The Structure and Reactivity of Organo-Phosphorus Compounds

The Infra-red Spectra of Complex Molecules

1975 • 5,475 citations

THE ATOM AND THE MOLECULE.

1916 • 1,594 citations

The Spectra and Electronic Structure of the Tetrahedral Ions MnO4−, CrO4−−, and ClO4−

1952 • 1,468 citations

The Utility of Phosphonate Carbanions in Olefin Synthesis

1961 • 1,326 citations

Phosphorus and its compounds

1958 • 1,074 citations

Über Triphenyl‐phosphin‐methylene als olefinbildende Reagenzien (I. Mitteil.

1954 • 966 citations

The relative affinities of ligand atoms for acceptor molecules and ions

1958 • 887 citations

The infrared spectra of complex molecules

1955 • 882 citations

The Factors Determining Nucleophilic Reactivities

1962 • 677 citations

Zur Reaktionsweise des Pentaphenyl‐phosphors und einiger Derivate

1953 • 651 citations

Mechanisms of Catalysis of Nucleophilic Reactions of Carboxylic Acid Derivatives.

1960 • 606 citations

Quantitative Correlation of Relative Rates. Comparison of Hydroxide Ion with Other Nucleophilic Reagents toward Alkyl Halides, Esters, Epoxides and Acyl Halides¹

1953 • 606 citations

Some Revisions of the Covalent Radii and the Additivity Rule for the Lengths of Partially Ionic Single Covalent Bonds^*

1941 • 555 citations

Ligand-field theory

1957 • 456 citations

1077. The rôle of 3d-orbitals in π-bonds between (a) silicon, phosphorus, sulphur, or chlorine and (b) oxygen or nitrogen

1961 • 376 citations

HEXAPHENYLCARBODIPHOSPHORANE, (C₆H₅)₃PCP(C₆H₅)₃

1961 • 370 citations

Phosphinemethylenes.¹ II. Triphenylphosphineacylmethylenes

1957 • 369 citations

Bond Energies and Polarities¹

1953 • 356 citations

CARBAMYL PHOSPHATE, THE CARBAMYL DONOR IN ENZYMATIC CITRULLINE SYNTHESIS¹

1955 • 349 citations

Correlation of Relative Rates and Equilibria with a Double Basicity Scale

1954 • 307 citations

The Basicity of Phosphines

1960 • 306 citations

Repulsive Forces in Relation to Bond Energies, Distances and Other Properties

1948 • 258 citations

Principles of Phosphorus Chemistry. II. Nuclear Magnetic Resonance Measurements¹

1956 • 236 citations

HCP, A UNIQUE PHOSPHORUS COMPOUND

1961 • 231 citations

Directed Valence

1940 • 215 citations

Neuere präparative Methoden der organischen Chemie II 13. Carbonyl-Olefinierung mit Triphenyl-phosphin-methylenen Wittig-Reaktion

1959 • 205 citations

Chemical bonds involving d-orbitals. Part I

1954 • 197 citations

The Lanthanum Hydroxide Gel Promoted Hydrolysis of Phosphate Esters

1955 • 181 citations

Darstellung und chemisches Verhalten aliphatischer und cycloaliphatischer Diphosphine, R₂PPR₂

1959 • 174 citations

490. The structure of the phosphonitrilic halides

1960 • 161 citations

A Linear Phosphoryl Absorption Relationship

1954 • 153 citations

Chemical effects of steric strains

1956 • 152 citations

Phosphororganische verbindungen optisch aktive tertiäre phosphine aus optisch aktiven quartären phosphoniumsalzen

1961 • 146 citations

Hydrolysis and Exchange in Esters of Phosphoric Acid^1a,b

1961 • 145 citations

Ultraviolet Absorption Spectra of Some Inorganic Ions in Aqueous Solutions

1954 • 143 citations

Darstellung und Eigenschaften des Pentaphenyl‐phosphors

1949 • 131 citations

716. The reactions of organic phosphates. Part I. The hydrolysis of methyl dihydrogen phosphate

1958 • 122 citations

Autoxidation of Trialkylphosphines

1962 • 122 citations

Barium Ethylene Phosphate

1956 • 119 citations

d-Orbital Resonance. III. Deuterium Exchange in Methyl “Onium” Salts and in Bicyclo [2.2.1]heptane-1-sulfonium Iodide¹

1955 • 118 citations

Studies in Molecular Orbital Theory of Valence. III. Multiple Bonds Involving d-Orbitals

1954 • 115 citations

KINETIC STUDY OF THE DECOMPOSITION OF QUATERNARY PHOSPHONIUM HYDROXIDES

1959 • 114 citations

Interatomic Distances and Bond Character in the Oxygen Acids and Related Substances

