Zusammenhänge zwischen Struktur und Reaktivität in der Chemie freier Radikale

A Correlation of Reaction Rates

1955 • 3,425 citations

Molecular Orbital Theory for Organic Chemists

1962 • 1,691 citations

Molecular Orbital Theory for Organic Chemists

2013 • 1,498 citations

Additivity rules for the estimation of thermochemical properties

1969 • 1,378 citations

Stereochemistry of carbon compounds

1962 • 1,110 citations

Free Radicals in Solution.

1958 • 957 citations

Free radicals in solution

1957 • 666 citations

III - Bond energies

1965 • 660 citations

Organic chemistry of stable free radicals

1968 • 466 citations

The valence-shell electron-pair repulsion (VSEPR) theory of directed valency

1963 • 378 citations

Organic chemistry of synthetic high polymers

1968 • 353 citations

A Quantitative Treatment of Directive Effects in Aromatic Substitution

1963 • 231 citations

Molecular geometry: Bonded versus nonbonded interactions

1968 • 210 citations

An Introduction to Free-Radical Chemistry

2000 • 197 citations

Kinetics and rate constants for the reduction of alkyl halides by organotin hydrides

1968 • 184 citations

I-Strain as a Factor in the Chemistry of Ring Compounds^1,2

1951 • 181 citations

Directive Effects in the Attack of Phenyl Radicals on Carbon-Hydrogen Bonds

1963 • 161 citations

ESR-Untersuchungen an kurzlebigen Radikalen während der Redoxpolymerisation einiger Monomeren

1964 • 130 citations

The Effect of Ring Size on the Rate of Solvolysis of the 1-Chloro-1-methylcycloalkanes^1,2

1952 • 128 citations

Torsional Effects in Polycyclic Systems. II. The Stereochemistry of Attack and Departure in Norbornane Derivatives

1967 • 123 citations

Electron‐Pair Repulsions and Molecular Shape

1967 • 120 citations

THE INHIBITED AUTOXIDATION OF STYRENE: PART II. THE RELATIVE INHIBITING EFFICIENCIES OF META- AND PARA-SUBSTITUTED PHENOLS

1963 • 120 citations

Elektronenpaar‐Abstoßung und Molekülgestalt

1967 • 117 citations

Isomerization and electron spin resonance of allylic radicals

1968 • 113 citations

Peresters. IV. Substituent Effects upon the Concerted Decomposition of t-Butyl Phenylperacetates¹

1960 • 112 citations

Conformation Analysis of Bridgehead Carbonium Ions

1967 • 102 citations

Viscosity dependence of bond homolysis. Qualitative and semiquantitative test for cage return

1970 • 101 citations

Azocumene. I. Preparation and Decomposition of Azocumene. Unsymmetrical Coupling Products of the Cumyl Radical

1966 • 92 citations

Absolute Rate Constants for Hydrocarbon Autoxidation

1968 • 90 citations

Nitrenes and the Decomposition of Carbonylazides

1967 • 87 citations

Hot Atom Chemistry

1965 • 86 citations

Nitroso‐acyl‐amine und Diazo‐ester XII. Zur Frage der Carbonium‐Umlagerungen Beim Zerfall der Alkyl‐Diazoester

1956 • 78 citations

Free Radical Reactions in Preparative Organic Chemistry.

1964 • 73 citations

The Effect of Ring Size on the Rate of Acetolysis of the Cycloalkyl p-Toluene and p-Bromobenzenesulfonates¹

1956 • 71 citations

Equilibrium constant for allyl radical recombination. Direct measurement of "allyl resonance energy"

1969 • 69 citations

Radicals in organic chemistry

1965 • 68 citations

Zur Kenntnis des Kohlenstoffringes. 67. Mitteilung. Solvolysegeschwindigkeit der Cyclanyl‐p‐toluolsulfonate mittlerer Ringgrösse in Eisessig

1955 • 65 citations

HANDBOOK OF ORGANIC STRUCTURAL ANALYSIS

1965 • 65 citations

Bridged, non-classical carbonium ions

1966 • 64 citations

Azo-bis Nitriles.¹ The Decomposition of Azo Compounds Derived from Cycloalkanones. An Accurate Measure of Differences in Ring Strain

1953 • 64 citations

Polar and Solvent Effects in the Cleavage of t-Alkoxy Radicals

1965 • 62 citations

Positive Halogen Compounds. XIII. t-Butyl Hypochlorite Chlorination of Ethers, Aldehydes, and Other Molecules with Polar Substituents

1967 • 59 citations

On the Relations between ESR-Hyperfine Splittings and Spin Densities in Simple Substituted Alkyl Radicals

1965 • 59 citations

Stereoselectivity in free radicals of the norbornyl type

1970 • 59 citations

Nichtkatalysierte Perester-Zersetzungen

2006 • 59 citations

Inversion barriers by the MINDO [modified intermediate neglect of differential overlap] method

1969 • 59 citations

Introduction to theoretical organic chemistry

1968 • 58 citations

Azocumene. II. Cage Effects and the Question of Spin Coupling in Radical Pairs

1966 • 54 citations

Relative Reactivities of Substituted Toluenes Toward Trichloromethyl Radicals

1960 • 50 citations

Rates of recombination of carbon radicals in solution

1969 • 49 citations

Free radical cyclizations

1967 • 48 citations

Über Nitrene und die Zersetzung von Carbonylaziden

1967 • 48 citations

Polar and Solvent Effects on Homolytic Abstraction of Benzylic Hydrogen of Substituted Toluenes by t-Butoxy Radical

