Chemical and stereochemical properties of compounds with silicon or germanium-transition metal bonds

Alkyl and aryl derivatives of π-cyclopentadienyl compounds of chromium, molybdenum, tungsten, and iron

1956 • 732 citations

Applications of metal carbonyl anions in the synthesis of ususual organometallic compounds

1970 • 222 citations

Dicobalt Octacarbonyl as a Catalyst for Hydrosilation of Olefins

1965 • 200 citations

Nucleophilic displacement at silicon sterochemistry and mechanistic implications

1980 • 156 citations

A silyliron compound; an Fe-Si ? bond

1956 • 128 citations

Silicon-transition metal chemistry. I. Photochemical preparation of silyl(transition metal) hydrides

1971 • 125 citations

Organometallic Compounds with Metal-Metal Bonds. IV. Pentacarbonylmanganese and Pentacarbonylrhenium Derivatives of Silicon, Germanium, Tin, and Lead. Preparation and Infrared and Nuclear Magnetic Resonance Studies

1966 • 123 citations

Transition Metal Organometallics in Organic Synthesis

1978 • 95 citations

Asymmetric synthesis at silicon

1975 • 90 citations

Stereochemistry of asymmetric silicon. XV. Stereospecific hydrosilation and exchange reactions of R3SiH(D) catalyzed by Group VIII metal centers

1969 • 86 citations

Trimethyl- and trichlorosilylcobalt tetracarbonyls and the hydrosilation of ethylene

1969 • 81 citations

Cyclopentadienyl complexes of chromium, molybdenum and tungsten

1972 • 79 citations

On the behaviour of an optically active cobalt—silicon bond. Evidence for the formation of analogues of silyl-grignard reagents

1977 • 67 citations

Bent [14]annulenes. Synthesis of 1,6:8,13-ethanediylidene[14]annulene

1972 • 61 citations

Anomalous reactions of triphenylchlorosilane with metal carbonyl anions

1972 • 46 citations

Silicon-transition metal chemistry. II. Anions derived from silyl(transition metal) hydrides and related compounds

1971 • 46 citations

Synthesis and properties of manganese hydrides having a functional silicon

1979 • 43 citations

Transition Metal Complexes with Group IVB Elements

1968 • 43 citations

Organometallic chemistry of the transition metals. XXXI. Stereoisomerism in cyclopentadienylrhenium(III) derivatives

1976 • 43 citations

Displacements at Asymmetric Germanium. Methyl-α-naphthylphenylgermyllithium and its Derivatives

1963 • 41 citations

Optically active silylanions. Evidence for the formation of analogues of silyl Grignard reagents

1976 • 40 citations

Synthesis, chemical behaviour and crystal structure of cobalt-stabilized carbenes, (Ph3Ge)(CO)3CoC(OEt)R

1979 • 40 citations

Silicon Hydrides and their Derivatives

1968 • 37 citations

Photolytic preparation of metal-metal bonds between some Group VI and Group IV metals

1967 • 36 citations

Oxidation of bis(triethylgermyl)mercury in the presence of tert-butyl alcohol

1972 • 36 citations

Problème du cation siliconium V. Mécanisme de la racémisation de chlorosilanes et de chlorogermanes diversement encombrés

1970 • 35 citations

Stéréochimie des réactions du triphénylgermyllithium et des germyllithiums asymétriques sur les chloro- et les alkoxy-germanes

1974 • 31 citations

Functionally substituted organolithium compounds.

1973 • 29 citations

Stereochemistry of the formation and cleavage of silicon–platinum bonds

1973 • 28 citations

Silyl-, Germyl-, and Stannyl-Pentacarbonylmetalates Of Chromium, Molybdenum, and Tungsten

1975 • 28 citations

Synthese und Reaktivität von Silicium‐Übergangsmetallkomplexen, VIII. Chlor/Fluor‐ und Wasserstoff/Fluor‐Austausch am Siliciumatom

1974 • 28 citations

Preparation et reactivite de composes chiraux et non chiraux derives de (η5-cyclopentadienyl) dicarbonylfer. stereochimie de la coupure de la liaison fer—silicium

1977 • 27 citations

Activation catalytique des reactifs de grignard par des complexes du nickel en serie organosiliciee

1974 • 26 citations

The preparation of optically active germyl- and silylplatinum complexes

1972 • 25 citations

Bonding of hydrido ligands in transition metal-silyl complexes: terminal or bridging? 1. Structure of bis(.mu.-diethylsilicon)-bis(tricarbonyldihydridorhenium)(Re-Re), Re2(CO)6H4(Si(C2H5)2)2

1977 • 24 citations

Molecular and crystal structure of (+)-tetracarbonyl(methyl-1-naphthylphenylgermyl)-cobalt

1977 • 23 citations

Preparation of an optically active and other organosilicon derivatives of π-cyclopentadienyliron dicarbonyl

1973 • 22 citations

Trispentafluorophenylsilane and trispentafluorophenylsilyl-metal derivatives. Preparation, and infrared and mass spectra

1969 • 22 citations

Metallkomplexe mit anionischen Liganden von Elementen der 4. Hauptgruppe, III. Homogene und heterogene (Trichlorstannido)metallat(0)‐Komplexe von Chrom, Molybdän und Wolfram

1974 • 22 citations

Metal-Carbene Complexes in Organic Synthesis

1976 • 22 citations

The interaction of organosilicon hydrides and dimethyl-bis(phosphine)platinum(II) complexes

1974 • 21 citations

A new route to hydrido(organosilyl)bis(triphenylphosphine)platinum(II) complexes

1972 • 20 citations

The absolute configuration of the optically-active silylplatinum complex (+)-trans-[PtCl{SiMe(1-C10H7)Ph}(PMe2Ph)2],

1973 • 19 citations

Synthesis of optically active silicon–iron compounds. Stereochemistry of silicon–iron bond breaking

1975 • 19 citations

Organometallic compounds having metal-metal bonds

1975 • 18 citations

The reaction between organosilyl derivatives of (η5-C5H5)Fe(CO)2 and triphenyl phosphite. New evidence for ortho-metalated phosphite ligands

1977 • 15 citations

Some new compounds containing platinumsilicon bonds

1968 • 15 citations

Platinum(II) grignard and lithio derivatives

1965 • 15 citations

The Coordination Behavior of Triphenylsilanide

1968 • 15 citations

Preparation and reactivity of the optically active silicon–manganese compound (–)-[(π-methylcyclopentadienyl) Mn(CO)₂(H)SiMePh(α-naphthyl)]

1976 • 14 citations

Stereochemistry of cleavage of silicon–platinum bonds in optically active silicon–platinum compounds

1972 • 13 citations

Formation of benzoylsilanes from the reaction of organosilylcobalt tetracarbonyl derivatives with phenyl-lithium

1977 • 13 citations

Use of triorganogermyl-lithium compounds in transition metal chemistry. Application to the synthesis of optically active anions containing a transition metal–germanium bond

1978 • 13 citations

Organogermyl complexes of platinum and palladium

1968 • 11 citations

Stèrèchimie de l;hydrogermylation des composès insaturès catalysèe par des complexe du rhodium et du platine

1972 • 7 citations

Complexing Behavior of Stannanide Ions: Tetrakis(trichlorostannanido)niccolate(0)

1969 • 4 citations