1952 • 111 citations

Acceleration of the Hydrolysis of Organic Fluorophosphates and Fluorophosphonates with Hydroxamic Acids

1955 • 108 citations

Die Reduktion organischer Peroxyde mit tertiären Phosphinen Tertiäre Phosphine VI

1955 • 106 citations

Some Overlap Integrals Involving d Orbitals

1953 • 101 citations

Conjugation in sulphones

1951 • 100 citations

Phosphonium Compounds. II. Decomposition of Phosphonium Alkoxides to Hydrocarbon, Ether and Phosphine Oxide

1960 • 97 citations

Phosphinemethylenes. I. Triphenylphosphoniumcyclopentadienylide

1957 • 94 citations

The Adjacent Charge Rule and the Structure of Methyl Azide, Methyl Nitrate, and Fluorine Nitrate

1937 • 93 citations

Zur Kenntnis der Organophosphorverbindungen, I. Das Tetraphenyl‐cyclo‐tetraphosphin

1958 • 91 citations

Optisch‐aktive Phosphinoxyde

1926 • 86 citations

465. Studies on phosphorylation. Part XI. The reaction between carbodi-imides and acid esters of phosphoric acid. A new method for the preparation of pyrophosphates

1953 • 85 citations

756. The reaction of oximes with isopropyl methylphosphono-fluoridate (Sarin)

1956 • 85 citations

CCCVII.—Influence of poles and polar linkings on the course pursued by elimination reactions. Part V. The mechanism of thermal decomposition of quaternary phosphonium hydroxides

1929 • 83 citations

Imidoester, I. Darstellung von Trichloracetimidsäureestern

1958 • 80 citations

The Acid Dissociation Constants of Aromatic Phosphonic Acids. I. Meta and Para Substituted Compounds¹

1953 • 80 citations

Intermolecular Hydrogen Bond Association between Phenol and Organophosphorus Compounds.

1960 • 79 citations

Electronic Absorption Spectra of Benzene and Its Derivatives

1942 • 78 citations

The Effect of Structure on the Reactivity of Alkylphosphonate Esters^1,2

1959 • 76 citations

955. d-Orbital contraction in chemical bonding

1956 • 75 citations

Neue Phosphors�ureester mit pupillenverengender Wirkung

1952 • 72 citations

38. An investigation of the occurrence of the co-ordinate or dative link by electric dipole-moment measurements

1945 • 71 citations

315. The infra-red spectra of organo-phosphorus compounds. Part II. Esters, acids, and amines

1952 • 69 citations

CRYSTALLINE 1:1 ADDUCTS FROM THE REACTION OF TERTIARY PHOSPHITE ESTERS WITH ortho-QUINONES AND WITH alpha-DIKETONES. NEW ROUTES TO QUINOL-MONOPHOSPHATES AND TO KETOL-MONOPHOSPHATES¹

1960 • 68 citations

Abwandlung der Phosphylen‐Methodik; zugleich III. Mitteil. über Phosphin‐alkylene als olefinbildende Reagenzien

1961 • 67 citations

The nature of the sulphur-oxygen bond

1950 • 66 citations

The Alkaline Hydrolysis of isoPropoxy-methyl-phosphoryl Fluoride (Sarin) and some Analogues.

1957 • 65 citations

316. The reactivity of some active nucleophilic reagents with organophosphorus anticholinesterases

1958 • 65 citations

Oxidative Phosphorylation: A Chemical Approach Using Quinol Phosphates

1958 • 63 citations

The Ultraviolet Absorption Spectra of Arylphosphonic and Diarylphosphinic Acids

1952 • 62 citations

New Compounds. Derivatives of Fluorene

1947 • 62 citations

The Preparation of Tetraethyl Pyrophosphate and Other Tetraalkyl Pyrophosphates

1948 • 59 citations

Über optisch‐aktive Verbindungen des Phosphors

1911 • 59 citations

SOME ASPECTS OF PHOSPHATE CHEMISTRY

1959 • 58 citations

477. The hydrolysis of phosphonate esters

1956 • 56 citations

Principles of Phosphorus Chemistry. I. Some Generalities Concerning Multiple Bonding¹

1956 • 55 citations

202. Delocalization in pπ–dπ bonds

1959 • 52 citations

Cyclic Sulfides. III. The Reaction of Some Ethylene Sulfides with Triphenylphosphine and with Triethyl Phosphite

1958 • 51 citations

134. The crystal structure of phosphorus pentachloride

1942 • 49 citations

371. The mechanism of hydrolysis of phosphonochloridates and related compounds. Part I. The effect of substituents

1960 • 49 citations

Der Einfluß α‐ständiger Sauerstoff‐ und Schwefelatome auf die Hydrolysierungsgeschwindigkeit der Kohlenstoff‐Halogen‐Bindung

