The Covalent Chemistry of Higher Fullerenes: C₇₀ and Beyond

Solid C60: a new form of carbon

1990 • 7,473 citations

Theoretical studies of icosahedral C60 and some related species

1986 • 1,844 citations

Specification of Molecular Chirality

1966 • 1,774 citations

Fullerenes with metals inside

1991 • 1,262 citations

Lanthanum complexes of spheroidal carbon shells

1985 • 1,166 citations

Chemistry of the Fullerenes: The Manifestation of Strain in a Class of Continuous Aromatic Molecules

1993 • 899 citations

Cyclopropanierung von Fullerenen

1993 • 875 citations

Spezifikation der molekularen Chiralität

1966 • 718 citations

Atoms in carbon cages: the structure and properties of endohedral fullerenes

1993 • 686 citations

The Higher Fullerenes: Isolation and Characterization of C ₇₆ , C ₈₄ , C ₉₀ , C ₉₄ , and C ₇₀ O, an Oxide of D _5h -C ₇₀

1991 • 658 citations

Covalent Fullerene Chemistry

1996 • 647 citations

The Chemistry of the Fullerenes

1994 • 613 citations

Isolation of the Heterofullerene C ₅₉ N as Its Dimer (C ₅₉ N) ₂

1995 • 595 citations

Basic Principles of the CIP‐System and Proposals for a Revision

1982 • 569 citations

NMR characterization of isomers of C78, C82 and C84 fullerenes

1992 • 514 citations

Noble Gas Atoms Inside Fullerenes

1996 • 470 citations

Stable Compounds of Helium and Neon: He@C ₆₀ and Ne@C ₆₀

1993 • 469 citations

Fullerene Chemistry in Three Dimensions: Isolation of Seven Regioisomeric Bisadducts and Chiral Trisadducts of C60 and Di(ethoxycarbonyl)methylene

1994 • 457 citations

Isolation of C76, a chiral (D2) allotrope of carbon

1991 • 411 citations

Fullerene Isomerism: Isolation of C _{2 v} ,-C ₇₈ and D ₃ -C ₇₈

1991 • 367 citations

Beyond C60: the higher fullerenes

1992 • 363 citations

Probing the interior of fullerenes by 3He NMR spectroscopy of endohedral 3He@C60 and 3He@C70

1994 • 342 citations

Incorporation of helium, neon, argon, krypton, and xenon into fullerenes using high pressure

1994 • 317 citations

Improved Purification of C₆₀ and Formation of σ‐ and π‐Homoaromatic methano‐bridged fullerenes by reaction with alkyl diazoacetates

1993 • 301 citations

Syntheses, structures, and properties of methanofullerenes

1994 • 278 citations

(.eta.2-C70)Ir(CO)Cl(PPh3)2: the synthesis and structure of an iridium organometallic derivative of a higher fullerene

1991 • 236 citations

Synthesis of Isomerically Pure Organodihydrofullerenes

1993 • 234 citations

Regio‐ and Diastereoselective Bisfunctionalization of C₆₀ and Enantioselective Synthesis of a C₆₀ Derivative with a Chiral Addition Pattern

1996 • 214 citations

Grundlagen des CIP-Systems und Vorschläge für eine Revision

2006 • 213 citations

Fluorinated fullerenes

1991 • 198 citations

Purification of gram quantities of C60. A new inexpensive and facile method

1992 • 183 citations

Formation and characterization of carbon mol.-helium (C60He+)

1991 • 177 citations

Exohedral adducts of La@C82

1995 • 171 citations

Oxygen and methylene adducts of C60 and C70

1991 • 171 citations

Synthesis of Prototypical Fullerene Cyclopropanes and Annulenes. Isomer Differentiation via NMR and UV Spectroscopy

1995 • 167 citations

Regiochemistry of Twofold Additions to [6,6] Bonds in C₆₀: Influence of the Addend‐Independent Cage Distortion in 1,2‐Monoadducts

1996 • 164 citations

Endohedral Metallofullerenes: New Spherical Cage Molecules with Interesting Properties

1996 • 157 citations

All-Carbon Polymers (Polyfullerenes) from Photochemical Reactions of Fullerene Clusters in Room-Temperature Solvent Mixtures

