Reactivity, photochemistry and thermochemistry of simple metal—ligand ions in the gas phase

Fourier transform ion cyclotron resonance spectroscopy

1974 • 1,008 citations

Proton affinities from dissociations of proton-bound dimers

1981 • 410 citations

Frequency-sweep fourier transform ion cyclotron resonance spectroscopy

1974 • 368 citations

Intrinsic basicity determination using metastable ions

1977 • 329 citations

Relative metal-hydrogen, -oxygen, -nitrogen, and -carbon bond strengths for organoruthenium and organoplatinum compounds; equilibrium studies of Cp*(PMe3)2RuX and (DPPE)MePtX systems

1987 • 320 citations

Fourier transform ion cyclotron resonance mass spectrometry

1985 • 317 citations

Reactions of atomic metal ions with alkyl halides and alcohols in the gas phase

1979 • 177 citations

Fourier transform ion cyclotron double resonance

1978 • 171 citations

Investigation of reactions of metal ions and their clusters in the gas phase by laser-ionization fourier-transform mass spectrometry

1985 • 152 citations

Gas-phase photodissociation of organometallic ions. Bond energy and structure determinations

1986 • 144 citations

Collision-induced dissociation in a fourier-transform mass spectrometer

1982 • 139 citations

Periodic trends in transition metal-hydrogen, metal-carbon, and metal-oxygen bond dissociation energies. Correlation with reactivity and electronic structure

1981 • 137 citations

Pulsed valve addition of collision and reagent gases in Fourier transform mass spectrometry

1983 • 135 citations

Laser ionization source for ion cyclotron resonance spectroscopy. Application to atomic metal ion chemistry

1980 • 126 citations

Pulsed laser evaporation and ionization of solid metal targets. Implications for studying the gas-phase reactions of laser-generated atoms and ions

1985 • 125 citations

Ion beam studies of the reactions of atomic cobalt ions with alkanes: determination of metal-hydrogen and metal-carbon bond energies and an examination of the mechanism by which transition metals cleave carbon-carbon bonds

1981 • 116 citations

On the mechanism of Fe+-induced hydrogen migrations in gaseous octyne/iron(I) complexes

1987 • 109 citations

Gas-phase reactions of iron(1+) with ketones and ethers

1981 • 104 citations

Selective-phase Ion Cyclotron Resonance Spectroscopy

1974 • 102 citations

Cleavage of alkanes by transition metal ions in the gas phase

1979 • 102 citations

Fourier transform mass spectrometry: Recent instrumental developments and applications

1986 • 102 citations

Gas-phase reactions of oxoiron(1+) ion (FeO+) with hydrocarbons

1984 • 87 citations

Gas-phase photodissociation of FeCH2+ and CoCH2+: determination of the carbide, carbyne, and carbene bond energies

1986 • 82 citations

Transition-metal hydride bond energies: first and second row

1986 • 80 citations

Ion beam studies of the reactions of Group VIII metal ions with alkanes: correlation of thermochemical properties and reactivity

1982 • 80 citations

Gas-phase reactions of yttrium and lanthanum ions with alkanes by Fourier transform mass spectrometry

1987 • 73 citations

Bond energy-bond order relations in transition-metal bonds: vanadium

1984 • 73 citations

Endothermic reactions of uranium ions with N2, D2, and CD4

1977 • 72 citations

Mechanism of the reaction of gas-phase iron ions with neutral olefins

1984 • 68 citations

Relative binding energies of organic molecules to aluminum(+) ion in the gas phase

1982 • 68 citations

Heteronuclear diatomic transition-metal cluster ions in the gas phase. The bond energy of FeCo+

1984 • 66 citations

Cobalt carbene ion: Reactions of Co+ with C2H4, cyclo-C3H6, and cyclo-C2H4O

1981 • 64 citations

Activation of carbon-hydrogen and carbon-carbon bonds in alkanes by first-row Group VIII atomic transition-metal ions in the gas-phase. Mechanistic details from a study of deuterium and 13C-labeled hydrocarbons

1983 • 64 citations

Gas-phase reactions of Group VIII metal hydride ions (FeD+, CoD+, and NiD+) with hydrocarbons

1983 • 63 citations

Gas-phase reactions of vanadium ion (V+) and vanadyl ion (VO+) with hydrocarbons using Fourier transform mass spectrometry

1986 • 60 citations

Silver ion affinities of alcohols as ordered by mass spectrometry/mass spectrometry

1982 • 60 citations

Dinuclear polyhydrides of rhenium: isolation and characterization of diamagnetic and paramagnetic complexes containing the octahydrodirhenium(n+) ([Re2H8]n+), heptahydrodirhenium((n + 1)+) ([Re2H7](n+1)+), and pentahydrodirhenium((n + 1)+) ([Re2H5](n+1)+) cores (n = 0 or 1) stabilized by phosphine, nitrile, and isocyanide ligands

1984 • 60 citations

Generation and reaction of atomic metal anions in the gas phase. Determination of the heterolytic and homolytic bond energies for the vanadium, chromium, iron, cobalt, and molybdenum hydrides VH, CrH, FeH, CoH, and MoH

1985 • 57 citations

Gas phase studies of Zn+2, Ag+3, and Ag+5

1988 • 57 citations

Quantitative metal-ligand bond dissociation energies in the gas phase by ion cyclotron resonance spectroscopy

1976 • 55 citations

Gas-phase reactions of rhodium(+) ion with alkanes

1982 • 55 citations

The chemistry of first-row transition-metal ions with primary amines in the gas phase: correlations of reactivity with electronic structure

1984 • 53 citations

Reactions of methyliron(1+) and methylcobalt(1+) ions with cyclic hydrocarbons in the gas phase

1984 • 53 citations

Does ground state Fe+ (iron(1+)) react with hydrogen?

