Bare transition metal atoms in the gas phase: reactions of M, M+, and M2+ with hydrocarbons

586. Olefin co-ordination compounds. Part III. Infra-red spectra and structure: attempted preparation of acetylene complexes

1953 • 1,604 citations

Organometallic chemistry in the gas phase

1991 • 840 citations

Transition metal-hydrogen and metal-carbon bond strengths: the keys to catalysis

1990 • 723 citations

Carbon-hydrogen and hydrogen-hydrogen activation in transition metal complexes and on surfaces

1984 • 589 citations

Carbon-hydrogen activation in completely saturated hydrocarbons: direct observation of M + R-H .fwdarw. M(R)(H)

1982 • 581 citations

Oxidative addition of the carbon-hydrogen bonds of neopentane and cyclohexane to a photochemically generated iridium(I) complex

1982 • 399 citations

Activation of carbon-hydrogen bonds in saturated hydrocarbons on photolysis of (.eta.5-C5Me5)(PMe3)IrH2. Relative rates of reaction of the intermediate with different types of carbon-hydrogen bonds and functionalization of the metal-bound alkyl groups

1983 • 372 citations

Electronic State-Specific Transition Metal ION Chemistry

1990 • 276 citations

Activation of methane by iridium complexes

1983 • 229 citations

Reaction mechanisms and thermochemistry of vanadium ions with ethane, ethene and ethyne

1986 • 192 citations

AB Initio Studies of Transition Metal Systems

1988 • 180 citations

Methane oligomerization in the gas phase by third-row transition-metal ions

1991 • 168 citations

Reductive coupling of hydrogen-hydrogen, hydrogen-carbon, and carbon-carbon bonds from palladium complexes

1984 • 157 citations

Theoretical study of the activation of alkane carbon-hydrogen and carbon-carbon bonds by different transition metals

1991 • 150 citations

Mechanisms for the reactions between methane and the neutral transition metal atoms from yttrium to palladium

1992 • 146 citations

Electronic effects in C-H and C-C bond activation. State-specific reactions of FE+ (6D,4F) with methane, ethane, and propane

1988 • 130 citations

Multicollision chemistry of gas-phase transition-metal ions with small alkanes: rate constants and product branching at 0.75 torr of helium

1988 • 127 citations

State-specific reactions of atomic transition-metal ions with molecular hydrogen, hydrogen deuteride, and molecular deuterium: effects of d orbitals on chemistry

1987 • 113 citations

Transition-metal ion mediated carbon-hydrogen and carbon-carbon bond activation of alkanes: dynamical coupling between entrance and exit channel transition states

1991 • 95 citations

Gas‐phase chemistry and photochemistry of doubly charged transition‐metal–containing ions

1991 • 95 citations

Relationships between bond energies in coordinatively unsaturated and coordinatively saturated transition-metal complexes: a quantitative guide for single, double, and triple bonds

1988 • 94 citations

Reactions of gas phase dipositive titanium ions with alkanes

1986 • 91 citations

Formation of thermodynamically stable dications in the gas phase by thermal ion-molecule reactions: tantalum(2+) and zirconium(2+) with small alkanes

1991 • 87 citations

Room temperature generation of reactive intermediates Cp*Zr:O and Cp*2Zr:S: trapping reactions with unsaturated organic molecules and dative ligands

1990 • 77 citations

Reactivity, photochemistry and thermochemistry of simple metal—ligand ions in the gas phase

1988 • 75 citations

Reactivity of neutral iron, cobalt, nickel, and copper atoms with linear alkanes and alkenes in the gas phase

1990 • 68 citations

Singlet and triplet potential surfaces for the nickel-ethylene [Ni(C2H4)] complex. A CASSCF-CI study

1985 • 61 citations

Transition-metal cation chemistry in 1 torr of helium: M+ + ethane reaction rates

1986 • 44 citations

Formation of thermodynamically stable dications in the gas phase by thermal ion–molecule reactions: Nb2+ with small alkanes

1989 • 40 citations

Nonadiabatic behavior of a transition metal system: exothermic reactions of iron(1+)(6D,4F) and propane

1987 • 40 citations

Atomic rhodium and niobium insertion into the carbon-hydrogen bond of methane

1991 • 33 citations

Excited state-selected transition metal cations from one-color UV multiphoton ionization

1986 • 29 citations

Resonant two photon ionization of V atoms: V+ electronic state distributions and J-resolved photoelectron angular distributions

1990 • 24 citations

Electronic-state-specific transition metal cation chemistry: Fe++C3H8 and n-C4H1

1992 • 19 citations