The gas-phase acidity scale

Thermochemical kinetics

1970 • 3,579 citations

Additivity rules for the estimation of thermochemical properties

1969 • 1,378 citations

Bond Dissociation Energies by Kinetic Methods

1966 • 934 citations

Equilibrium acidities of carbon acids. VI. Establishment of an absolute scale of acidities in dimethyl sulfoxide solution

1975 • 544 citations

Molecular Refractivity and Polarizability

1965 • 391 citations

Free-radical and molecule thermochemistry from studies of gas-phase iodine-atom reactions

1969 • 321 citations

Intrinsic acidities of substituted phenols and benzoic acids determined by gas-phase proton-transfer equilibriums

1977 • 264 citations

Gas-phase acidities of alcohols

1970 • 241 citations

Kinetic study of the proton hydrate H+(H2O)n equilibriums in the gas phase

1972 • 238 citations

Summary of gas phase acidity measurements involving acids AH. Entropy changes in proton transfer reactions involving negative ions. Bond dissociation energies D(A—H) and electron affinities EA(A)

1978 • 223 citations

Basicity. Comparison of hydrogen bonding and proton transfer to some Lewis bases

1974 • 216 citations

Gas phase basicities and relative proton affinities of compounds between water and ammonia from pulsed ion cyclotron resonance thermal equilibriums measurements

1977 • 208 citations

Dynamics of proton transfer involving delocalized negative ions in the gas phase

1976 • 150 citations

The very low‐pressure pyrolysis of phenyl ethyl ether, phenyl allyl ether, and benzyl methyl ether and the enthalpy of formation of the phenoxy radical

1977 • 133 citations

The structures of acetylacetone, trifluoroacetyl-acetone and trifluoroacetone

1972 • 110 citations

Negative Ions and the Magnetron

1969 • 107 citations

Potential for rotation about C(sp2)-O and C(sp2)-S bonds: electron diffraction results for CH2CH-OCH3 and CH2

1975 • 96 citations

Heats of formation of C1?C4 alkyl nitrites (RONO) and their RO-NO bond dissociation energies

1974 • 88 citations

Laser photoelectron spectrometry of C5H−5: A determination of the electron affinity and Jahn–Teller coupling in cyclopentadienyl

1977 • 76 citations

Alkali-phosphorverbindungen und ihr reaktives verhalten

1965 • 71 citations

Gas-phase acidities of amines

1971 • 69 citations

Phenolic-OH torsional frequency as a probe for studying .pi.-electron distortions in aromatic systems

1975 • 67 citations

The Determination of Silicon-Carbon and Silicon-Hydrogen Bond Dissociation Energies by Electron Impact

1962 • 64 citations

.alpha.-Fluoro and .alpha.-alkoxy substituents as deactivators in carbanion formation

1967 • 62 citations

Acidity order of selected Broensted acids in the gas phase of 300.deg. K

1972 • 61 citations

Fluoronitroaliphatics. I. The Effect of α Fluorine on the Acidities of Substituted Nitromethanes¹

1966 • 60 citations

The polarizability of molecules in strong electric fields

1952 • 60 citations

Intrinsic acidities of carbon and nitrogen acids measured by gas phase proton transfer equilibriums. Substituent effects on the stabilities of gas phase carbanions and nitrogen anions

1976 • 58 citations

Reactions of NO2− and NO3− with HCl and HBr

1972 • 55 citations

Photodetachment of electrons from enolate anions. Gas phase electron affinities of enolate radicals

1977 • 55 citations

Photodetachment of electrons from Group IVa binary hydride anions: The electron affinities of the SiH3 and GeH3 radicals

1974 • 54 citations

Pulsed ion cyclotron resonance mass spectrometer for studying ion–molecule reactions

1978 • 53 citations

Alkyl effects on equilibrium acidities of carbon acids in protic and dipolar aprotic media and the gas phase

1978 • 51 citations

Absolute gas-phase acidities of CH₃NH₂, C₂H₅NH₂, (CH₃)₂ NH, and (CH₃)₃N

1976 • 51 citations

Effects of halogen substituents on the intrinsic acidity of acetic acids determined by measurements of gas-phase ion equilibriums

