Reactivity of Mono-Meso-Substituted Iron(II) Octaethylporphyrin Complexes with Hydrogen Peroxide in the Absence of Dioxygen. Evidence for Nucleophilic Attack on the Heme

Fenton's reagent revisited

1975 • 2,778 citations

On the preparation of metalloporphyrins

1970 • 1,714 citations

Peroxidases in chemistry and biology

1990 • 1,039 citations

Catalytic Oxidations with Hydrogen Peroxide as Oxidant

1992 • 645 citations

Cytochrome P450

1995 • 582 citations

Polyhaloporphyrins: Unusual Ligands for Metals and Metal-Catalyzed Oxidations

1997 • 495 citations

Totalsynthese des Chlorophylls

1960 • 225 citations

Sterically protected hemins with electronegative substituents: efficient catalysts for hydroxylation and epoxidation

1984 • 215 citations

Reaction of Hydrogen Peroxide with Ferrylhemoglobin: Superoxide Production and Heme Degradation

2000 • 199 citations

Formation of Fluorescent Heme Degradation Products during the Oxidation of Hemoglobin by Hydrogen Peroxide

1998 • 187 citations

Substituent effects on chemical reactivity. Improved evaluation of field and resonance components

1983 • 174 citations

Mechanism of heme degradation by heme oxygenase

2000 • 166 citations

Heme Oxygenase-1, Intermediates in Verdoheme Formation and the Requirement for Reduction Equivalents

1997 • 121 citations

Zur weiteren Kenntnis des Chlorophylls und des Hämins, VI. Formylierung der meso‐Kohlenstoffatome von Alkyl‐substituierten Porphyrinen

1966 • 118 citations

Preparation and Characterization of a Dialkoxyiron(IV) Porphyrin

1985 • 108 citations

Heme oxygenase structure and mechanism

2000 • 104 citations

The Interaction of Cytochrome Oxidase with Hydrogen Peroxide: The Relationship of Compounds P and F

1995 • 100 citations

The meso-reactivity of porphyrins and related compounds. Part VI. Oxidative cleavage of the haem system. The four isomeric biliverdins of the IX series

1973 • 100 citations

HAEM catabolism and coupled oxidation of haemproteins

1969 • 94 citations

Ion radicals. 45. Reactions of zinc tetraphenylporphyrin cation radical perchlorate with nucleophiles

1979 • 91 citations

Facilemeso Functionalization of Porphyrins by Nucleophilic Substitution with Organolithium Reagents

1998 • 85 citations

The meso Reactivity of Porphyrins and Related Compounds. I. Nitration

1965 • 85 citations

Novel meso-substitution reactions of metalloporphyrins

1979 • 82 citations

Isolation and characterization of an iron biliverdin-type complex that is formed along with verdohemochrome during the coupled oxidation of iron(II) octaethylporphyrin

1993 • 79 citations

Structural characterization of verdoheme analogs. Iron complexes of octaethyloxoporphyrin

1993 • 74 citations

[30] Hydrogen peroxide-mediated ferrylhemoglobin generation in Vitro and in red blood cells

1994 • 69 citations

Grünes Haemin aus Blut‐Haemin

1930 • 62 citations

Efficient Coupled Oxidation of Heme by an Active Site Variant of Horse Heart Myoglobin

1996 • 57 citations

Studies on the Iron(II) meso-Oxyporphyrin .pi.-Neutral Radical as a Reaction Intermediate in Heme Catabolism

1995 • 54 citations

Direct hydroxylation at the meso position of gold(III) tetraphenylporphyrin by nucleophilic addition: novel hydroxyphlorin derivatives

1992 • 50 citations

Oxidation of the meso-Methylmesoheme Regioisomers by Heme Oxygenase

1996 • 49 citations

Coordination chemistry with meso-hydroxylated porphyrins (oxophlorins), intermediates in heme degradation

2000 • 49 citations

Chemistry of iron oxophlorins. 1. Proton NMR and structural studies of five-coordinate iron(III) complexes

1992 • 46 citations

Reaction of Bovine Cytochrome c Oxidase with Hydrogen Peroxide Produces a Tryptophan Cation Radical and a Porphyrin Cation Radical

2000 • 44 citations

Synthesis of oxophlorins (oxyporphyrins) from magnesium and zinc porphyrin chelates

1973 • 44 citations

Reactions of the iron(III) tetraphenylporphyrin .pi. cation radical with triphenylphosphine and the nitrite anion. Formation of .beta.-substituted iron(III) porphyrins

1991 • 43 citations

Oxidation of α-meso-Formylmesoheme by Heme Oxygenase

1997 • 42 citations

Nuclear magnetic resonance studies of axial amine coordination in synthetic ferryl, (FeIVO)2+, porphyrin complexes and in ferryl myoglobin

1985 • 41 citations

In Situ Monitoring of the Degradation of Iron Porphyrins by Dioxygen with Hydrazine as Sacrificial Reductant. Detection of Paramagnetic Intermediates in the Coupled Oxidation Process by ¹H NMR Spectroscopy

1999 • 40 citations

The structure of verdohemochrome and its implications for the mechanism of heme catabolism

1982 • 36 citations

A Role for Electron Transfer in Heme Catabolism? Structure and Redox Behavior of an Intermediate, (Pyridine)₂Fe(octaethyloxophlorin)

1996 • 36 citations

NMR studies of metalloporphyrin radicals. Iron(II) oxophlorin radical formed from iron(III) meso-hydroxyoctaethylporphyrin

1986 • 34 citations

Heme/Hydrogen Peroxide Reactivity: Formation of Paramagnetic Iron Oxophlorin Isomers by Treatment of Iron Porphyrins with Hydrogen Peroxide

2000 • 32 citations

Novel Reactions of Iron(III) Tetraphenylporphyrin .pi.-Cation Radicals with Pyridine

1995 • 31 citations

Coordination patterns for oxophlorin ligands. Pyridine-induced cleavage of dimeric manganese(III) and iron(III) octaethyloxophlorin complexes

1993 • 29 citations

Sulfur compounds. 148. Generation and characterization of dihydroxy disulfide, HOSSOH: the chainlike isomer of thiosulfurous acid

1992 • 29 citations

Oxidation of an α-Meso-Methyl-Substituted Heme to an α-Biliverdin by Heme Oxygenase. A Novel Heme Cleavage Reaction

1996 • 26 citations

Electronic states of iron oxyporphyrin and verdohemochrome obtained by coupled oxidation of iron porphyrin

1981 • 26 citations

Disproportionation of Iron(III) Porphyrin π-Cation Radicals in the Presence of Sterically Hindered Pyridines. Spectroscopic Detection of Asymmetric Highly Oxidized Intermediates

1996 • 24 citations

Synthesis of meso-pyridinium porphyrin salts

1976 • 15 citations

Metalloporphyrins in Polymeric Matrices, Micelles, and Vesicles, V. 5‐(1′‐Methyl‐4,4′‐bipyridinium‐1‐yl)Octaethylporphyrin Dichloride, a meso‐Viologenporphyrinate

1984 • 11 citations

¹H nuclear magnetic resonance studies of the reaction of iron(III) porphyrin cation radical with aryl Grignard reagents

1993 • 10 citations

The Preparation of 2-Vinylthiazoles

1951 • 5 citations