Linear Polyene Electronic Structure and Potential Surfaces

Quantum theory of many-particle systems

1971 • 5,270 citations

Soliton excitations in polyacetylene

1980 • 3,019 citations

Quantum Theory of Many Particle Systems

1972 • 2,855 citations

Relationship between Absorption Intensity and Fluorescence Lifetime of Molecules

1962 • 2,364 citations

Handbook of Fluorescence Spectra of Aromatic Molecules

1971 • 2,347 citations

Higher Excited States of Polyatomic Molecules

1975 • 1,376 citations

Topochemische Reaktionen von Monomeren mit konjugierten Dreifachbindungen / Tochemical Reactions of Monomers with conjugated triple Bonds

1969 • 961 citations

Energy Levels and Thermodynamic Functions for Molecules with Internal Rotation I. Rigid Frame with Attached Tops

1942 • 915 citations

Chemical and Biochemical Applications of Lasers

1974 • 821 citations

The molecular orbital theory of conjugated systems

1967 • 750 citations

Calculation of ground and excited state potential surfaces of conjugated molecules. I. Formulation and parametrization

1972 • 736 citations

Tables of molecular vibrational frequencies

1978 • 732 citations

The molecular orbital theory of conjugated systems

1966 • 605 citations

On the origin of a low-lying forbidden transition in polyenes and related molecules

1972 • 483 citations

Soliton dynamics in polyacetylene

1980 • 476 citations

A low-lying weak transition in the polyene α,ω-diphenyloctatetraene

1972 • 407 citations

Average structures of butadiene, acrolein, and glyoxal determined by gas electron diffraction and spectroscopy

1968 • 405 citations

Correlation effects in the spectra of polyenes

1976 • 393 citations

Linear Polyene Electronic Structure and Spectroscopy

1974 • 390 citations

The relations between the fluorescence and absorption properties of organic molecules

1963 • 388 citations

The Normal Vibrations of Polyatomic Molecules as Treated by Urey-Bradley Field

1949 • 376 citations

Polyene spectroscopy: The lowest energy excited singlet state of diphenyloctatetraene and other linear polyenes

1973 • 355 citations

Absorption Spectra of Dyes in Solution

1954 • 315 citations

Electronic Absorption Spectra and Geometry of Organic Molecules

1970 • 306 citations

Electronic Absorption Spectra and Geometry of Organic Molecules

1967 • 298 citations

Vibrational spectra of some carotenoids and related linear polyenes. Raman spectroscopic study

1973 • 282 citations

Conjugated polyene fatty acids as fluorescent probes: spectroscopic characterization

1977 • 256 citations

Molecular orbital theory of the electronic structure of organic compounds. IV. Internal rotation in hydrocarbons using a minimal Slater-type basis

1970 • 254 citations

Far Ultraviolet Absorption Spectra of Ethylene and Ethylene-d4

1955 • 244 citations

The electronic structure of conjugated systems. Parts III and IV

1948 • 236 citations

Electronic Spectral Shifts of Nonpolar Molecules in Nonpolar Solvents

1957 • 231 citations

Excited states of biological molecules

1976 • 205 citations

THEORY OF ONE-DIMENSIONAL MOTT SEMICONDUCTORS AND THE ELECTRONIC STRUCTURE OF LONG MOLECULES HAVING CONJUGATED BONDS

1973 • 184 citations

Solid-state polymerization of diacetylenes

1972 • 184 citations

Thermodynamic Properties of Gaseous 1,3-Butadiene and the Normal Butenes above 25°C Equilibria in the System 1,3-Butadiene, n-Butenes, and n-Butane

1946 • 178 citations

Electronic energy levels in a homologous series of unsubstituted linear polyenes

1980 • 178 citations

The Molecular Structure of 1,3-Butadiene and 1,3,5-trans-Hexatriene.

