“Orbital steering”, entropy, and rate accelerations

The Effect of Geminal Substitution Ring Size and Rotamer Distribution on the Intramolecular Nucleophilic Catalysis of the Hydrolysis of Monophenyl Esters of Dibasic Acids and the Solvolysis of the Intermediate Anhydrides

1960 • 209 citations

The energetics of neighbouring group participation

1973 • 185 citations

Neighboring Carbon and Hydrogen. XIV. Participation in Solvolysis of Some Primary Benzenesulfonates¹

1953 • 114 citations

Indication of the magnitude of orientation factors in esterification

1972 • 93 citations

Intramolecular Carboxylate Attack on Ester Groups. The Hydrolysis of Substituted Phenyl Acid Succinates and Phenyl Acid Glutarates¹

1960 • 70 citations

Effect of small changes in orientation on reaction rate

1972 • 62 citations

The Kinetics of Some Gaseous Diels—Alder Reactions

1936 • 52 citations

Intramolecular Catalysis of Hydrolytic Reactions. IV. A Comparison of Intramolecular and Intermolecular Catalysis^1,2

1958 • 50 citations

Nuclearmagnetic resonance studies of selectively hindered internal motion of substrate analogs at the active site of pyruvate kinase

1972 • 37 citations

Proximity, entropy and orbital steering

1973 • 35 citations

A thermochemical and kinetic analysis of the mechanisms of pyrolysis of polycyclic molecules

1970 • 32 citations

Solvation and approximation. Solvent effects on the bimolecular and intramolecular nucleophilic attack of carboxyl anion on phenyl esters

1970 • 23 citations

The contribution of proximity and orientation to catalytic reaction rates

1973 • 19 citations

Entropic rate accelerations and orbital steering

1972 • 9 citations

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