Dynamics of intramolecular metal-centered rearrangement reactions of tris-chelate complexes

Mechanisms of Inorganic Reactions

1958 • 1,053 citations

The symmetry groups of non-rigid molecules

1963 • 1,037 citations

Mechanisms of Inorganic Reactions

1966 • 871 citations

Idealized polytopal forms. Description of real molecules referenced to idealized polygons or polyhedra in geometric reaction path form

1974 • 686 citations

Dynamic Nuclear Magnetic Resonance Spectroscopy

1975 • 527 citations

NMR of Paramagnetic Molecules

1973 • 465 citations

Rates and Mechanisms of Substitution in Inorganic Complexes in Solution.

1952 • 381 citations

Some problems in the stereochemistry of coordination compounds

1958 • 220 citations

Detailed nature of the six-coordinate polyhedra in tris(bidentate ligand) complexes

1972 • 179 citations

Intramolecular rearrangement mechanisms in five-coordinate complexes

1972 • 131 citations

Stereochemistry of sulfur compounds. I. Stereochemical reaction cycles involving an open chain sulfoxide, sulfimide, and sulfoximide

1970 • 131 citations

Solution structure of coinage metal-phosphine complexes

1970 • 113 citations

Mechanism of Racemization of Complex Ions. II. Kinetics of the Dissociation and Racemization of Tris-(1,10-phenanthroline)-iron(II) and Tris-(2,2'-dipyridyl)-iron(II) Complexes^1,2

1954 • 110 citations

Stereochemically Nonrigid Six-Coordinate Molecules.' III. The Temperature-Dependent 'H and 31P Nuclear Magnetic Resonance Spectra of Some Iron and Ruthenium Dihydrides

1973 • 108 citations

Three-dimensional macrocyclic encapsulation reactions. III. Geometrical and electronic features of tris(diimine) complexes of trigonal-prismatic, antiprismatic, and intermediate stereochemistry

1972 • 93 citations

Coördination Compounds of Trivalent Metals with Unsymmetrical Bidentate Ligands. I. Benzoylacetonates

1962 • 89 citations

Dynamic stereochemistry of tris(chelate) complexes. I. Tris(dithiocarbamato) complexes of iron, cobalt, and rhodium

1973 • 74 citations

Tris(N,N-disubstituted dithiocarbamato)iron(IV) tetrafluoroborates

1972 • 72 citations

Intramolecular rearrangement reactions of tris-chelate complexes. I. General theory and the kinetics and probable mechanism of the isomerization and racemization of tris(5-methylhexane-2,4-dionato)cobalt(III)

1970 • 71 citations

Stereochemistry of tris(bidentate) complexes

1972 • 70 citations

Trigonal prismatic vs. octahedral stereochemistry in complexes derived from innocent ligands

1972 • 63 citations

Synthesis and stereochemical rearrangements of complexes containing the Fe-S6 core

1971 • 60 citations

Coordination Compounds of Trivalent Metals with Unsymmetrical 1,3-Diketones. III. Mechanism of Stereochemical Rearrangements

1964 • 60 citations

Optical and geometrical isomerization of β-diketonate complexes

1971 • 58 citations

Applications of isotropic shifts to the investigation of structures and structural equilibriums of metal complexes

1969 • 54 citations

Intramolecular rearrangement reactions of tris-chelate complexes. III. Analysis of the rearrangements of tris(.alpha.-isopropenyl- and .alpha.-isopropyltropolonato)aluminum(III) and -cobalt(III). Examples of stereochemically nonrigid aluminum(III) and cobalt(III) complexes

1972 • 53 citations

Structural studies in the tris(NN-dialkyldithiocarbamato)iron(<scp>III</scp>)‘cross-over’ system

1972 • 53 citations

Intramolecular isomerization of octahedral complexes by mechanisms not involving bond rupture

1967 • 52 citations

Stereochemical rearrangements of metal tris-.beta.-diketonates. I. Partial resolution and racemization of some tris(acetylacetonates)

1970 • 52 citations

Modes of rearrangement in phosphoranes

1972 • 51 citations

Conformational studies of chelated ethylenediamines by nuclear magnetic resonance. Paramagnetic nickel(II) complexes of N-alkylethylenediamines

1969 • 49 citations

Stereochemistry and rearrangement rates of some tris(β-diketonato)- and tris(β-thioketonato)metal(III) complexes

1971 • 45 citations

Stereochemical rearrangements of metal tris-.beta.-diketonates. II. Kinetics and mechanism of geometrical isomerization, optical, inversion, and ligand-exchange reactions of cobalt(III) benzoylacetonate

1970 • 43 citations

Kinetics investigation of carbon-nitrogen bond rotation in dithiocarbamato complexes of iron by proton magnetic resonance

1973 • 43 citations

Intramolecular rearrangement reactions of tris-chelate complexes. II. Kinetics and probable mechanism of the isomerization and racemization of the "fast" complexes tris(1-phenyl-5-methylhexane-2,4-dionato)aluminum(III) and -gallium(III)