1986 • 53 citations

Reactions of iron(1+) ion and (olefin)iron(1+) ion complexes with alkenes in the gas phase using Fourier transform mass spectrometry

1983 • 52 citations

Thermochemical properties of gaseous FeO and FeOH

1980 • 51 citations

Neutral and ionic metal methyl bond energies: zinc

1986 • 50 citations

Nickel ions effect a highly specific 1,4-dehydrogenation of hydrocarbons in the gas phase: metallacycles are not involved

1982 • 49 citations

Determination of the iron(1+) ion-hydroxyl and cobalt(1+) ion-hydroxyl bond energies by deprotonation reactions and by photodissociation

1984 • 49 citations

Parallels in the formation of transition metal-amide bonds in solution and in the gas phase: an ion cyclotron resonance study of cobalt ion chemistry with amines

1984 • 47 citations

Ion-beam studies of the reactions of atomic cobalt ions with alkenes

1981 • 47 citations

Carbon-hydrogen bond dissociation energies in alkylbenzenes. Proton affinities of the radicals and the absolute proton affinity scale

1982 • 47 citations

Transition-metal cation chemistry in 1 torr of helium: M+ + ethane reaction rates

1986 • 44 citations

Reactions of the metal carbenes FeCH2+ and CoCH2+ with olefins in the gas phase. Studies involving olefin metathesis

1985 • 44 citations

Structural determination of NiCnH2n+ ions in the gas phase using Fourier-transform mass spectrometry collision-induced dissociation

1983 • 43 citations

Reactions of CoCp+ (Cp = cyclopentadienyl) with hydrocarbons in the gas phase. Observation of novel skeletal isomerizations/dehydrocyclizations resulting in cobaltocenium formation

1985 • 43 citations

Generation of transition-metal polysulfide ions in the gas phase by sequential reactions of metal ions with ethylene sulfide

1981 • 42 citations

Determination of carbide, carbyne, and carbene bond energies by gas-phase photodissociation of RhCH2+, NbCH2+, and LaCH2+

1987 • 42 citations

Gas-phase reactions of MS+ ions (M = Fe, Co, Ni) with alkanes. An FTMS study

1986 • 42 citations

Generation and decomposition of Group VIII metal (iron, cobalt, nickel) ion metallacycles in the gas phase

1984 • 42 citations

Dynamics of monoolefin-metal ion complexes in the gas phase. Determination of the number of labile .beta.-hydrogens by reaction with ethene-d4

1985 • 40 citations

Formation, chemistry, and thermochemistry of primary amide complexes of iron(I) and cobalt(I) in the gas phase

1987 • 39 citations

Experimental and theoretical studies of the reaction Ba+(D2, D)BaD+: sequential impulse model for endothermic reactions

1980 • 38 citations

Bimolecular reactions of doubly charged metal ions in the gas phase. Formation of NbCH22+

1987 • 36 citations

Transition-metal-carbene chemistry. Structure, thermodynamics, and reactivity of rhodium methylidene ion (RhCH2+) in the gas phase

1985 • 35 citations

Reactions of methyliron(1+) and methylcobalt(1+) ions with aliphatic alkanes in the gas phase

1984 • 33 citations

Heteronuclear triatomic transition metal cluster ions in the gas phase. Activation of carbon-hydrogen bonds in alkanes by iron-cobalt(1+) ion (FeCo2+)

1984 • 32 citations

Reactions of iron carbene (FeCH2+) and cobalt carbene (CoCH2+) with cyclic alkanes in the gas phase

1985 • 32 citations

Study of endothermic reactions involving transition metal ions: The FTMS analogy of the ion-beam experiment

1987 • 29 citations

Theoretical and experimental study of the low energy ionic states of π-cyclopentadienylnickel nitrosyl

1974 • 28 citations

Chemistry of cobalt(1+) and Co(ligand)n+ with mono- and bi-substituted n-butanes in the gas phase: using a simple "ligand competition" model and collision-induced dissociation analysis to provide insights into product structures

1984 • 27 citations

Reactions of the iron and cobalt carbenes FeCH2+ and CoCH2+ with aliphatic alkanes in the gas phase. Activation of carbon-hydrogen and carbon-carbon bonds by naked transition-metal carbene ions

1985 • 25 citations

Activation of allylic carbon-carbon bonds by gas-phase copper(I)

1987 • 24 citations

Mechanism and energetics of the ligand-induced reductive elimination of hydrogen from a binuclear platinum hydride

1983 • 22 citations

Gas-phase reactions of cobalt(1+) and rhodium(1+) with toluene, cycloheptatriene, and norbornadiene

1984 • 20 citations

The kinetic energy dependence of ion/molecule collisions studied by FT-ICR spectrometry

1986 • 19 citations

Reactions of methyliron(1+) (MeFe+) and methylcobalt(1+) (MeCo+) with aliphatic alkenes and alkynes in the gas phase

1985 • 16 citations

Reactions of FeOH+ and CoOH+ with alkanes in the gas phase

1986 • 14 citations

Gas-phase photodissociation of (.eta.5-cyclopentadienyl)nitrosylnickel(1+) ion

1979 • 13 citations

Hydrogenation of the rhodium complex RhC7H6+ in the gas phase

1984 • 10 citations

Positive-ion chemistry of cyclopentadienylcobalt dicarbonyl

1981 • 6 citations