New Developments in the Field of Vitamin B12: Reactions of the Cobalt Atom in Corrins and in Vitamin B12 Model Compounds
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Abstract
References (65)
Nucleophilic reactivity constants toward methyl iodide and trans-dichlorodi(pyridine)platinum(II)
1968 • 447 citations
Inorganic chemistry of vitamin B12.
1972 • 395 citations
Organocobalt chemistry of vitamin B12 model compounds (cobaloximes)
1968 • 376 citations
Structure of the 5,6-Dimethylbenzimidazolylcobamide Coenzyme
1961 • 313 citations
Reactions of cobalt(I) supernucleophiles. The alkylation of vitamin B12s, cobaloximes(I), and related compounds
1969 • 298 citations
Alkylcobaloximes and Their Relation to Alkylcobalamins
1966 • 252 citations
Coenzym B12‐Modelle
1964 • 235 citations
Photochemical and thermal cobalt-carbon bond cleavage in alkylcobalamins and related organometallic compounds. Comparative study
1968 • 175 citations
Alkylcobalamins and alkylcobaloximes. Electronic structure, spectra, and mechanism of photodealkylation
1970 • 174 citations
The nucleophilicity of vitamin B(sub 12s)
1968 • 169 citations
Cobalamin Model Compounds. Preparation and Reactions of Substituted Alkyl- and Alkenylcobaloximes and Biochemical Implications
1967 • 148 citations
Hydridocobaloximes
1971 • 105 citations
Organometallic derivatives of cobalt chelates of bis(acetylacetone) ethylendiamine
1966 • 104 citations
Kinetics of the Reactions of Pentacyanocobaltate(II) with Organic Halides
1965 • 100 citations
Die Konstitution von Vitamin B12s
1965 • 99 citations
Organometallic derivatives of cobalt(III) chelates of bis(salicylaldehyde) ethylenediimine
1967 • 98 citations
Über Cobaloxime(II) und deren Beziehung zum Vitamin B12r
1966 • 91 citations
Biological cycles for elements in the environment
1975 • 86 citations
Superoxocobalamin, the first intermediate in the autoxidation of vitamin B12
1969 • 84 citations
The molecular and electronic structure of vitamin B12(sub r), cobaloximes(II), and related compounds
1968 • 80 citations
Preparation of organocyanocobaltate(III) complexes
1965 • 76 citations
Insertions photochimique et spontanée d'oxygène dans les liaisons cobaltcarbone des alcoylcobaloximes
1972 • 62 citations
Stereochemistry of the alkylation of cobalt(I)
1970 • 59 citations
Cobalt-carbon bond cleavage in substituted alkylcobalamins and alkylcobaloximes. Evidence for d-orbital participation and olefin.pi. complexes of cobalt(I) nucleophiles
1970 • 59 citations
Reaction of coordinated purines. Facile, high yield synthetic route to N(7)-alkylated xanthines and hypoxanthines. Structure of [bis(dimethylglyoximato)(xanthinato)(tri-n-butylphosphine)cobalt(III)] and the trans influence in cobalt(III) chemistry
1975 • 58 citations
Hydridocobalamin and a new synthesis of organocobalt derivatives of vitamin B12
1971 • 57 citations
Mise en évidence de l'hydrure des cobaloximes(I)
1970 • 55 citations
On cobaloximes with cobalt-sulfur bonds and some model studies related to cobamide-dependent methyl-group-transfer reactions
1967 • 54 citations
Kinetics of the reactions of bis(glyoximato)cobalt(II) complexes with organic halides
1969 • 53 citations
Preparation and Reactions of Organocobalt (III) Complexes
1973 • 51 citations
Bisdimethylglyoximatorhodium derivatives. Analogs of cobaloximes
1970 • 48 citations
Stereochemistry and mechanism of the photochemical and thermal insertion of oxygen into the carbon-cobalt bond of alkyl(pyridine)cobaloximes
1975 • 43 citations
Reductive dealkylation of alkylcobaloximes, alkylcobalamins, and related compounds: Simulation of corrin dependent reductase and methyl group transfer reactions
