Endohedral Metallofullerenes: New Spherical Cage Molecules with Interesting Properties

Density-functional thermochemistry. III. The role of exact exchange

1993 • 95,597 citations

Density-functional exchange-energy approximation with correct asymptotic behavior

1988 • 50,231 citations

Density-functional approximation for the correlation energy of the inhomogeneous electron gas

1986 • 17,918 citations

C60: Buckminsterfullerene

1985 • 15,178 citations

Ab initio effective core potentials for molecular calculations. Potentials for K to Au including the outermost core orbitals

1985 • 14,719 citations

Solid C60: a new form of carbon

1990 • 7,473 citations

Self-consistent molecular orbital methods. 21. Small split-valence basis sets for first-row elements

1980 • 3,758 citations

Relativistic Dirac-Fock expectation values for atoms with Z = 1 to Z = 120

1973 • 1,358 citations

Fullerenes with metals inside

1991 • 1,262 citations

Lanthanum complexes of spheroidal carbon shells

1985 • 1,166 citations

Atoms in carbon cages: the structure and properties of endohedral fullerenes

1993 • 686 citations

NMR characterization of isomers of C78, C82 and C84 fullerenes

1992 • 514 citations

Noble Gas Atoms Inside Fullerenes

1996 • 470 citations

Stable Compounds of Helium and Neon: He@C ₆₀ and Ne@C ₆₀

1993 • 469 citations

Confirmation by X-ray diffraction of the endohedral nature of the metallofullerene Y@C82

1995 • 466 citations

Electron paramagnetic resonance studies of lanthanum-containing C82

1992 • 428 citations

Probing the interior of fullerenes by 3He NMR spectroscopy of endohedral 3He@C60 and 3He@C70

1994 • 342 citations

Encapsulation of a scandium trimer in C82

1992 • 325 citations

Incorporation of helium, neon, argon, krypton, and xenon into fullerenes using high pressure

1994 • 317 citations

Threshold photodetachment of cold C−60

1991 • 312 citations

Endohedral complexes: Atoms and ions inside the C60 cage

1991 • 279 citations

XPS probes of carbon-caged metals

1992 • 261 citations

Scandium Clusters in Fullerene Cages

1992 • 236 citations

Isolation and characterization of the metallofullerene LaC82

1993 • 223 citations

Redox Properties of Organofullerenes

1994 • 223 citations

Mass Spectroscopic and ESR Characterization of Soluble Yttrium-Containing Metallofullerenes YC₈₂ and Y₂C₈₂

1992 • 215 citations

Isolation and spectroscopic properties of scandium fullerenes (Sc2@C74, Sc2@C82, and Sc2@C84)

1993 • 198 citations

Structural and Electronic Properties of La@C ₈₂

1992 • 187 citations

Exohedral adducts of La@C82

1995 • 171 citations

C60La: a deflated soccer ball?

1986 • 154 citations

A theoretical approach to C82 and LaC82

1993 • 149 citations

Carbon clusters revisited: The ‘‘special’’ behavior of C6 and large carbon clusters

1988 • 149 citations

Electronic and geometric structure of La@<mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline"><mml:mrow><mml:msub><mml:mrow><mml:mi mathvariant="normal">xaC</mml:mi></mml:mrow><mml:mrow><mml:mn>82</mml:mn></mml:mrow></mml:msub></mml:mrow></mml:math>and<mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline"><mml:mrow><mml:msub><mml:mrow><mml:mi mathvariant="normal">C</mml:mi></mml:mrow><mml:mrow><mml:mn>82</mml:mn></mml:mrow></mml:msub></mml:mrow></mml:math…

1994 • 143 citations

Electrochemistry and Ab Initio Study of the Dimetallofullerene La₂@C₈₀

1995 • 141 citations

Electrochemical properties of fullerenolanthanides

1996 • 138 citations

Metallofullerenes MC82 (M = Sc, Y, and La). A theoretical study of the electronic and structural aspects

1993 • 133 citations

Isomers and carbon-13 hyperfine structures of metal-encapsulated fullerenes M@C82 (M = Sc, Y, and La)

1992 • 132 citations

A theoretical study of C80 and La2@C80

1995 • 126 citations

Reaction of C60 with silylene, the first fullerene silirane derivative

1993 • 125 citations

Studies of metallofullerene primary soots by laser and thermal desorption mass spectrometry

1993 • 120 citations

Electronic structure of metallofullerene<mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline"><mml:mrow><mml:msub><mml:mrow><mml:mi mathvariant="normal">LaC</mml:mi></mml:mrow><mml:mrow><mml:mn>82</mml:mn></mml:mrow></mml:msub></mml:mrow></mml:math>: Electron transfer from lanthanum to<mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline"><mml:mrow><mml:msub><mml:mrow><mml:mi mathvariant="normal">C</mml:mi></mml:mrow><mml:mrow><mml:mn>82</mml:mn></mml:mrow…

