Nichtkatalysierte Perester-Zersetzungen

A Reëxamination of the Hammett Equation.

1953 • 2,102 citations

Free Radicals in Solution.

1958 • 957 citations

Advances in Heterocyclic Chemistry

2011 • 700 citations

The Factors Determining Nucleophilic Reactivities

1962 • 677 citations

Free radicals in solution

1957 • 666 citations

Resonance in Organic Chemistry.

1956 • 483 citations

Cubane

1964 • 439 citations

Resonance in Organic Chemistry

1956 • 390 citations

THE BASE CATALYZED DECOMPOSITION OF A DIALKYL PEROXIDE

1951 • 339 citations

An X-Ray Diffraction Study of Nonplanar Carbanion Structures

1964 • 322 citations

Peroxide Reaction Mechanisms.

1962 • 249 citations

Die Umlagerung der Dekalin‐peroxydester als Folge von kationischem Sauerstoff

1948 • 244 citations

Color and Constitution. XIII.¹ Merocyanines as Solvent Property Indicators²

1965 • 223 citations

Empirische Parameter der Lösungsmittelpolarität

1965 • 202 citations

Peresters. V.¹ Di-t-butylperoxyoxalate

1960 • 189 citations

A Series of Tertiary Butyl Peresters Showing Concerted Decomposition

1958 • 189 citations

Solvent Effects in Organic Chemistry. V. Molecules, Ions, and Transition States in Aqueous Ethanol¹

1965 • 178 citations

Small-Ring Compounds. X. Molecular Orbital Calculations of Properties of Some Small-Ring Hydrocarbons and Free Radicals¹

1952 • 177 citations

A Quantitative Treatment for Electrophilic Reactions of Aromatic Derivatives^1-3

1957 • 176 citations

Directive Effects in the Attack of Phenyl Radicals on Carbon-Hydrogen Bonds

1963 • 161 citations

Salt Effects and Ion Pairs in Solvolysis and Related Reactions. IX. The threo-3-p-Anisyl-2-butyl System^1-3

1958 • 156 citations

Galvinoxyl (2,6-Di-tert-butyl-α-(3,5-di-tert-butyl-4-oxo-2,5-cyclohexadiene-1-ylidene)-p-tolyloxy) as a Scavenger of Shorter-lived Free Radicals

1962 • 153 citations

Effect of Structure on the Rate of Spontaneous Thermal Decomposition of Substituted Benzoyl Peroxides

1950 • 150 citations

Correlation of Solvolysis Rates. IX. p-Methoxyneophyl Toluenesulfonate in a Variety of Solvents. Ionizing Power of Hydroxylic and Non-hydroxylic Solvents^1,2

1961 • 143 citations

PEROXIDE reaction mechanisms

1962 • 131 citations

The Linear Relationship between Enthalpy and Entropy of Activation

1964 • 115 citations

The Synthesis and Stability of Some Cyclopropenyl Cations with Alkyl Substituents

1962 • 114 citations

Peresters. IV. Substituent Effects upon the Concerted Decomposition of t-Butyl Phenylperacetates¹

1960 • 112 citations

Notes on Molecular Orbital Calculations

1974 • 108 citations

Reduction of Organic Halides by Chromium(II). Mechanism of the Formation of Benzylchromium Ion

1964 • 98 citations

Esters of Peroxycarbonic Acids

1950 • 95 citations

The Decomposition of Benzoyl Peroxide in Solvents. II. Ethers, Alcohols, Phenols and Amines

1947 • 94 citations

Improved Iodometric Method of Analysis for tert-Butyl Peresters

1958 • 93 citations

Bicyclo [2.1.1.]hexane Derivatives¹

1961 • 92 citations

Free Radicals by Mass Spectrometry. XXI. The Ionization Potentials of Some meta and para Substituted Benzyl Radicals

1961 • 81 citations

Über den Mechanismus der Oxydationsvorgänge (IV.)

1921 • 74 citations

Studies in Organic Peroxides. XXV. Preparation, Separation and Identification of Peroxides Derived from Methyl Ethyl Ketone and Hydrogen Peroxide

1959 • 70 citations

Ein neuer Weg in die Cyclodecanreihe

1945 • 68 citations

XIII. Die ersten Einwirkungsprodukte von Alkalimetallen auf Butadiene

1934 • 67 citations

Mechanisms of Reaction of Organomercurials. II. Electrophilic Substitution on Saturated Carbon. Acetolysis of Dialkylmercury Compounds

