Mechanisms of flavin catalysis

Chemiluminescence of organic peroxides. Conversion of ground-state reactants to excited-state products by the chemically initiated electron-exchange luminescence mechanism

1979 • 384 citations

Rates of Ionization of Pseudo Acids.¹ IV. Relation between Rates and Equilibria

1953 • 374 citations

Flavin-oxygen derivatives involved in hydroxylation by p-hydroxybenzoate hydroxylase.

1976 • 330 citations

フラビン補酵素生物学的酸化-還元化学の交差点

1980 • 255 citations

Crystal structure of p-hydroxybenzoate hydroxylase

1979 • 188 citations

The oxidation of reduced flavin mononucleotide by molecular oxygen

1962 • 185 citations

Ligated chlorophyll cation radicals: Their function in photosystem II of plant photosynthesis

1979 • 157 citations

Simple synthesis of a 4a-hydroperoxy adduct of a 1,5-dihydroflavine: preliminary studies of a model for bacterial luciferase.

1976 • 143 citations

Redox chemistry of dioxygen species

1979 • 142 citations

The molybdenum site of xanthine oxidase. Structural evidence from x-ray absorption spectroscopy

1979 • 106 citations

On the Structure of Flavin‐Oxygen Intermediates Involved in Enzymatic Reactions

1977 • 104 citations

The molybdenum site of sulfite oxidase. Structural information from x-ray absorption spectroscopy

1979 • 92 citations

Flash photolysis of flavins. V. Oxidation and Disproportionation of flavin radicals

1971 • 91 citations

Studies on the Mechanism of Action of the Flavoenzyme Lactate Oxidase

1973 • 88 citations

A postulated mechanism for the bioluminescent oxidation of reduced flavin mononucleotide

1972 • 85 citations

Photo-induced Benzyl Substitution of Flavins by Phenylacetate: a Possible Model for Flavoprotein Catalysis

1967 • 80 citations

Oxidation of thiophenol and nitroalkanes by an electron deficient isoalloxazine

1975 • 77 citations

Bacterial bioluminescence - identification of fatty acid as product, its quantum yield and a suggested mechanism

1973 • 71 citations

Chemiluminescent reactions and electrophilic oxygen donating ability of 4a-hydroperoxyflavins: general synthetic method for the preparation of N5-alkyl-1,5-dihydroflavins.

1977 • 67 citations

Spectral evidence for a flavin adduct in a monoalkylated derivative of pig heart lipoamide dehydrogenase.

1976 • 65 citations

4a-Hydroperoxyflavin N-oxidation of tertiary amines

1979 • 60 citations

Oxaziridines as Possible Intermediates in Flavin Monooxygenases

1974 • 48 citations

Studies on the reaction mechanism of lactate oxidase. Formation of two covalent flavin-substrate adducts on reaction with glycollate.

1980 • 47 citations

Studies on the mechanism of action of the flavoenzyme lactate oxidase. Proton uptake and release during the binding of transition state analogs.

1977 • 46 citations

Use of heterocyclic compounds as photosensitisers for the decarboxylation of carboxylic acids

1973 • 41 citations

The kinetics and mechanisms of 1,5-dihydroflavin reduction of carbonyl compounds and flavin oxidation of alcohols. 2. Ethyl pyruvate, pyruvamide, and pyruvic acid

1976 • 34 citations

Chemiluminescence accompanying the decomposition of 4a-flavin alkyl peroxide. Model studies of bacterial luciferase

1977 • 33 citations

O₂‐affinity of flavin radical species as studied by pulse radiolysis

1975 • 31 citations

Mechanism of the photoinduced decarboxylation of carboxylic acids sensitised by aromatic ketones and quinones

1972 • 31 citations

The mechanism of flavin 4a substitution which accompanies photolytic decarboxylation of .alpha.-substituted acetic acids. Carbanion vs. radical intermediates

1980 • 30 citations

Importance of 1,2-enediols in the reduction of lumiflavin by .alpha.-ketols

1974 • 29 citations

Kinetics and mechanisms of the 1,5-dihydroflavin reduction of carbonyl compounds and the flavin oxidation of alcohols. 4. Interconversion of formaldehyde and methanol

1977 • 29 citations

Question of covalent intermediate formation in the flavine-catalyzed carbonyl to carbinol oxidation-reduction reaction

1973 • 28 citations

Transfer of oxygen from a 4a-hydroperoxyflavin anion to a phenolate ion. A flavin-catalyzed dioxygenation reaction

1979 • 25 citations

Detection and trapping of a chemiluminescent o-xylylene peroxide. Chemical light formation along two separate paths

1978 • 24 citations

Stereochemical analysis of the elimination reaction catalyzed by D-amino-acid oxidase

1976 • 22 citations

Kinetics and mechanism of the isoalloxazine (flavine) dehydrogenation of dimethyl dihydrophthalates

1972 • 21 citations

A proposed symmetry forbidden oxidation mechanism for the bacterial luciferase catalyzed reaction

1976 • 20 citations

Metabolism and enzymology of fluorosuccinic acids

1970 • 19 citations

Reactions of 4a-peroxides and 4a-pseudobases of N10- and N5-phenethylflavins

1980 • 19 citations

The kinetics and mechanisms of 1,5-dihydroflavin reduction of carbonyl compounds and flavin oxidation of alcohols. 3. Oxidation of benzoin by flavin and reduction of benzil by 1,5-dihydroflavin

1976 • 18 citations

On the mechanism of oxygen activation by tetrahydropterin and dihydroflavin-dependent monooxygenases

1977 • 18 citations

Carbanions. Electron transfer vs. proton capture. 4. Products of base-catalyzed reactions of various 9-substituted fluorenes with aromatic nitro compounds

1976 • 15 citations

Oxidation of 9-hydroxy- and 9-methoxyfluorene carbanions by flavin. Proof of radical mechanism

1977 • 15 citations

Importance of C^4a-and N⁵-covalent adducts in the flavin oxidation of carbanions

1978 • 12 citations

THE ROLE OF DIOXYGEN SPECIES IN THE BASE‐ AND COBALT‐CATALYZED OXYGENATION OF HINDERED PHENOLS

1978 • 10 citations

Kinetic study of the fate of a covalent intermediate of the type proposed to be involved in flavin catalysis

1974 • 8 citations

Mechanistic investigation of the oxidation of the carbanion of methyl 2-methoxy-2-phenylacetate by an isoalloxazine

1980 • 6 citations

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