1966 • 172 citations

Determination of the torsional potential function of 1,3-butadiene

1975 • 169 citations

Solvent-Shift Effects on Electronic Spectra and Excited-State Dipole Moments and Polarizabilities

1973 • 169 citations

The 2 1A g–1 1B u energy gap in the polyenes: An extended configuration interaction study

1979 • 158 citations

High-resolution one and two photon excitation spectra of t r a n s, t r a n s-1,3,5,7-octatetraene

1980 • 155 citations

Vibrational structure of electronic transitions in conjugated molecules

1972 • 144 citations

The application of the Urey-Bradley force field to the in-plane vibrations of benzene

1961 • 140 citations

Solvent and temperature effects on the fluorescence of all-trans-1,6-diphenyl-1,3,5-hexatriene

1975 • 139 citations

Absorption Coefficients of Ethylene in the Vacuum Ultraviolet

1953 • 139 citations

A b i n i t i o study of the π-electron states of t r a n s-butadiene

1975 • 138 citations

Spectroscopic properties of polyenes. III. 1,3,5,7-Octatetraene

1978 • 136 citations

Electronic spectroscopy of s-trans 1,3-butadiene by electron impact

1973 • 135 citations

RESONANCE RAMAN STUDIES OF VISUAL PIGMENTS

1977 • 133 citations

Far Ultraviolet Absorption Spectra of Unsaturated and Aromatic Hydrocarbons

1955 • 130 citations

Franck–Condon analysis of the 1 1A g→1 1B u absorption in linear polyenes with two through six double bonds

1981 • 128 citations

LOW RESOLUTION OPTICAL SPECTROSCOPY OF RETINYL POLYENES: LOW LYING ELECTRONIC LEVELS AND SPECTRAL BROADNESS*

1973 • 128 citations

Spectroscopic properties of polyenes. I. The lowest energy allowed singlet-singlet transition for cis- and trans- 1,3,5-hexatriene

1973 • 126 citations

Photodynamics of polyenes: The effect of electron correlation on potential surfaces

1980 • 125 citations

Vibrational assignments for glyoxal, acrolein and butadiene

1964 • 124 citations

On the ultraviolet spectrum of t r a n s-1,3-butadiene

1976 • 121 citations

Topochemical Reactions of Monomers with Conjugated Triple‐Bonds VII Mechanism of Transition from Monomer to Polymer Phase During Solid‐State Polymerisation

1972 • 117 citations

Vibrational analysis of polyene chains. Assignments of the resonance Raman lines of poly (acetylene) and β‐carotene

1975 • 115 citations

Electron impact study of the energy levels of t r a n s-1,3-butadiene: II. Detailed analysis of valence and Rydberg transitions

1980 • 114 citations

Electronic spectroscopy of polyatomic molecules by low-energy, variable-angle electron impact

1979 • 111 citations

Vibronic coupling in polyenes: High resolution optical spectroscopy of 2,10-dimethylundecapentaene

1975 • 108 citations

The multiphoton ionization spectrum of t r a n s-1,3-butadiene

1976 • 108 citations

Ring Orientation in βIonone and Retinals

1971 • 107 citations

The Single and Double Bonds between sp2-Hybridized Carbon Atoms, as studied by the Gas Electron Diffraction Method. II. The Molecular Structure of 1,3,5-trans, trans, trans-Hexatriene.

1968 • 106 citations

Electronic structure of polyenes and polyacetylene

1978 • 99 citations

Self-Consistent Theory of Bond Alternation in Polyenes: Normal State, Charge-Density Waves, and Spin-Density Waves

1969 • 94 citations

Intensities of Electronic Transitions in Molecular Spectra VII. Conjugated Polyenes and Carotenoids

1939 • 94 citations

Low energy, variable angle electron-impact excitation of 1,3,5-hexatriene

1977 • 93 citations

Environmental effects on radiative rate constants with applications to linear polyenes

1978 • 91 citations

An investigation of the structure of butadiene by high resolution infra-red and raman spectroscopy

1962 • 91 citations

Experimental confirmation of the dipole forbidden character of the lowest excited singlet state in 1,3,5,7-octatetraene

1979 • 89 citations

Spectroscopic properties of polyenes. II. The vacuum ultraviolet spectra of cis- and trans-1,3,5-hexatriene

1974 • 86 citations

The Single and Double Bonds between sp2-Hybridized Carbon Atoms, as Studied by the Gas Electron Diffraction Method. III. The Molecular Structure of 1,3,5-cis-Hexatriene.

