Alkylation of chiral prolinol propionamide enolates with epoxides: Complete reversal of predicted facial selectivity

.alpha.-Methoxy-.alpha.-trifluoromethylphenylacetic acid, a versatile reagent for the determination of enantiomeric composition of alcohols and amines

1969 • 2,435 citations

Structure of FK506, a novel immunosuppressant isolated from Streptomyces

1987 • 504 citations

Reactions that proceed with a combination of enantiotopic group and diastereotopic face selectivity can deliver products with very high enantiomeric excess: experimental support of a mathematical model

1987 • 205 citations

Enantioselective alkylation of chiral enolates

1980 • 172 citations

Acyclic stereoselection. 11. Double stereodifferentiation as a method for achieving superior Cram's rule selectivity in aldol condensations with chiral aldehydes

1981 • 123 citations

Asymmetric alkylation of amide anions. Product analysis by GLC using cholesteryl cinnamate, a liquid crystal phase

1980 • 73 citations

Asymmetric epoxidation of divinyl carbinol: A new approach to the synthesis of 2,6-dideoxyhexoses

1986 • 44 citations

A diastereospecific, non-racemic synthesis of the C.10–C.18 segment of FK-506

1988 • 39 citations

One pot synthesis of α-bromo and α-iodo ketones from epoxides

1981 • 25 citations

Asymmetric induction in additions to epoxides. Addition of .alpha.-anions of N,N-disubstituted carboxamides

1981 • 23 citations