1995 • 154 citations

A new route to nitrogen heterofullerenes and the first synthesis of (C69N)2

1996 • 153 citations

Isolation and Characterization of C₈₀

1996 • 147 citations

Semiempirical calculations of dihydrogenated buckminsterfullerenes, C60H2

1992 • 146 citations

Optically Active Carbon: Kinetic Resolution of C ₇₆ by Asymmetric Osmylation

1993 • 143 citations

Theoretical Evidence for a C ₆₀ "Window" Mechanism

1994 • 142 citations

Fullerenes synthesis in combustion

1992 • 141 citations

Fullerenchemie in drei Dimensionen: Isolierung von sieben regioisomeren Bisaddukten sowie chiralen Trisaddukten aus C₆₀ und Di(ethoxycarbonyl)methylen

1994 • 140 citations

Structure and properties of C70

1991 • 134 citations

Preparation of hydrofullerenes by hydrogen radical induced hydrogenation

1993 • 130 citations

Synthesis, Chiroptical Properties, and Configurational Assignment of Fulleroproline Derivatives and Peptides

1996 • 129 citations

High-energy collisions of fullerene radical cations with target gases: capture of the target gas and charge stripping of C60.bul.+, C70.bul.+, and C84.bul.+

1992 • 123 citations

Nomenclature and terminology of fullerenes: A preliminary study

1997 • 120 citations

Progress in the design of selectors for buckminsterfullerene

1992 • 119 citations

C₅₉N⁺ and C₆₉N⁺: Isoelectronic Heteroanalogues of C₆₀ and C₇₀

1995 • 117 citations

Analysis of Isomers of the Higher Fullerenes by 3He NMR Spectroscopy

1995 • 117 citations

Buckminsterfullerenes

1994 • 116 citations

Characterization and stability of highly fluorinated fullerenes

1992 • 116 citations

Electrochemistry of Mono‐ through Hexakis‐adducts of C₆₀

1995 • 115 citations

Chemistry of the Higher Fullerenes: Preparative isolation of C₇₆ by HPLC and synthesis, separation, and characterization of Diels‐Alder monoadducts of C₇₀ and C₇₆

1994 • 111 citations

Gibbs energies of gas-phase electron transfer reactions involving the larger fullerene anions

1996 • 105 citations

Synthesis, Isolation, and Equilibration of 1,9- and 7,8-C ₇₀ H ₂

1994 • 104 citations

Photoinduced polymerization of solid C70 films

1994 • 104 citations

Structure of a Product of Double Addition to C₇₀: [C₇₀{Ir(CO)Cl(PPhMe₂)₂}₂]·3C₆H₆

1992 • 102 citations

Preparation of C60F36 and C70F36/38/40

1996 • 101 citations

Synthesis of the First Adducts of the Dimetallofullerenes La2@C80 and Sc2@C84 by Addition of a Disilirane

1995 • 100 citations

Formation and characterisation of C70Cl10

1995 • 93 citations

Partial Separation and Structural Characterization of C84 Isomers by Crystallization of (.eta.2-C84)Ir(CO)Cl(P(C6H5)3)2

1994 • 91 citations

Exohedral derivatization of an endohedral metallofullerene Gd@C82

1995 • 90 citations

Methanofullerene Molecular Scaffolding: Towards C₆₀‐substituted poly(triacetylenes) and expanded radialenes, preparation of a C₆₀–C₇₀ hybrid derivative, and a novel macrocyclization reaction

1997 • 90 citations

Asymmetric bisosmylation of fullerene C60: novel chiral .pi.-systems

1993 • 87 citations

Multiple Cyclopropanations of C₇₀. Synthesis and characterization of bis‐, tris‐, and tetrakis‐adducts and chiroptical properties of bis‐adducts with chiral addends, including a recommendation for the configurational description of fullerene derivatives with a chiral addition pattern

1995 • 87 citations

Osmylation of C70: reactivity versus local curvature of the fullerene spheroid

1993 • 85 citations

How Does Helium Get into Buckminsterfullerene?