1941 • 48 citations

Isomerization of β-Ethylmercaptoethyl Diethyl Thionophosphate (Systox)^1-3

1954 • 48 citations

677. The nature of the co-ordinate link. Part IV. Complex formation by phosphorus trifluoride

1951 • 45 citations

Phosphoramidate Anions: The Preparation of Carbodiimides, Ketenimines and Isothiocyanates

1962 • 45 citations

REACTIVITY AT BRIDGEHEAD SILICON. II. 1-SILABICYCLO [2.2.2] OCTANE

1959 • 44 citations

Mechanisms of Hydrolysis of Carbonyl Chlorides¹

1955 • 41 citations

Phosphororganische Verbindungen, XXI. Zur Umsetzung von Phosphorhalogenverbindungen mit Alkylhalogeniden

1960 • 39 citations

Ionization Constants of Several Substituted Phenylarsonic Acids

1943 • 39 citations

The Chlorine-catalyzed Hydrolysis of Isopropyl Methylphosphonofluoridate (Sarin) in Aqueous Solution

1956 • 39 citations

738. The effects of substituents on the rates of hydrolysis of some organophosphorus compounds. Part I. Rates in alkaline solution

1956 • 38 citations

The Transesterification of Trialkyl Phosphites with Aliphatic Alcohols^1,2

1956 • 37 citations

The Rates of Alcoholysis of Acyl Chlorides

1936 • 36 citations

STEREOCHEMISTRY OF DISPLACEMENT REACTIONS AT AN ASYMMETRIC PHOSPHONIUM CATION

1960 • 35 citations

Cyclische Phosphin-methylene II

1963 • 34 citations

The molecular and crystal structure of (PCF₃)₅

1961 • 34 citations

474. Chemical applications of nuclear quadrupole resonance. Part IV. The transmission of the electronic effect of various substituents by a phosphorus atom

1961 • 32 citations

Über die Reaktionsweisen des Phosphorpentachlorids (I. Mitteil.)

1930 • 32 citations

287. Studies on phosphorylation. Part XV. The use of phosphoramidic esters in acylation. A new preparation of adenosine-5? pyrophosphate and adenosine-5? triphosphate

1957 • 32 citations

Zur Chemie der „energiereichen Phosphate”︁, VIII. Carbamylphosphate

1959 • 31 citations

Phosphorobenzene-Alkali Metal Adducts

1957 • 30 citations

The Stereochemistry of Asymmetric Phosphorus Compounds. IV. The Synthesis and Stereochemistry of Displacement Reactions of Optically Active Isopropyl Methylphosphonochloridate

1962 • 30 citations

Modellreaktion zur oxydativen Phosphorylierung

1958 • 29 citations

Kinetics of the Reaction of Isopropyl Methylphosphonofluoridate with Catechols at 25°

1956 • 28 citations

Phosphororganische Verbindungen, XXIII: Zur Umsetzung von „Phosphobenzol”︁ mit Alkylhalogeniden

1961 • 27 citations

101. Kinetic studies in the phosphinyl chloride and phosphorochloridate series. Part I. Solvolytic reactions

1953 • 27 citations

590. The organic chemistry of phosphorus. Part III. The nature of the compounds of triaryl phosphites and the halogens

1956 • 26 citations

STEREOSPECIFIC CONVERSION OF METHYLETHYLPHENYLBENZYLPHOSPHONIUM IODIDE TO METHYLETHYLPHENYLPHOSPHINE OXIDE

1959 • 26 citations

The Phosphonitrilic Halides and their Derivatives

1959 • 25 citations

Notes- Desulfurization of Thiiranes with Triethyl Phosphate

1958 • 24 citations

Über organische Phosphorverbindungen, V. Mitteilung Über die Einwirkung von Carbonylenderivaten auf Phosphazine

1921 • 24 citations

136. Influence of poles and polar linkings on the course pursued by elimination reactions. Part XVII. Thermal decomposition of phosphonium ethoxides

1933 • 23 citations

DECOMPOSITION OF OPTICALLY ACTIVE METHYLETHYLPHENYLBENZYLPHOSPHONIUM n-BUTOXIDE

1960 • 23 citations

416. Studies on phosphorylation. Part VII. The action of salts on neutral benzyl esters of the oxy-acids of phosphorus. A new method of selective debenzylation

1950 • 22 citations

Crystal Structure of Phosphorus Pentabromide

1940 • 22 citations

372. The mechanism of hydrolysis of phosphonochloridates and related compounds. Part II. The effect of the solvent

1960 • 22 citations

12. Bond lengths in some inorganic molecules and complex ions

1949 • 21 citations

Über Phosphobenzol

1952 • 21 citations

340. The basic strengths of tertiary amines, phosphines, and arsines

1937 • 21 citations

The thermochemistry of organic phosphorus compounds. Part I. Heats of hydrolysis and oxidation

1955 • 21 citations

702. The mechanism of hydrolysis of phosphorochloridates and related compounds. Part III. Phosphoramidochloridates

1962 • 20 citations

Intermolecular Hydrogen Bond Association between Phenol and Compounds which Contain the Phosphoryl and Carbonyl Groups.