1967 • 48 citations

Free radical reactions in preparative organic chemistry

1964 • 47 citations

A Further Study of the exo- and endo-2-Carbo-t-butylperoxynorbornanes

1965 • 45 citations

Electron-Spin Resonance Studies of Short-Lived Organic Radicals

1967 • 41 citations

Acidity of hydrocarbons. XXXII. Kinetic acidities of medium-sized cycloalkanes. Pyramidal alkyl anions

1969 • 40 citations

The thermolysis of bridgehead tert-butyl peresters

1968 • 38 citations

The Mechanism of the Thermal Decomposition of α-Phenylethylazomethane. A Two-Step Reaction¹

1965 • 38 citations

Solvolyses of tertiary .alpha.-arylcycloalkyl and -polycycloalkyl chlorides. Effects of ring size and substituents in the aryl ring on the solvolysis rates

1970 • 35 citations

Formation of the bridgehead free radical 1-adamantyl by perester decomposition

1968 • 35 citations

A modern look at Markovnikov's rule and the peroxide effect

1969 • 34 citations

Free Radical Studies at Low Temperatures

1968 • 34 citations

Theoretical Organic Chemistry

1903 • 31 citations

Reaction of 2,4,6-tri-tert-butylphenoxy radical with unhindered phenols

1967 • 31 citations

Reactions of ester-free radicals. The 2-carbomethoxy-2-propyl radical

1968 • 29 citations

Bridgehead free radical stability. The decomposition of t-butylperoxyesters of the 1-adamantyl, 1-bicyclo[2•2•2]octyl, and 1-norbornyl systems

1968 • 29 citations

Relative rates of addition of cyclopropyl radicals to olefins. I

1970 • 28 citations

Nitrene insertion selectivities. Reaction of ethyl azidoformate with saturated cyclic hydrocarbons

1968 • 28 citations

Evidence of the Re-formation of an Initiator from a Geminate Pair (Internal Return from the Cage)

1967 • 27 citations

Degenerate [3,3]sigmatropic shift of acetyl peroxide

1970 • 25 citations

Chemistry at High Velocities

1966 • 25 citations

Secondary deuterium isotope effects in radical-forming reactions. V. tert-Butyl peracetate and substituted tert-butyl phenylperacetates

1970 • 22 citations

Acidity of hydrocarbons. XXX. Kinetic isotope effects of the cesium cyclohexylamide catalyzed proton exchange of cyclohexane with cyclohexylamine

1969 • 21 citations

REACTIONS OF ATOMS AND FREE RADICALS. VII. DIACETYL PEROXIDE AS AN AGENT FOR LINKING α-CARBON TO α-CARBON ATOMS IN ORGANIC ESTERS

1945 • 21 citations

Die Untersuchung freier Radikale bei tiefer Temperatur

1968 • 20 citations

Secondary deuterium isotope effects in radical-forming reactions. IV. Concerted perester decompositions

1969 • 19 citations

Correlation of secondary .alpha.-deuterium isotope effects with primary nitrogen isotope effects in the thermolysis of azo compounds

1967 • 16 citations

Neue Tieftemperatur‐Initiatoren

1966 • 16 citations

A COMPARATIVE STUDY OF SOME REACTIONS OF THE METHYL AND THE ETHOXY FREE RADICALS IN A GRADED SERIES OF SOLVENTS¹

1954 • 16 citations

Nature of the polar effect in hydrogen atom abstractions from alcohols, ethers, and esters

1968 • 15 citations

Shape of Alkyl Radicals by Electron Spin Resonance

1969 • 15 citations

The Secondary α-Deuterium Isotope Effect in the Thermal Decomposition of α-Phenylethylazo-2-propane

1963 • 14 citations

Reactivities of monomers towards the phenyl radical; a scale of phenyl affinities

1969 • 14 citations

Relative reactivities and linear free energy relationships in competitive addition of substituted phenyl radicals to vinyl monomers

1969 • 13 citations

Organic Reaction Mechanisms

1968 • 13 citations

Organische Peroxyde, V. Ionische Perester‐Fragmentierungen unter Einwirkung von Säure

1966 • 11 citations

Organische Peroxide, VI. Die Zerfallsgeschwindigkeit des p‐Methylmercapto‐phenylperessigsäure‐tert.‐butylesters

1967 • 11 citations

Essais de Chloration Dirigée V‐Photochloration des dérivés butyriques(⁸)

1957 • 11 citations

Abbruch bei Reaktionen freier Radikale

1960 • 9 citations

Secondary deuterium isotope effects in radical forming reactions. III. Decomposition of acetyl peroxide

1969 • 9 citations

Stereochemistry of the reactions of molecular oxygen with 1,4-dimethylcyclohexyl and 2-methylnorbornyl radicals generated from isomeric sources

1970 • 6 citations

Steric effects on the course of radical additions to olefins

1968 • 4 citations

Abstraction of hydrogen atoms from bicyclo[2.1.1]hexane by methyl radicals and chlorine atoms: photochlorination of 1-methylbicyclo[2.1.1]hexane

1969 • 4 citations

Molekularstrahl‐Streuexperimente zur Untersuchung von chemischen Reaktionen

1969 • 4 citations

Die Chemie freier Radikale

1969 • 3 citations