1996 • 84 citations

Theoretical studies of selected C60H2 and C70H2 isomers

1993 • 82 citations

A superior synthesis of [6,6]-methanofullerenes: The reaction of sulfonium ylides with C60

1995 • 80 citations

Adduct of C70 at the Equatorial Belt: Photochemical Cycloaddition with Disilirane

1994 • 77 citations

Formation of C70Ph10 and C70Ph8 from the electrophile C70Cl10

1996 • 77 citations

Preparation and Isolation of Three Isomeric C70 Isoxazolines: Strong Deshielding in the Polar Region of C70

1994 • 76 citations

Resolution and Configurational Stability of the Chiral Fullerenes C76, C78, and C84: A Limit for the Activation Energy of the Stone-Wales Transformation

1994 • 75 citations

Reactions of fullerenes C60 and C70 with cyclopentadiene

1993 • 74 citations

[7H]Benzanthrone, a catalyst for the transfer hydrogenation of C60 and C70 by 9,10-dihydroanthracene

1993 • 73 citations

1,3-Dipolar Cycloaddition of N-Methylazomethine Ylide to C70

1995 • 73 citations

Filled Buckyballs: Recent Developments from the Endohedral Metallofullerenes of Lanthanides

1995 • 72 citations

Configurational Description of Chiral Fullerenes and Fullerene Derivatives with a Chiral Functionalization Pattern

1997 • 70 citations

[2 + 2] Cycloadditions of Fullerenes: Synthesis and Characterization of C62O3 and C72O3, the First Fullerene Anhydrides

1995 • 69 citations

Regio‐ und diastereoselektive Bisfunktionalisierung von C₆₀‐Fulleren und enantioselektive Synthese eines C₆₀‐Fullerenderivates mit chiralem Additionsmuster

1996 • 67 citations

Photo-transformations of C60, C70, C60O, and C60O2

1993 • 59 citations

Synthesis of [70]Azafulleroids: Investigations of Azide Addition to C₇₀

1997 • 59 citations

Patterns of Multiple Additions to Fullerene C₇₀: Isolation and Structural Characterization of [C₇₀{Pt(PPh₃)₂}₄]

1996 • 59 citations

A Guide to IUPAC Nomenclature of Organic Compounds

2002 • 58 citations

Holey fullerenes! a bis-lactone derivative of [70]fullerene with an eleven-atom orifice

1995 • 56 citations

Cycloaddition Reactions of Fullerenes

1995 • 53 citations

Synthesis and Characterization of the First C₇₀O Epoxides. Utilization of ³He NMR in Analysis of Fullerene Derivatives

1996 • 52 citations

The X-Ray Crystal Structures of a 1,9- and a 7,8-Diels-Alder monoadduct of C70

1995 • 50 citations

Product Predictions for Nucleophilic Additions toC₇₀

1992 • 47 citations

Chiral non-racemic C60 derivatives: A proposed sector rule for fullerene absolute configuration

1996 • 47 citations

Preparation and Structure of C₇₆(S₈)₆: A First Step in the Crystallographic Investigation of Higher Fullerenes

1994 • 43 citations

Addition of Aryl and Fluoroalkyl Radicals to Fullerene C₇₀: ESR Detection of Five Regioisomeric Adducts and Density Functional Calculations

1996 • 41 citations

Covalent fullerene chemistry

1997 • 40 citations

Single Column Purification of Gram Quantities of C70

1994 • 40 citations

Reaction of C60 and C70 with molecular oxygen

1996 • 39 citations

The EPR spectra of free radical adducts of C70

1992 • 39 citations

Polyhydrogenation of [60]- and [70]fullerenes with Zn/HCl and Zn/DCl

1996 • 38 citations

Chemoselective Synthesis and Resolution of Chiral [1,9]Methanofullerene[70] Derivatives

1996 • 37 citations

π‐Electron Ring‐Current Effects in Multiple Adducts of ³He@C₆₀ and ³He@C₇₀: A ³He NMR Study

1997 • 37 citations

Highly oxygenated derivatives of fluorinated C60, and the mode of fragmentation of the fluorinated cage under electron impact lonization conditions

1993 • 36 citations

[4+2+] Diels-Alder Cycloaddition to C60 and C70 Radical Cations in the Gas Phase: A Comparison with Solution