1971 • 42 citations

Stereochemistry of tropolonato complexes utilizing the higher coordination numbers. I. Nine-coordinate tetrakis(tropolonato)-N,N'-dimethylformamidethorium(IV)

1970 • 41 citations

Hindered ligand systems. IV. Complexes of cis,cis-1,3,5-tris(pyridine-2-carboxaldimino)cyclohexane. Trigonal-prismatic vs. octahedral coordination

1970 • 37 citations

Intramolecular rearrangement reactions of tris-chelate complexes. IV. Rearrangements of tris(.alpha.-isopropenyl- and .alpha.-isopropyltropolonate)metal(III,IV) complexes

1973 • 36 citations

Dynamic stereochemistry of tris-chelate complexes. II. Tris(dithiocarbamato) complexes of manganese (III), vanadium(III) chromium(III), gallium(III), and indium(III)

1974 • 35 citations

Determination of rates of optical inversion of aluminum .beta.-diketonate complexes by nuclear magnetic resonance studies of racemic mixtures

1967 • 35 citations

Dynamic stereochemistry of tris-chelate complexes. III. Tris(dithiocarbamato) complexes of ruthenium(III)

1974 • 34 citations

Synthesis and stereochemistry of bis(N,N-disubstituted-dithiocarbamato)maleonitriledithioleneiron complexes

1972 • 34 citations

Dynamic stereochemistry of tris-chelate complexes. IV. Crystal structure of tris(N,N-diethyldithiocarbamato)ruthenium(III)

1974 • 34 citations

Modes of intramolecular rearrangement in octahedral complexes

1972 • 32 citations

The Chemistry of Metal Chelate Rings. IV. Electrophilic Substitution of Optically Active Tris-acetylacetonates

1963 • 30 citations

NMR Studies of Iron (III) N-Methyl-N-Phenyldithiocarbamate and Its meta- and para-Fluorophenyl Derivatives

1968 • 29 citations

Reaction mechanisms in inorganic chemistry

1972 • 28 citations

Nuclear magnetic resonance studies of configuration and ligand conformation in paramagnetic octahedral complexes of nickel(II). IX. 1,3-Diamine chelates

1974 • 28 citations

Stereochemically nonrigid ruthenium(III) and cobalt(III) tris-chelate complexes

1973 • 26 citations

Symmetry groups of nonrigid tris-chelate complexes

1973 • 24 citations

Chelate chemistry. VI. Solution behavior of tropolonates

1969 • 24 citations

Conformational studies of chelated ethylenediamines by nuclear magnetic resonance. Tris-(ethylenediamine)nickel(II) ion in aqueous solution

1970 • 24 citations

Contact shift studies of nickel-butylenediamine complexes

1971 • 20 citations

Kinetics of stereochemical rearrangements for mixed .beta.-diketonate complexes of aluminum(III)

1971 • 19 citations

880. The reactivity of co-ordinated oxalated. Part I. Oxygen-18 exchange studies on oxalic acid, the trisoxalatochromium(III) anion, and the trisoxalatocobalt(III) anion

1964 • 19 citations

Electrochemistry and isomerization kinetics of tris[(+)-3-acetylcamphorato]ruthenium(III). Circular dichroism and absolute configurations of the analogous ruthenium(II) and ruthenium(IV) diastereomers

1974 • 18 citations

Intramolecular rearrangement reactions of tris(N-methyl-N-benzyldithiocarbamato)-iron(IV) tetrafluoroborate by proton magnetic resonance

1972 • 16 citations

Electrochemical behaviour of iron(III) N,N-diethyldithiocarbamate synthesis of an iron(IV) species

1973 • 16 citations

Detection of rapid optical inversion in "labile" cobalt(II) chelates using proton magnetic resonance

1970 • 12 citations

Radionuclides in the environment : a symposium sponsored by the Division of Nuclear Chemistry and Technology at the 155th meeting of the American Chemical Society, San Francisco, Calif., April 1-3, 1968

1970 • 12 citations

Rate of electron transfer between tris(dithiocarbamato) complexes of iron(III) and iron(IV) by proton magnetic resonance

1974 • 10 citations

Acid-catalysed oxygen-18 exchange, racemisation, and aquation studies with the trisoxalatocobaltate(III) anion in aqueous solution

1971 • 10 citations

Direct measurement of enantiomerization of labile aluminium(<scp>III</scp>)β-diketonates

1971 • 9 citations

Substitution Reactions of Oxalato Complex Ions. IV. Oxalate Exchange and Aquation Reactions of the Trisoxalatorhodium(III) Complex

1962 • 9 citations

Evidence for a trigonal twist mechanism in the intramolecular rearrangement of tris-(N-methyl-N-phenyldithiocarbamato)iron(III)

1972 • 8 citations

Optically active tris(dithiocarbamato)cobalt(III) complexes

1974 • 8 citations

Isorotatory points and racemization

1967 • 7 citations

Oxygen exchange between tris(oxalato)rhodate(III) ion and solvent water. Exchange of outer and inner oxygens

1968 • 6 citations