1973 • 43 citations
Direct method for cobalt-carbon bond formation in cobalt(III)-containing cobalamins and cobaloximes. Further support for cobalt(III) .pi. complexes in coenzyme B12 dependent rearrangements
1973 • 41 citations
Diol dehydrase model studies. Acid catalyzed rearrangement of .beta.-hydroxyisopropylcobaloxime
1974 • 37 citations
Organometallderivate des Bis(dimethylglyoximato)‐kobalts
1969 • 36 citations
Neuere chemische und biochemische Entwicklungen auf dem Vitamin‐B12‐Gebiet
1963 • 35 citations
New Chemical and Biochemical Developments in the Vitamin B12 Field
1964 • 34 citations
Theoretical analysis of corrin optical spectra
1970 • 34 citations
Electron paramagnetic resonance spectra of some vitamin B12 derivatives
1969 • 33 citations
Reactions of the Carbon-Cobalt Bond of Alkylcobalamins
1966 • 31 citations
Ligand-exchange kinetics in methylatobis(dimethylglyoximato)cobalt(III) complexes
1969 • 29 citations
Factors affecting the anaerobic photolysis of the cobalt-carbon bond of cobalt-methylcobalamin
1966 • 29 citations
Novel Degradation Reactions of Halomethyl Derivatives of Bis(diacetyldioximato)cobalt
1971 • 28 citations
Fragmentierungen durch supernucleophile—I
1975 • 27 citations
The reaction of vitamin B12a and of cobaloximes with carbon monoxide. Evidence for self-reduction of vitamin B12a in neutral solution
1968 • 26 citations
Synthesis of Methyl Groups catalysed by Vitamin B12r in vitro
1967 • 22 citations
α-(5,6-Dimethylbenzimidazolyl)rhodibamide and Rhodibinamide, the Rhodium Analogues of Vitamin B12 and Cobinamide
1973 • 22 citations
Elektronenstruktur, Lichtabsorption und Reaktionen von Vitamin B12 und seinen Derivaten
1966 • 21 citations
New σ-bonded bisalkyl and alkyl-aryl cobalt complexes of bis(diacetylmonoxime-imino)propane 1.3
1969 • 21 citations
Reactions of alkylcobalamins and of related complexes with mercaptide ions: S-alkylation by nucleophilic attack
1974 • 20 citations
Mechanism of action of coenzyme B12 in dioldehydrase and related enzymes. Synthesis and reactions of postulated organocorrin intermediates
1973 • 20 citations
Synthesis and reactions of formylmethylcobalamin and of related compounds
1975 • 19 citations
Methylcobalamin and methylcobalt complexes of vitamin B12 model compounds as substrates in nucleophilic displacement reactions
1974 • 18 citations
Rhodium(II)-to-rhodium(II) single bond in bis(triphenylphosphine)tetrakis(dimethylglyoximato)dirhodium
1969 • 18 citations
THE CHEMISTRY OF Co(I) DERIVATIVES OF VITAMIN B12 AND OF RELATED CHELATES
1969 • 18 citations
The reduction of vitamin B12a by carbon monoxide
1970 • 17 citations
Kinetic differentiation between Id [dissociative interchange] and D [dissociative] mechanisms for axial base-ligand exchange in alkyl(base)cobaloximes
1975 • 17 citations
Reductive CoC bond cleavage of alkylcorrins and of vitamin B12 model compounds by alkaline CO, S2O4-- and stannite
1973 • 13 citations
Cobaloxime template reactions I. The formation of N-nitrosamines
1974 • 12 citations
Formation of vitamin B12s by anaerobic photolysis of cobalt-alkylcobalamins
1966 • 12 citations
Mechanisms of Corrin Dependent Enzymatic Reactions
1974 • 9 citations
Relationship between the cobalamin-dependent methyltransferase activities in Escherichia coli B and an E. coli B (met H−) mutant
1973 • 6 citations
Neuartige Abbaureaktionen von Halogenmethyl‐Derivaten des Bis(diacetyldioximato)kobalts
1971 • 5 citations
Additions and Corrections - A New Ring System. 2,6-Dioxabicyclo[2.2.2]octane, a Highly Reactive Bicyclic Acetal.
1975 • 4 citations