Matrix isolation studies of hydroformylation intermediates. Infrared spectroscopic evidence for stepwise substitution of ethylene into [5-cyclopentadienyl tricarbonyl(hydrido)-molybdenum and -tungsten complexes followed by insertion into the metal-hydrogen bond

Synthesis and characterization of the pentacarbonylmanganese(0) radical, Mn(CO)5, in low-temperature matrixes

1981 • 84 citations

Transient species of importance in the stoichiometric hydroformylation reaction I. Evidence for HCo(CO)3 by matrix isolation

1978 • 44 citations

Photogeneration of intermediates involved in catalytic cycles. .beta.-Hydride elimination from the 16-electron alkyl species generated by irradiation of tricarbonyl(.eta.5-cyclopentadienyl)(n-pentyl)tungsten(II)

1980 • 37 citations

Photolysis of matrix-isolated hydridotetracarbonylcobalt(I). Evidence for metal-hydrogen bond homolysis

1980 • 35 citations

Photolysis of matrix-isolated hydridotetracarbonylcobalt(I). Comparison of the probabilities of carbonyl loss with hydrogen atom loss

1982 • 34 citations

Evidence for the production of hydridotetracarbonylmanganese, HMn(CO)₄, on Reversible photolysis of hydridopentacarbonylmanganese, HMn(CO)₅, in argon at 15°<scp>K</scp>

1969 • 29 citations

Photochemistry of methyl- and acetyl-dicarbonyl(η-cyclopentadienyl)-iron in frozen gas matrices at 12 K. Infrared spectroscopic evidence for the formation of tricarbonyl(η-cyclopentadienyl)methyliron and acetylmonocarbonyl(η-cyclopentadienyl)iron

1981 • 18 citations

Photochemistry of tricarbonyl(η-cyclopentadienyl)methylmolybdenum in frozen gas matrices at 12 K. Infrared spectroscopic evidence for the formation of dicarbonyl(η-cyclopentadienyl)methylmolybdenum and dicarbonyl(η-cyclopentadienyl)(dinitrogen)methylmolybdenum

1981 • 16 citations

Infrared evidence for the formation of acetyl- and methyltetracarbonylmanganese on photolysis of acetyl- and methylpentacarbonylmanganese in matrices at 15° K

1970 • 12 citations