1973 • 50 citations

In support of anionic hyperconjugation. The versatile methyl group

1977 • 48 citations

Heats of formation of free radicals by mass spectrometry

1973 • 48 citations

Electron photodetachment from negative ions of C2v symmetry. Electron affinities of allyl and cyanomethyl radicals

1977 • 45 citations

Acidity of hydrocarbons. XXIX. Kinetic acidities of benzal fluoride and 9-fluorofluorene. A pyramidal benzyl anion

1968 • 41 citations

Carbon acidity. LII. Equilibrium acidity of cyclopentadiene in water and in cyclohexylamine

1976 • 40 citations

Gas-phase acidities of carbon acids

1968 • 39 citations

Acid-base properties and gas-phase ion chemistry of trimethylborane

1976 • 39 citations

Photodetachment of electrons from large molecular systems: Cyclopentadienide and methylcyclopentadienide ions. An upper limit to the electron affinities of C5H5· and CH3C5H4·

1973 • 38 citations

Thermodynamic properties of several nitrotoluenes

1971 • 36 citations

Reactions of borane. II. Absolute rate of the reaction of borane with ethylene in the gas phase

1971 • 36 citations

The very low‐pressure pyrolysis of phenyl methyl sulfide and benzyl methyl sulfide. The enthalpy of formation of the methylthio and phenylthio radicals

1977 • 36 citations

Photodetachment of electrons from phenoxides and thiophenoxide

1975 • 34 citations

Relative Acidities of Some Hydrides of Groups IV and V in Liquid Ammonia. Nuclear Magnetic Resonance Spectra of the Hydrides and Their Anions

1966 • 33 citations

The enol of acetone

1977 • 31 citations

Gas phase oxidation and reduction reactions with C6H7-, HNO-, and HO2-

1978 • 29 citations

The kinetics and thermochemistry of the gas phase reaction of cyclopentadiene and iodine. Relevance to the heat of formation of cyclopentadienyl iodide and cyclopentadienyl radical

1971 • 27 citations

Photodetachment of electrons from large molecular systems. Pyrrolate ion. Electron affinity of C4H4N

1975 • 27 citations

Amino substituent effect on the properties of ionic compounds

1975 • 25 citations

Free radicals by mass spectrometry. XLI. Ionization potential and heat of formation of the PH2 radical

1969 • 25 citations

Carbon acids. 10. Resonance saturation of substituent effects in the fluorene series

1976 • 24 citations

Kinetics of the gas‐phase reaction of acetone with iodine: Heat of formation and stabilization energy of the acetonyl radical

1970 • 23 citations

Photodetachment of electrons from large molecular systems: Benzyl anion. An upper limit to the electron affinity of C6H5CH2

1975 • 23 citations

Relative gas-phase acidities of some fluoroalcohols

1977 • 22 citations

Aqueous vs. gas-phase acidities of the haloacetic acids. Enthalpies of hydration of haloacetic acids and haloacetate ions

1976 • 21 citations

Far-Infrared Group Frequencies. I. Aliphatic Alcohols

1972 • 21 citations

Heats of formation of some alkylthio radicals

1970 • 20 citations

Intrinsic Acidities of α, β, γ Chlorosubstituted Aliphatic Acids from Gas Phase Equilibrian Mesurements

1974 • 19 citations

Acidity, basicity, and gas-phase ion chemistry of hydrogen selenide by ion cyclotron resonance spectroscopy

1972 • 16 citations

Ab initio SCF calculations of the acidity of distorted ethanes and ethylenes

1974 • 15 citations

Acidity, basicity, and ion-molecule reactions of arsine in the gas phase by ion cyclotron resonance spectroscopy

1974 • 14 citations

Pyrolysis of trifluoroacetaldehyde. The formation of trifluoromethane and hexafluoroethane

1977 • 6 citations

Thermochemistry of the gas-phase equilibrium CH3COCH3 + Br2 = CH3COCH2Br + HBr. The enthalpy of formation of bromoacetone

1971 • 6 citations

Effects of ring substituents on the torsional frequency of the amino group in anilines

1977 • 3 citations