion reactions of carbenes. Kinetics and mechanism of migratory insertion reactions of zirconoxy carbene complexes of niobocene hydride and alkyls

1981 • 93 citations

New syntheses and molecular structures of the decamethylmetallocene dicarbonyls (.eta.5-C5Me5)2M(CO)2 (M = titanium, zirconium, hafnium)

1981 • 85 citations

Fischer-Tropsch intermediates: tris[(.eta.2-formaldehyde)zirconocene] from the carbonylation of a zirconium hydride

1983 • 76 citations

Hydrogenation of alkylzirconium(IV) complexes: heterolytic activation of hydrogen by a homogeneous metal alkyl

1982 • 76 citations

Extended Hueckel calculations related to the chemistry of titanocene

1970 • 71 citations

Silylmethyl and related complexes. 5. Metallocene bis(trimethylsilyl)methyls and benzhydryls of early transition metals [M(.eta.5-C5H5)2R](M = T or V) and [M(.eta.5-C5H5)2(X)R](M = Z or H and X = C or R), and the crystal and molecular structures of [M(.eta.5-C5H5)2(CHPh2)2](M = Z or H)

1977 • 69 citations

Electrophile-induced disproportionation of the neutral formyl (.eta.-C5H5)Re(PPh3)(NO)(CHO). Generation of cationic rhenium carbenes of the formula [(.eta.-C5H5)Re(PPh3)(NO)(CHX)]+ (X = hydrogen, methoxy, hydroxy)

1979 • 67 citations

Mechanisms of dihydrogen activation by zirconocene alkyl and hydride derivatives

1979 • 67 citations

Low-temperature infrared study of d0 carbonyl complexes

1980 • 61 citations

Reaction of carbon monoxide with (.eta.5-pentamethylcyclopentadienyl)tetramethyltantalum. Intramolecular reductive coupling of carbon monoxide via an ".eta.2-acetone" intermediate

1979 • 60 citations

Extrem verzerrte Bindungswinkel bei Organozirconium‐Verbindungen, die gegen Ethylen aktiv sind

1976 • 60 citations

Stoicheiometric reduction of CO and CO₂to methanol: evidence for carbon monoxide insertion into zirconium–hydrogen bond

1978 • 56 citations

Hydrogenation of d0 complexes: zirconium(IV) alkyl hydrides

1978 • 55 citations

Transition-metal-mediated hydrogenation of carbon monoxide to olefins: intermediacy of coordinated carbenes

1981 • 54 citations

The crystal and molecular structure of dimethyl-π-cyclopentadienyl(methylcyclopentadiene)rhenium

1967 • 52 citations

Bildung und umlagerung stereoisomerer acetylkomplexe bei der carbonylierung von bis(η5-cyclopentadienyl)dimethylzirconium

1980 • 50 citations

Zur Carbonylierung von Zirconocenhydrid‐Komplexen

1982 • 50 citations

The role of fluorocarbons in oxidative-addition and -elimination reactions

1972 • 48 citations

Reversible carbonylation of dialkylbiscyclopentadienylzirconium(<scp>IV</scp>): synthesis and structure of π-acyl derivatives of zirconium and X-ray structure of biscyclopentadienyl(π-acetyl)methylzirconium

1976 • 48 citations

Alane reduction of coordinated carbon monoxide: selective ethene production

1979 • 47 citations

Crystal and molecular structure of tetrabenzylzirconium at –40 °C

1971 • 46 citations

Polymer-supported .eta.5-cyclopentadienylcobalt. An immobilized "homogeneous" Fischer-Tropsch catalyst

1979 • 46 citations

Die Bildung stereoisomerer (η2-Aroyl)arylbis(η5-cyclopentadienyl)zirconium(IV)-Verbindungen

1978 • 46 citations

Reduction of carbon monoxide to linear alcohols by aluminum hydrides and zirconium complex catalysts at room temperature

1977 • 45 citations

Photoelectron studies of some bent bis(η-cyclopentadienyl)metal complexes. Part I. Some eighteen-electron systems with hydride, alkyl, olefin, allyl, and carbonyl ligands