1994 • 36 citations

Biscyclopropanation of C₇₀

1995 • 35 citations

C₅₉N⁺ und C₆₉N⁺: isoelektronische Hetero‐Analoga von C₆₀ und C₇₀

1995 • 34 citations

Regiochemistry of Radical Addition to C70

1994 • 34 citations

Catalytic Hydrogenation of Fullerenes in the Presence of Metal Catalysts in Toluene Solution

1993 • 32 citations

Preparation and characterisation of C70Ph9OH; the first fullerene with a single hydroxy group attached to the cage

1996 • 32 citations

Buckyballs mit Inhalt: Neues von den endohedralen Metallofullerenen der Lanthanoide

1995 • 31 citations

Observation of difluorinated higher fullerene anions by Knudsen cell mass spectrometry and determination of electron affinities of C60F2 and C70F2

1994 • 31 citations

6,6 überbrückte geschlossene methanofullerene aus C60 und phosphoniumyliden

1994 • 30 citations

Doppelte Addition eines Iridiumkomplexes an C₇₀: [C₇₀{Ir(CO)CI(PPhMe₂)₂}₂] · 3C₆H₆

1992 • 30 citations

Synthesis, Separation, and Characterization of Optically Pure C₇₆ Mono‐Adducts

1996 • 30 citations

Nonchromatographic Purification of Fullerenes via Reversible Addition to Silica-Supported Dienes

1996 • 30 citations

Chiralität in der Fullerenchemie

1996 • 29 citations

Produktvoraussagen bei nucleophilen Additionen an C₇₀

1992 • 29 citations

The EPR spectra of hydrides of C70. An experimental and theoretical investigation

1994 • 28 citations

Reactions of C2ν-symmetrical C60 pentakis-adducts with diazomethane: regioselective formation of hexakis- to octakis-adducts and mechanism of methanofullerene formation by addition of diazomethane followed by dinitrogen extrusion

1997 • 28 citations

Reaction of C₆₀, C₇₀, C₇₆, C₇₈, and C₈₄ with ozone at 23.5°C

1993 • 27 citations

Isolierung und Charakterisierung von C₈₀

1996 • 27 citations

Structural characterization of C₇₀O. Remarkable disorder in crystalline [(η²-C₇₀O)Ir(CO)Cl(PPh₃)₂]·5C₆H₆

1996 • 25 citations

Preparation and Characterization of Fluorinated Fullerenes

1993 • 25 citations

Regioselective addition of silylene on to [70]fullerene

1995 • 24 citations

[3 + 2] Cycloadditions of Nitrile Oxides to C₇₀ Affording 4,5‐Dihydroisoxazoles and Their Structure Determination

1996 • 22 citations

Synthesis of Heterocycle-Containing [60]Fullerene Derivatives

1996 • 21 citations

Synthese der ersten Addukte der Dimetallofullerene La₂@C₈₀ und Sc₂@C₈₄ durch Addition eines Disilirans

1995 • 20 citations

Regiochemistry of Azide Additions to [70]Fullerene

1996 • 19 citations

ESR Detection of the Regioisomers Due to Addition of Methoxy and Methylthio Radicals to Fullerene C₇₀

1996 • 19 citations

Review of recent EPR and theoretical studies on the addition of free radicals to C₆₀ and C₇₀

1995 • 17 citations

Synthesis and Properties of Platinum Complexes of Fullerenes (C60 and C70)

1995 • 14 citations

Reaction of [70]fullerene with benzyne

1994 • 14 citations

Cycloaddition of Dipolar Trimethylenemethane to C₇₀Promoted by a Trace Amount of Water

1996 • 12 citations

Muster bei Mehrfachadditionen an das Fulleren C₇₀; Synthese und Struktur von [C₇₀{Pt(PPh₃)₂}₄]

1996 • 12 citations

Synthese und Struktur von C₇₆(S₈)₆: ein erster Schritt zur Kristallographie der höheren Fullerene

1994 • 11 citations

Molecular orbitals calculations of C70H radicals

1994 • 10 citations

Investigations on C70H30 obtained by the Birch reduction of C70

1993 • 8 citations

Reaction of Fullerenes with Radicals Generated by Thermal Decomposition of Azo Compounds

1995 • 5 citations

Structures, Stabilities and Strain in C₆₀and C₇₀Derivatives

1995 • 4 citations