Asymmetric sharpless epoxidation of divinylcarbinol. Erythro-D- and -L-4-pentenitols by hydrolysis of regioisomeric epoxy-4-pentenols

Quantitative analyses of biochemical kinetic resolutions of enantiomers

1982 • 2,569 citations

The first practical method for asymmetric epoxidation

1980 • 2,522 citations

Catalytic asymmetric epoxidation and kinetic resolution: modified procedures including in situ derivatization

1987 • 1,853 citations

Asymmetric synthesis of bicyclic intermediates of natural product chemistry

1974 • 1,187 citations

Kinetic resolution of racemic allylic alcohols by enantioselective epoxidation. A route to substances of absolute enantiomeric purity?

1981 • 766 citations

Spezifikation der molekularen Chiralität

1966 • 718 citations

Modern Synthetic Methods

1990 • 658 citations

Tetrahedron report number 203

1986 • 652 citations

Procedure for the catalytic asymmetric epoxidation of allylic alcohols in the presence of molecular sieves

1986 • 452 citations

Stereoisomerism and local chirality

1984 • 407 citations

Neuartige asymmetrische Cyclisierung zu optisch aktiven Steroid‐CD‐Teilstücken

1971 • 383 citations

Tetrahedron report number 195 (R)- and (S)-2,3-0-isopropylideneglyceraldehyde in stereoselective organic synthesis

1986 • 370 citations

Doppelte Stereodifferenzierung und eine neue Strategie zur Stereokontrolle in der Organischen Synthese

1985 • 327 citations

Asymmetric Epoxidation of Allylic Alcohols: The Sharpless Epoxidation

1986 • 313 citations

Epoxide Migrations with α,β-Epoxy Alcohols

1962 • 292 citations

Total synthesis of FK506 and an FKBP probe reagent, [C(8),C(9)-13C2]-FK506

1990 • 254 citations

Spezifikation des sterischen Verlaufs von asymmetrischen Synthesen

1982 • 227 citations

Grundlagen des CIP-Systems und Vorschläge für eine Revision

2006 • 213 citations

Stereo and regioselective openings of chiral 2,3-epoxy alcohols. Versatile routes to optically pure natural products and drugs. Unusual kinetic resolutions

1983 • 207 citations

Reactions that proceed with a combination of enantiotopic group and diastereotopic face selectivity can deliver products with very high enantiomeric excess: experimental support of a mathematical model

1987 • 205 citations

Bifunctional chiral synthons via biochemical methods. III. Optical purity enhancement in enzymic asymmetric catalysis

1984 • 195 citations

Asymmetric epoxidation of allyl alcohol: efficient routes to homochiral .beta.-adrenergic blocking agents

1986 • 179 citations

An efficient, enantioselective synthesis of the taxol side chain

1986 • 173 citations

Interpretations of enzyme reaction stereospecificity

1975 • 160 citations

Asymmetric synthesis of loganin. Stereospecific formation of (1R,2R)- and (1S,2S)-2-methyl-3-cyclopenten-1-ol and (2R)- and (2S)-2-methylcyclopentanone

1973 • 145 citations

Directed openings of 2,3-epoxy alcohols via reactions with isocyanates: synthesis of (+)-erythro-dihydrosphingosine

1985 • 136 citations

Microbial oxidation in synthesis: A six step perparation of (+)-pinitol from benzene

1987 • 134 citations

Non-enzymatic asymmetric transformations involving symmetrical bifunctional compounds

1990 • 129 citations

Pseudoasymmetrie in der organischen Chemie

1972 • 127 citations

Hydroboration. 61. Diisopinocampheylborane of high optical purity. Improved preparation and asymmetric hydroboration of representative cis-disubstituted alkenes

1982 • 125 citations

On the steric course of the addition of some organometallic reagents to (R)-2,3-isopropylidene glyceraldehyde. Synthesis of optically active α-benzyloxy aldehydes, alcohols, carboxylic acids and 1,2-diols.

1983 • 125 citations

Asymmetric synthesis of prostaglandin intermediates

1973 • 114 citations

Acyclic Stereoselective Synthesis of Carbohydrates

1984 • 113 citations

Synthesis of the brevetoxin B IJK ring system

1989 • 97 citations

Synthesis of amino sugars via isoxazolines

1985 • 95 citations

New perspectives in asymmetric induction

1985 • 89 citations

Asymmetric microbial reduction of prochiral 2,2,-disubstituted cycloalkanediones

1987 • 86 citations

Enantioselective Synthesis of <scp>D</scp>‐erythro‐Sphingosine and of Ceramide

1986 • 86 citations

Bifunctional chiral synthons via microbiological methods. 1. Optically active 2,4-dimethylglutaric acid monomethyl esters

1981 • 79 citations

Enantioselective synthesis of D-erythro-sphingosine

1983 • 76 citations

Symmetry-assisted synthesis of triepoxide stereoisomers of E,Z,E,-dodeca-2,6,10-trien-1,12-diol and their cascade reactions to 2,5-linked bistetrahydrofurans

1985 • 73 citations

Optisch aktive C₅‐Bausteine zur Synthese von natürlich vorkommenden Terpenen

1983 • 70 citations

Enantioselective synthesis of swainsonine, a trihydroxylated indolizidine alkaloid

1985 • 69 citations

Sugar epoxides

1959 • 68 citations

Asymmetrische CC-Verknüpfungen über Epoxide

1984 • 66 citations

The asymmetric epoxidation of divinyl carbinols: theory and applications

1990 • 66 citations

A new synthetic method for γ-butyrolactols by the paladium-catalyzed regioselective oxidation of 1-alken-4-ols