1993 • 117 citations

Analysis of Isomers of the Higher Fullerenes by 3He NMR Spectroscopy

1995 • 117 citations

Characterization of the Isolated Y@C82

1994 • 113 citations

Preparation and structure of crystals of the metallofullerene Sc2@C84

1994 • 112 citations

¹³C-NMR Study on the Structure of Isolated Sc₂@C₈₄ Metallofullerene

1996 • 105 citations

Isolation and Characterization of an ESR-Active La@C82 Isomer

1994 • 104 citations

Spectroscopic Properties of Isolated Sc3@C82 Metallofullerene

1994 • 101 citations

Synthesis of the First Adducts of the Dimetallofullerenes La2@C80 and Sc2@C84 by Addition of a Disilirane

1995 • 100 citations

Magnetic properties of Gd@C82 metallofullerene

1995 • 99 citations

Electrochemical properties of La@C82

1993 • 99 citations

Encapsulation of Radioactive 159Gd and 161Tb Atoms in Fullerene Cages

1994 • 94 citations

Multiple species of La@C82 and Y@C82. Mass spectroscopic and solution EPR studies

1992 • 89 citations

Organic chemical derivatization of fullerenes. 2. Photochemical [2 + 3] cycloaddition of C60 with disiliranes

1993 • 88 citations

Theoretical study of the lanthanide fullerene CeC82. Comparison with ScC82, YC82 and LaC82

1994 • 87 citations

Theoretical study of the dimetallofullerene Sc2@C84

1994 • 85 citations

Correlation between Volatility of Rare-Earth Metals and Encapsulation of Their Carbides in Carbon Nanocapsules

1994 • 85 citations

Magnetic properties of rare-earth metallofullerenes

1995 • 80 citations

3He NMR: A Powerful New Tool for Following Fullerene Chemistry

1994 • 79 citations

Anaerobic sampling and characterization of lanthanofullerenes: extraction of LaC76 and other LaC2n

1992 • 77 citations

Adduct of C70 at the Equatorial Belt: Photochemical Cycloaddition with Disilirane

1994 • 77 citations

The He I valence photoelectron spectrum ofC70 in the gas phase

1992 • 72 citations

ESR study of the electronic structures of metallofullerenes: a comparison between lanthanum fullerene (La@C82) and scandium fullerene (Sc@C82)

1993 • 69 citations

Stability of M@C60 endohedral complexes

1993 • 62 citations

Structural information on Y ions in C82 from EXAFS experiments

1993 • 61 citations

Theoretical study of heteroatom-containing compounds. From aromatic and polycyclic molecules to hollow cage clusters

1993 • 60 citations

Chemical Reactivity of a Metallofullerene: EPR Study of Diphenylmethano-La@C82 Radicals

1995 • 58 citations

Si60 and Si60X (X=Ne, F− and Na+)

1991 • 58 citations

Chemical derivatization of endohedral metallofullerene La@C82 with digermirane

1996 • 55 citations

An Oriented Cluster Formation of Endohedral Y@C82 Metallofullerenes on Clean Surfaces

1995 • 52 citations

Synthesis and 3He NMR Studies of C60 and C70 Epoxide, Cyclopropane, and Annulene Derivatives Containing Endohedral Helium

1994 • 47 citations

Direct STM imaging of spherical endohedral discandium fullerenes (Sc2@C84)

1993 • 47 citations

AM1 computed thermal effects within the nine isolated-pentagon-rule isomers of C82

1995 • 44 citations

Divalent scandium atoms in the cage of<mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline"><mml:mrow><mml:msub><mml:mrow><mml:mi mathvariant="normal">C</mml:mi></mml:mrow><mml:mrow><mml:mn>84</mml:mn></mml:mrow></mml:msub></mml:mrow></mml:math>

1995 • 44 citations

Higher Fullerenes: Structure and Properties

1994 • 43 citations

Endohedral effect in inclusion complexes of the C6 cluster

1992 • 43 citations

Carbon Clusters Containing Two Metal Atoms: Structures, Growth Mechanism, and Fullerene Formation

1996 • 31 citations

2D EPR investigation of endohedral La@C82 in solution

1995 • 31 citations

Formation and stability of small metallocarbon clusters: what is the specificity for the formation of stable metallofullerenes?

1994 • 30 citations

Networked and Endohedral La2Cn+ (n = 28-100) Metallofullerenes

1995 • 25 citations

An ESR study of the formation of La@C82 isomers in arc synthesis

1996 • 23 citations

An XAFS study of metallofullerene La@C82

1995 • 20 citations

Organosilicon Derivatives of Buckminsterfullerene (C₆₀): First Preparation of A Fullerene Silirane

1993 • 6 citations