1960 • 20 citations

The Heat of Formation of Nitric Oxide and Phosphorus Trioxide

1952 • 20 citations

232. Influence of poles and polar linkings on the course pursued by elimination reactions. Part XIX. Thermal decomposition of phosphonium chlorides

1933 • 19 citations

Phosphorothioates. II. The Effect of the Nucleophilicity of the Attacking Anion upon Rates of Displacement on O,O-Diphenyl Phosphorochloridothioate

1962 • 19 citations

178. The use of 3d orbitals in certain valency states of the carbon atom and other first-row elements

1952 • 18 citations

Nonequivalence of Chlorine Atoms in Phosphorus Pentachloride

1954 • 18 citations

209. Kinetic studies in the phosphinyl chloride and phosphorochloridate series. Part V. Evidence for a one-stage mechanism in the hydrolysis of diethyl phosphorochloridate

1956 • 18 citations

Stereochemie siliciumorganischer Verbindungen

1962 • 15 citations

53. Hydrolysis of dialkylphosphinic fluorides and dialkyl phosphorofluoridates. Kinetic and tracer studies

1959 • 14 citations

236. Studies on phosphorylation. Part XIX. The P 1 P 1-diethyl-pyrophosphate ion

1960 • 12 citations

Preparation and Properties of Some Unsymmetrical Tetraalkyl Phrophosphates¹

1950 • 12 citations

Das Solvosystem Phosphoroxychlorid I

1952 • 12 citations

503. Phospholipids. Part II. The stability of some derivatives of 2-aminoethyl phosphate

1957 • 12 citations

703. The mechanism of hydrolysis of phosphorochloridates and related compounds. Part IV. Phosphoryl chloride

1962 • 12 citations

285. Thermochemistry of organophosphorus compounds. Part II. Triethyl phosphate, tripropylphosphine oxide, and tributylphosphine oxide

1956 • 12 citations

CCCCXI.—Influence of poles and polar linkings on the course pursued by elimination reactions. Part II. Mechanism of exhaustive methylation (continued)

1928 • 11 citations

199. Nucleophilic reactivity. Part III. The significance of the brönsted relation, with particular reference to acylation and alkylation

1962 • 11 citations

Untersuchung der gegenseitigen Abhängigkeit der Atombindungen. Wärmetönung der Reaktion 2 PF₃ + O₂ = 2 POF₃. Beschreibung eines neuen Gascalorimeters

1929 • 10 citations

Magnesium Salts of Arylphosphonic Acids. The Preparation of o-Nitrophenylphosphonic Acid¹

1955 • 10 citations

Analytical applications of the reaction of thorium with benzenephosphonic acid

1955 • 10 citations

Zur Chemie der energiereichen Phosphate IX: Die Reaktionen von Triestern der Pyrophosphorsäure

1961 • 10 citations

Notes - Kinetics of Reaction of Acyl Chlorides. III. Hydrolysis of Phosphinyl Chlorides.

1956 • 10 citations

102. Kinetic studies in the phosphinyl chloride and phosphorochloridate series. Part II. Reaction of diisopropyl phosphorochloridate with anionic reagents

1953 • 8 citations

Communications- Ultraviolet Absorption Spectra of Tri-2-pyrrylphosphine Oxides: Evidence for dπ-pπ Bonding

1961 • 8 citations

852. The existence of the P 1 P 1-diethyl pyrophosphate ion

1961 • 8 citations

Organic Phosphorus Compounds. IV.¹ A Study of the Transesterification of Dialkyl Alkylphosphonites

1958 • 8 citations

EUCARVONE ENOL TRIPHENYLMETHYL ETHER: A SUBSTITUTED CARADIENE

1960 • 7 citations

165. Interaction of hydrogen halides and n-butyl phosphites

1952 • 7 citations

The Reaction between Amines and Ethyl Methylphosphonochloridate

1963 • 5 citations

The Ultraviolet Absorption Spectra of Two Arylalkylphosphinic Acids and Related Compounds

1952 • 4 citations

90. The heats of hydrolysis of some halides and oxyhalides of phosphorus

1953 • 4 citations

Versammlungsberichte

1958 • 2 citations

458. The solvolysis of acetic anhydride in 50% aqueous acetone catalysed by nitrite ion

1958 • 2 citations

Ultraviolet Absorption Study Of Protolysis Constants Of Some Para-Substituted Phenylphosphonic Acids In Water

1956 • 1 citations

Deleted Work

1955 • 0 citations