1968 • 86 citations

Observation of the low-energy 1Ag state of diphenylhexatriene by two-photon excitation spectroscopy

1978 • 85 citations

Conformational analysis of 1,3-butadiene

1973 • 79 citations

Fluorescence Spectra of Some Retinyl Polyenes

1969 • 79 citations

Two-photon excitation spectra of the low energy excited states of diphenylhexatriene and diphenyloctatetraene

1976 • 79 citations

The valence electronic excited states of trans-1,3-butadiene and trans, trans-1,3,5-hexatriene from generalized valence bond and configuration interact

1979 • 77 citations

The fluorescence of all-trans diphenyl polyenes

1978 • 76 citations

Internal Dispersion Forces. The Polyenes

1951 • 75 citations

Valence-Bond Theory for Simple Hydrocarbon Molecules, Radicals, and Ions

1968 • 73 citations

Two-photon spectroscopy of diphenylbutadiene. The nature of the lowest-lying 1A g*−ππ* state

1980 • 72 citations

The absorption spectra of conjugated dienes in the vacuum ultra-violet (1)

1940 • 72 citations

The Vibrational Spectra and Geometric Configuration of cis-1,3,5-Hexatriene

1962 • 72 citations

Observation of ’’hidden’’ electronic states by two-photon excitation spectroscopy: Confirmation of the low-energy 1A g state of diphenyloctatetraene

1977 • 69 citations

High-resolution optical spectroscopy of polyenes related to the visual chromophore

1976 • 68 citations

Microwave Studies of Butadiene Derivatives. I. Spectrum of Fluoroprene

1962 • 68 citations

The fluorescence of diphenyl- and retinol-polyenes

1975 • 68 citations

Structure of α,ω-diphenyl-polyenes. IV. Crystal and molecular structure of 1,8-diphenyl-1,3,5,7-octatetraene

1955 • 66 citations

On the forbidden 2000 Å transition of trans-1,3-butadiene

1975 • 62 citations

Two-photon absorption studies of diphenylbutadiene: The location of a 1Ag excited state

1973 • 62 citations

Removal of Xenon and Radon from Contaminated Atmospheres with Dioxygenyl Hexafluoroantimonate, O2SbF6

1973 • 61 citations

Electronic structure of polyenes related to the visual chromophore. A simple model for the observed band shapes

1977 • 61 citations

Absorption and emission of 2,12-dimethyltridecahexaene

1981 • 60 citations

Correlation of Pi-Electron Density with Vibrational Frequencies of Linear Polyenes

1971 • 58 citations

Vibrational spectroscopy of the electronically excited state: pulse radiolysis/time-resolved resonance Raman study of triplet .beta.-carotene

1979 • 55 citations

The spectra of carbonium ions, cyanine dyes, and protonated Schiff base polyenes

1980 • 55 citations

Conformations of conjugated hydrocarbons. Part 1. A spectroscopic and thermodynamic study of buta-1,3-diene and 2-methylbuta-1,3-diene (isoprene)

1976 • 55 citations

Triplet states in 1,3-butadiene

1973 • 53 citations

Electron-impact investigation of excited singlet states in 1,3-butadiene

1978 • 53 citations

Multiphoton ionization spectrum of t r a n s-hexatriene in the 6.2 eV region

1976 • 53 citations

Electron impact study of the energy levels of t r a n s-1,3-butadiene

1979 • 52 citations

Fluorescence polarization measurements on molecules oriented in liquid crystals

1970 • 51 citations

Polyene spectroscopy: Vibronic evidence for a forbidden transition in DECA-2,4,6,8-tetraene

1978 • 51 citations

The Vibrational Spectra and Geometrical Configuration of 1,3,5,7-Octatetraene

1959 • 49 citations

Multiphoton transitions in trans-butadiene observed by multiphoton ionization and thermal lensing spectroscopy

1978 • 47 citations

RADIATIVE AND NON‐RADIATIVE LOSSES IN THE RETINOL POLYENES

1970 • 46 citations

Time-resolved resonance Raman spectroscopy: the excited triplet state of all-trans-.beta.-carotene

1980 • 46 citations

Vibrational spectroscopy of the electronically excited state. 4. Nanosecond and picosecond time-resolved resonance Raman spectroscopy of carotenoid excited states

1981 • 45 citations

Electronic spectra of butadiene and its methyl derivatives: A multiphoton ionization study