1955 • 67 citations

LARGE SALT EFFECTS IN NON-POLAR SOLVENTS

1959 • 67 citations

The Reaction of Acyl Peroxides with Phenols¹

1958 • 64 citations

Studies in Organic Peroxides. IX. t-Butyl Peresters

1946 • 61 citations

Der mechanismus der Bachmann-Gomberg reaktion

1964 • 61 citations

Studies of the Mechanisms of the Reactions of Benzoyl Peroxide with Secondary Amines and Phenols

1960 • 58 citations

Dünnschichtchromatographische Identifizierung organischer Peroxide

1962 • 58 citations

Carbonium Ions. VIII. Diarylolefin-Diarylalkyl Cation Equilibria¹

1959 • 55 citations

Electrophilic Fragmentation in the Tropilidene Series

1959 • 54 citations

542. Infra-red absorption of the carbonyl group. Part I. Diacyl peroxides, per-esters, and per-acids

1951 • 54 citations

Anchimerically Accelerated Bond Homolysis. II.¹ Neighboring Iodide and Sulfide Groups in t-Butyl Perester Decompositions

1962 • 54 citations

Decompositions of Di-t-alkyl Peroxides. IV. Decomposition of Pure Liquid Peroxide

1950 • 53 citations

Stereochemical Evidence of Bridged Radicals

1963 • 53 citations

Peroxides. VI.² Preparation of t-Butyl Peresters and Diacyl Peroxides of Aliphatic Monobasic Acids³

1959 • 51 citations

Peresters. III.¹ t-Butyl Phenylperacetate, Trichloroperacetate and Trimethylperacetate

1960 • 50 citations

Acidity of Hydrocarbons. XIV. Polarographic Reduction of Substituted Benzyl Chlorides and Polycyclic Arylmethyl Chlorides

1964 • 49 citations

Chemiluminescence from the Reaction of 9-Chlorocarbonyl-10-methylacridinium Chloride with Aqueous Hydrogen Peroxide¹

1965 • 48 citations

Der Einfluß α‐ständiger Sauerstoff‐ und Schwefelatome auf die Hydrolysierungsgeschwindigkeit der Kohlenstoff‐Halogen‐Bindung

1941 • 48 citations

Über ein krystallisiertes Dekalinperoxyd

1944 • 48 citations

Photosensibilisierte Synthese Tertiärer Allylhydroperoxyde Aus Symmetrisch Tetrasubstituierten Äthylenen

1958 • 47 citations

The Diphenylcyclopropenyl Cation. Synthesis and Stability¹

1961 • 47 citations

The Kinetics of the Thermal Decomposition of Peresters. III. The Effect of p-Substituents on the Unimolecular Decomposition of t-Butyl Perbenzoates¹

1951 • 47 citations

The Stereochemistry of the Perbenzoic Acid Oxidation of Optically Active exo-Acetylnorbornane¹

1959 • 45 citations

STRUCTURAL CRITERIA FOR CHEMILUMINESCENCE IN ACYL PEROXIDE DECOMPOSITION REACTIONS

1965 • 42 citations

Notes: Small-Ring Compounds. XXIV. Molecular Orbital Calculations of the Delocalization Energies of Some Small-Ring Systems

1959 • 41 citations

Darstellung und Veresterung tertiärer Hydroperoxyde

1948 • 41 citations

Cage Recombination of t-Butoxy Radicals

1965 • 41 citations

The Stereochemistry of 9-Decalyl Free Radicals

1965 • 39 citations

Infrared Absorption Frequencies of tert-Butoxy Group

1960 • 38 citations

Peresters. XI. Di-tert-butylperoxy Diphenylmalonate. α-Lactone Intermediates in Free Radical Reactions

1963 • 36 citations

The Decomposition of Benzoyl Peroxide in the Presence of Iodine. II. In Carbon Tetrachloride Solution^1,2

1950 • 35 citations

Über Triphenylmethyl‐hydroperoxyd

1931 • 34 citations

Effects of Nonpolar Solvents on an Ionic Reaction. The Ionic Decomposition of tert-Butylperoxy Formate

1964 • 33 citations

Ueber Aethylhydroperoxyd

1901 • 33 citations

Darstellung von Percarbonsäure‐tert.‐butylestern über Carbonsäure‐imidazolide

1963 • 32 citations

Preparation and Properties of Esters of N-Substituted Peroxycarbamic Acids

1958 • 32 citations

Electron Spin Resonance of Tropenyl Radical¹

1965 • 32 citations

The Thermal Decomposition of t-Butyl 2,5-Dioxo-1-pyrrolidineperformate

1964 • 31 citations

Quantitative Bestimmung organischer Perverbindungen in Gemischen

1958 • 30 citations

Radikalumlagerungen, VII: Relative Wanderungsgeschwindigkeiten substituierter Phenylreste beim thermischen Zerfall von β‐Aryl‐perisovaleriansäure‐tert.‐butylestern