1975 • 44 citations

Bis(chlorocyclopentadienylzirconium)oxide

1974 • 43 citations

Disproportionation of a neutral metal-formyl complex and synthesis of a stable hydroxymethyl-metal compound

1979 • 43 citations

Struktur und reaktivität eines formaldehydeisen-komplexes

1981 • 40 citations

Hydrido complexes of zirconium II. Reactions of dicyclopentadienylzirconium dihydride with carboxylic acids

1970 • 39 citations

Approaches to homogenous reduction of carbon monoxide. 2. Reactions of bis(.eta.5-cyclopentadienyl)trihydridoniobium with metal carbonyls: selective reduction of carbon monoxide to ethane

1980 • 38 citations

Stable acyls and iminoacyls of zirconium(IV), [Zr(η-C5H5)2{C(:X)R}R′] [X = O or NTol-p; R = Me3CCH2, Me3SiCH2, or (Me3Si)2CH; R′ = Cl or alkyl]

1979 • 38 citations

Die bildung von CC-bindungen bei der carbonylierung von 1,1-bis(η5-cyclopentadienyl)zirconaindan

1980 • 36 citations

Electron paramagnetic resonance spectra of the bis-(π-cyclopentadienyl)vanadium(<scp>IV</scp>) and bis-(π-cyclopentadienyl)niobium(<scp>IV</scp>) complexes (π-C₅H₅)₂VX₂and (π-C₅H₅)₂NbX₂

1973 • 34 citations

Dyotrope Umlagerungen zweikerniger μ‐Aldehyd‐zirconocen‐Komplexe

1982 • 33 citations

Reversal of the benzophenone reactivity upon η5-complexation to bis (η-cyclopentadienyl) zirconium

1980 • 32 citations

The structure of bis(cyclooctatetraene)(tetrahydrofuran)zirconium

1972 • 30 citations

Heterobimetallic hydrogen transfer in the reduction of metal acyl complexes

1980 • 29 citations

Formation of methane and ethane by reduction of carbon monoxide coordinated through both carbon and oxygen on Mg[CpFe(CO)2]2.4THF

1980 • 25 citations

Photochemistry of complex ions. XIII. The cis-dichlorobis(ethylenediamine)cobalt(III) and cis-chloroaquobis(ethylenediamine)cobalt(III) complexes

1974 • 22 citations

Electron spin resonance studies of Ziegler-type catalysts. Part I. Characterisation of a vanadium–aluminium complex obtained on mixing dichlorobis(η-cyclopentadienyl)vanadium with ethylaluminium dichloride

1974 • 21 citations

New π-carboxo complexes of nickel(0)

1977 • 21 citations

Umlagerungen in der Organobor-Chemie

1973 • 20 citations

Synthese und Röntgen‐Strukturanalyse eines Mo‐Komplexes mit η²‐koordiniertem Benzaldehyd; Umwandlung eines CO‐Liganden durch doppelte α‐Addition

1979 • 16 citations

Evidence for anchimeric assistance by the Cp2ZrCl-group in the homolytic cleavage of an OCH3 bond

1981 • 12 citations

Dyotrope Umlagerungen, VIII: Mechanismus der Umlagerung von (Silyl)methyl‐silyl‐äthern

1976 • 12 citations

Dyotrope Umlagerungen, XIII. Fluoridionen‐katalysierte Umlagerungen von Allyl‐ und Benzyl‐(silylmethyl)‐ethern

1977 • 12 citations

Anchimer beschleunigte Homolysen, III: Mechanismus der thermischen Umlagerung von Alkyl‐(silylmethyl)‐ethern

1978 • 11 citations

The x-ray structure of the h5-cyclopentadienyltris(tropolonato)zirconium(IV) 1:1 dichloromethane solvate

1976 • 9 citations

The photochemistry of some cis-dihalo rhodium(III) complexes

1976 • 8 citations

An Introduction to Physical Organic Chemistry. Von E. M. Kosower. J. Wiley and Sons., Inc., New York‐London‐Sydney 1968. 1. Aufl., XVI, 503 S., zahlr. Abb. und Tab., 115s

1970 • 4 citations

MO‐Theorie metallorganischer Verbindungen

1982 • 2 citations