1988 • 66 citations

Studies in Organic Chemistry 39

1989 • 65 citations

Total synthesis of (-)-vertinolide. A general approach to chiral tetronic acids and butenolides from allylic alcohols

1983 • 64 citations

Enzyme-catalyzed enantioconvergent lactonization of .gamma.-hydroxy diesters in organic solvents

1989 • 64 citations

A Convenient Synthesis of Enantiomerically Pure (2S,3S)- or (2R,3R)-3-Hydroxyleucine

1990 • 61 citations

A Short Synthesis of (S)‐5‐Hydroxy‐2‐penten‐4‐olide from <scp>D</scp>‐Mannitol via 2,3‐O‐Isopropylidene‐<scp>D</scp>‐glyceraldehyde

1987 • 59 citations

Prostaglandin synthesis via two-component coupling. Highly efficient synthesis of chiral prostaglandin intermediates 4-alkoxy-2-alkyl-2-cyclopenten-1-one and 4-alkoxy-3-alkenyl-2-methylenecyclopentan-1-one

1988 • 58 citations

Extension of Sugar Chains through Acetylenic Intermediates. IV Derivatives of 1-pentyne-D-erythro(andD-threo)-3,4,5-triol

1968 • 58 citations

Dissymmetric Non-conjugated Chromophores. Optical Rotatory Dispersion of Bicyclo[2.2.1]hept-5-en-2-one and Bicyclo[2.2.2]oct-5-en-2-one

1962 • 56 citations

Prostereoisomerism (prochirality)

2006 • 52 citations

Enantioselective total synthesis of (+)-pumiliotoxin A

1985 • 51 citations

Enzymes in organic synthesis. 42. Investigation of the effects of the isozymal composition of pig liver esterase on its stereoselectivity in preparative-scale ester hydrolysis of asymmetric synthetic value

1988 • 49 citations

Asymmetric epoxidation of divinyl carbinol: A new approach to the synthesis of 2,6-dideoxyhexoses

1986 • 44 citations

p-Nitrobenzoate esters of epoxy alcohols: convenient synthons for water-soluble epoxy alcohols

1987 • 44 citations

Studies relating to the synthesis of the immunosuppressive agent FK-506: synthesis of the cyclohexyl moiety via a group-selective epoxidation

1989 • 43 citations

Preparation and Electrophilic Substitution of 1‐Trimethylsilylpentadienyllithium

1980 • 42 citations

Synthesis of the Oviposition‐Deterring Pheromone (ODP) in Rhagoletis cerasi L. Preliminary communication

1989 • 41 citations

A diastereospecific, non-racemic synthesis of the C.10–C.18 segment of FK-506

1988 • 39 citations

Alkylation of chiral prolinol propionamide enolates with epoxides: Complete reversal of predicted facial selectivity

1988 • 36 citations

Synthesis of Side-Chain Unsaturatedendo- andexo-Brevicomins. Representatives of Pheromone Analogs in the Dioxabicyclo[3.2.1]octane Series

1988 • 34 citations

A highly practical synthesis of chiral (E)-1-trimethylsilyl-1-alken-3,4-diols via the sharpless asymmetric epoxidation of 1,5-bis(trimethylsilyl)-1,4-pentadien-3-ol. Formal total synthesis of lipoxin b

1988 • 34 citations

Regiocontrol in the synthesis of optically active amino-4-pentenediols via epoxy-4-pentenols. Novel acyclic adenosine analogues

1989 • 33 citations

Synthesis of two pairs of enantiomeric C18-sphingosines

1989 • 32 citations

Application of kinetic, asymmetric selection to the breaking of molecular symmetry

1985 • 32 citations

Synthese optisch aktiver Olefin-Bausteine aus D-Ribonolacton: Isopropyliden-Derivate von D-erythro-Pentendi- und -triolen (cis-4-substituierte 5-Vinyldioxolane)

1987 • 30 citations

Enantio- and stereo-selective synthesis of 2,6-dideoxyhexoses from divinylcarbinol

1986 • 24 citations

Stereoselective synthesis of functionalized erythro/1,3-diols

1987 • 20 citations

Facile synthesis of the enantiomers of frontalin

1984 • 19 citations

Stereokontrollierte Totalsynthesen der Lipoxine A5 und B5

1987 • 16 citations

Cyclisierung N‐geschützter 1‐Amino‐4‐penten‐2,3‐diole zu lyxo‐konfigurierten Desoxyiminozuckern (cis‐Dihydroxypyrrolidinen); Synthese potentieller Glycosidase‐Inhibitoren

1990 • 16 citations

Divinylglykole zur Synthese von Desoxyhexosen ‐ Synthese von <scp>D</scp>‐ und <scp>L</scp>‐Chalcose

1986 • 16 citations

Use of a Grignard reagent to lengthen a triose carbon chain

1967 • 16 citations

Die Sharpless‐Epoxidierung

1989 • 13 citations

Synthesis of endo-1,3-dimethyl-2,9-dioxa-bicyclo [3.3.1.] nonane

1987 • 11 citations

229. The conversion of d-glucose into d-idose

1939 • 10 citations

Stereoselective epoxidation of divinylmethanol: A synthetic approach to the pentitols

1982 • 9 citations

Synthesis and genotoxicity of acetoxyoxirane, the epoxide of vinyl acetate

1986 • 8 citations

22. GDCh-Hauptversammlung

1989 • 5 citations