1965 • 29 citations

The Roles of the Potential Anions in the Rearrangements of trans-9-Decalyl Hydroperoxide Benzoate and p-Methoxy-p″-nitrobenzyl Peroxide¹

1957 • 29 citations

Anchimerically Accelerated Bond Homolysis. III.¹ Polar and Geometric Factors Influencing the Radical Decomposition of t-Butyl o-Phenylthioperbenzoate

1963 • 27 citations

Mehrfunktionelle peroxyde als initiatoren der vinylpolymerisation. 424. Mitteilung über makromolekulare verbindungen

1955 • 26 citations

Autoxydation von Kohlenwasserstoffen, XX. Mitteil.¹⁾: Methylierte Hydroperoxyde und sonstige Derivate

1955 • 25 citations

Stability of the Succinimidyl Radical. Decomposition of t-Butyl N-Succinimidepercarboxylate

1964 • 25 citations

Silver-Catalyzed Decomposition of Hypobromites

1965 • 25 citations

A New Insertion Reaction of Cationic Oxygen

1964 • 25 citations

A Study of the Induced Decomposition of Benzoyl Peroxide in Diethyl Ether

1959 • 24 citations

The Kinetics of the Thermal Decomposition of Peresters. I. The Effect of Perbenzoate Concentration on the Decomposition of t-Butyl Perbenzoate¹

1951 • 24 citations

Peresters. VI.¹ Ethyl, Benzyl, p-Nitrobenzyl and p-Methoxybenzyl t-Butyl-peroxyoxalates

1960 • 24 citations

Peroxides. VIII.² X-Ray Diffraction and Polarographic Study of t-Butyl Peresters and Diacyl Peroxides of Aliphatic Monobasic Acids³

1959 • 24 citations

The Thermal Decomposition of 2-Phenoxybenzoyl Peroxide

1955 • 24 citations

The Kinetics of the Thermal Decomposition of Peresters. II. The Effect of Solvent and Strong Acid on the Decomposition of t-Butyl Perbenzoate¹

1951 • 23 citations

Die Perester‐Reaktion

1964 • 20 citations

Bimolecular Reactions in Frozen Organic Solutions¹

1965 • 20 citations

Cyclic Polyolefins. VIII. Reactions of 6-Hydroxycyclodecanone and Cyclodecan-1,6-diol p-Toluenesulfonates

1950 • 19 citations

Über ein Peroxyd des Hydrindans und seine Umwandlungen

1951 • 19 citations

The Decomposition of Peroxycarbamates and their Efficiency as Initiators in Vinyl Polymerization^1,2

1957 • 19 citations

Peresters. VII. t-Butylperoxyesters of exo- and endo-2-Norbornanecarboxylic Acids

1962 • 18 citations

A Kinetic Study of the Rearrangement of Some Benzoates of 9-Decalyl Hydroperoxide

1953 • 18 citations

The Solvolysis of Acid Chlorides with t-Alkyl Hydroperoxides¹

1964 • 18 citations

Ionic Fission of the O-O Bond in t-Butyl Arylpersulfonates¹

1958 • 17 citations

A Free-Radical 1,2-Vinyl Migration

1965 • 17 citations

Peresters. VIII. Di-tert-butyl Monoperoxyoxalate

1962 • 17 citations

Peresters. X. tert-Butylperoxy Chloroformate

1963 • 16 citations

The Oxidation of Hydrocarbons. I. The Oxidation of Cyclohexene in Acetic and Propionic Anhydride Solutions¹

1958 • 16 citations

Neue Tieftemperatur‐Initiatoren

1966 • 16 citations

Anchimerically Accelerated Bond Homolysis. IV.¹ Participation of a Neighboring Olefinic Double Bond in the Decomposition of a t-Butyl Perester

1964 • 15 citations

372. Organic peroxides. Part II. Esters of the monopercarbonic acids

1953 • 14 citations

Radikalumlagerungen, VI: Zur Frage der Nachbargruppenbeteiligung beim Peresterzerfall

1965 • 14 citations

Anchimerically Accelerated Bond Homolysis. V.¹ Decomposition of an Oxygen-18 Labeled t-Butyl Perester

1964 • 14 citations

Studies in Organic Peroxides. XXII. The Thermal Decomposition of t-Butylperoxy Isobutyrate

1958 • 13 citations

Comparative Rates of Homolysis of exo and endo Bonds in Norbornane and Norbornene Systems

1962 • 13 citations

CATIONIC DISPLACEMENT OF HYDROGEN BY OXYGEN AT A SATURATED CARBON ATOM

1958 • 12 citations

Säurekatalysierte Fragmentierung von Norcaradien‐per‐carbonsäure‐tert.‐butylester Ein neuartiger Peresterzerfall