1980 • 45 citations

Soliton formation and cis trans isomerization in polyacetylene

1980 • 45 citations

1,6-Diphenyl-1,3,5-hexatriene as a fluorescence standard

1974 • 41 citations

Electronic spectroscopy of propadiene (allene) by electron impact

1975 • 39 citations

A search for a low-lying excited1 a state in 1,3,5-hexatriene

1977 • 39 citations

Raman Spectrum of 1,3-Butadiene in the Gaseous and Liquid States*

1950 • 36 citations

Rotational fine structure of an infra-red of butadiene and the length of the central CC bond

1967 • 35 citations

The crystal structure of 15,15'-dehydrocanthaxanthin

1968 • 35 citations

S U(2) symmetry for linear polyenes

1981 • 35 citations

The symmetry of the 6.2 eV two-photon Rydberg state in hexatriene from the polarization properties of the multiphoton ionization spectrum

1978 • 34 citations

Generalized oscillator strength for the transition A1B2u ← X1A1g in benzene at initial kinetic energies 400 eV and 500 eV

1977 • 34 citations

High pressure fluorescence studies of radiative and nonradiative processes in diphenyl hexatriene, diphenyl octatetraene, and retinyl acetate

1979 • 32 citations

The excited electronic states of all-trans-1,3,5-hexatriene

1979 • 30 citations

Low frequency vibrations of 1,3-butadiene, 1,3-butadiene-d4, and 1,3-butadiene-d6

1973 • 30 citations

Polarized fluorescence spectra of retinol ad diphenyl octatetraene

1973 • 29 citations

Geometric effects in the excited states of conjugated trienes

1979 • 28 citations

Length dependence of excitation energies in linear polyenes: Localized and delocalized descriptions

1976 • 28 citations

An efficient approach to CI: General matrix element formulas for spin-coupled particle–hole excitations

1980 • 27 citations

Planar Vibrations of Carbon Skeleton of Polyenes

1969 • 27 citations

Absolute total cross sections for scattering of hydrogen atoms by argon, krypton and xenon

1972 • 27 citations

The band gap in linear polyenes

1977 • 26 citations

Electronic relaxation processes in retinol and retinal: anomalous external heavy-atom effects and temperature dependence of fluorescence

1976 • 25 citations

100 eV electron impact excitation spectra of 1,3,5-hexatriene

1975 • 25 citations

Comment: Reinterpretation of hexatriene spectrum and comparison with theory

1975 • 24 citations

The low frequency normal modes of trans, trans-1,3,5,7-octatetraene

1979 • 23 citations

Low-energy electron impact excitation of 1,3,5-trans-hexatriene

1973 • 23 citations

Excited electronic states of ketene

1976 • 22 citations

Electronic spectra of carotenoids. β-Carotene

1974 • 21 citations

Convergence of valence bond and molecular orbital theories

1973 • 20 citations

Polarity of 1,3-butadiene, 2,3-dichloro-1,3-butadiene, and their van der Waals adducts with ethylene

1973 • 20 citations

Polarization of the Lowest-Energy Allowed Transition of β-Ionylidene Crotonic Acid and the Electronic Structure of the Polyenes

1966 • 18 citations

Spectroscopic studies of trans -l,6-diphenyl-1,3,5-hexatriene in ordered liquid crystal solutions

1973 • 18 citations

Radiative Lifetime Anomalies

1976 • 17 citations

Anomalous V1←N vibrational band intensities in the low energy electron impact spectra of t r a n s-dienes

1980 • 14 citations

Electronic spectroscopy of stilbene in bibenzyl crystals: spectra of stilbene dimers

1979 • 13 citations

Influence of the long-range coulomb interaction upon the energy spectrum of infinite polyenes

1980 • 12 citations

Spectroscopy of 2,4,6,8,10-dodecapentaenal: Laser site selection of a retinal analog

1981 • 12 citations

Classification of π-Electron States¹

1956 • 11 citations

Spectral and photophysical behavior of 2,4,6,8,10-dodecapentaenal and schiff base: evidence for a low-lying singlet excited state of forbidden character

1979 • 10 citations

Vibronic structure of the second triplet state of 1,3,5-hexatriene

1978 • 8 citations

The first excited singlet valence states of trans-polyenes and α,υ-diphenyl-trans-polyenes

1978 • 6 citations

Comment on ’’Environmental effects on radiative rate constants with applications to linear polyenes’’

1979 • 4 citations

The lowest excited singlet states of 1-arylbutadienes: photochemical implications

1977 • 2 citations