1962 • 12 citations

DECOMPOSITION OF n- AND sec-BUTYL PEROXYACETATE¹

1960 • 12 citations

Isolierung von Benzoyl‐Radikalen

1965 • 12 citations

Notiz über die Umsetzung von Isocyansäureestern mit Wasserstoffperoxyd

1956 • 12 citations

Notes- The Structure of the Crystalline Peroxide Formed in the Oxidation of Acetaldehyde

1961 • 11 citations

A Study of the Mechanism of the Reaction of t-Alkyl Peresters with Trisubstituted Phosphines¹

1961 • 11 citations

Studies in Organic Peroxides. XXX. Organic Peroxides Derived from 2,5-Hexanedione and Hydrogen Peroxide^1a

1962 • 11 citations

The Decomposition of Peresters. I. t-Butyl Esters of Long-chain Aliphatic Percarboxylic Acids in Several Solvents

1962 • 10 citations

Ionic decomposition of 2-alkoxy-2-propyl per-p-nitrobenzoates baeyer-villiger-type reactions of a ketal and an orthoester

1962 • 10 citations

Peresters. IX. Di-t-butyl Monoperoxycarbonate

1962 • 10 citations

The Rearrangement of trans-9-Decalyl Perbenzoate and Per-p-nitrobenzoate in Methanol and Aqueous Methanol

1953 • 9 citations

THE MECHANISMS OF SOME PEROXIDE REACTIONS

1960 • 9 citations

Some Decomposition and Rearrangement Products of Decahydronaphthalene Hydroperoxide

1956 • 9 citations

The C—Br bond dissociation energy in substituted benzyl bromides

1951 • 9 citations

Zur Autoxydation mehrkerniger, partiell hydrierter Aromaten, III. Die Autoxydation der hydrierten Pyrene, insbesondere des 1.2.3.4.5.8.9.10.11.16‐Dekahydro‐pyrens, und die Ringspaltung mehrkerniger Hydroperoxyde zu Makrocyclen mit in meta‐Stellung eingebautem Benzolkern

1958 • 9 citations

Thermal Decomposition of t-Butyl 3,3,3-Triarylperpropionates. Evidence for the Intramolecular Rearrangement and Cyclization of Aliphatic Acyloxy Radicals

1963 • 9 citations

Organische Peroxyde, I. Mitteil.: Propyl‐ und Isopropyl‐hydroperoxyd

1932 • 8 citations

tert-Butyl Peroxyformate. A Highly Stable Peroxide and a New Form of Induced Peroxide Decomposition

1962 • 7 citations

Products and Rates of Decomposition of Some t-Butyl Perthenoates

1965 • 7 citations

Über Barium‐methylperoxyd (V. Mitteil. über Alkylperoxyde)

1930 • 7 citations

Notiz zur Darstellung von tert.‐Butyl‐performiat

1964 • 7 citations

Peroxy-phosphorsäureester I. Diäthyl-tert.-butylperoxyphosphat

1959 • 7 citations

Zur Autoxydation mehrkerniger, partiell hydrierter Aromaten, IV. Die Autoxydation des Hexahydrophenalins und die Überführung seines tertiären Hydroperoxyds in 2.6‐Heptamethylen‐phenol

1961 • 7 citations

66. The behaviour of keten towards olefins and olefinic peroxides

1945 • 5 citations

The Mechanism of the Thermal Decomposition of Di-t-butyl Diperoxycarbonate

1961 • 5 citations

Effects of Nonpolar Solvents on an Ionic Reaction. II. Catalyst Basicity, Activation Parameters, Salt Effects, and Deuterium Isotope Effects in the Ionic Decomposition of t-Butylperoxy Formate

1965 • 5 citations

Radikalumlagerungen - VI zur frage der nachbargruppenbeteiligung beim peresterzerfall

1962 • 4 citations

The Course of Acid-catalyzed Rearrangement of Phenylcyclohexane Hydroperoxide and its Derivatives; Observations on the Properties and Oxidation of 6-Hydroxyhexanophenone

1959 • 4 citations

The Mechanism of the Decompositions of t-Butyl 3-Phenylperpropionate and t-Butyl 4-Phenylperbutyrate

1962 • 4 citations

Dipole Moments of t-Butylperphthalic Acid and Di-t-butyldiperphthalate

1954 • 4 citations

Deuterium isotope effects in the decompositions of acetyl peroxide and two -butyl peresters

1965 • 3 citations

The detection of organic peroxides

1961 • 3 citations

Gesellschaft Deutscher Chemiker

1962 • 1 citations

Die Criegee‐Umlagerung von α‐Ketonhydroperoxyestern

1963 • 1 citations