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Some Implications in Carbohydrate Chemistry of Theories Relating to the Mechanisms of Replacement Reactions

Data up to Jan 2025

Published1954
Citations119
References127

Total Citations Per Year

Abstract

References (127)

Ueber einige Derivate des Traubenzuckers und der Galactose

1901 • 694 citations

The Shape of Pyranoside Rings

1950 • 223 citations

Cuprammonium-Glycoside Complexes

1951 • 175 citations

The Reaction of 2,3,4,6-Tetrabenzoyl-α-D-glucopyranosyl Bromide and 2,3,4,6-Tetrabenzoyl-α-D-mannopyranosyl Bromide with Methanol. Certain Benzoylated Derivatives of D-Glucose and D-Mannose

1950 • 173 citations

Eine neue Methode zur Synthese von Glykosiden der Phenole 1 ).

1933 • 173 citations

Concerted Displacement Reactions. VII. The Mechanism of Acid—Base Catalysis in Non-aqueous Solvents1

1952 • 154 citations

Polarimetry, saccharimetry and the sugars

1942 • 154 citations

The Structure of Molecules Containing Cyclohexane or Pyranose Rings.

1947 • 150 citations

d‐Idose aus d(+)‐Galaktose

1945 • 133 citations

Chemical Effects of Steric Strains. I. The Effect of Structure upon the Hydrolysis of Tertiary Aliphatic Chlorides

1949 • 121 citations

The Role of Neighboring Groups in Replacement Reactions. I. Retention of Configuration in the Reaction of Some Dihalides and Acetoxyhalides with Silver Acetate1

1942 • 115 citations

The Preparation and Rearrangement of Phenylglycosides

1942 • 110 citations

The Role of Neighboring Groups in Replacement Reactions. XII. Rates of Acetolysis of 2-Substituted Cyclohexyl Benzenesulfonates1

1948 • 104 citations

139. Methylglucosaminide : its structure, and the kinetics of its hydrolysis by acids

1938 • 100 citations

A NOTE ON THE ACTION OF SILVER SALTS OF ORGANIC ACIDS ON BROMOACETYL SUGARS. A NEW FORM OF TETRAACETYL l-RHAMNOSE

1939 • 99 citations

The Stability of Chelate Compounds. III. Exchange Reactions of Copper Chelate Compounds

1946 • 94 citations

Kohlenhydrate II. Über ein neues, das 1,2-Anhydrid der Glucose.

1922 • 93 citations

Über Acetobrom‐rhamnose und ihre Verwendung zur Synthese von Rhamnosiden

1920 • 93 citations

Relative Reactivities of Hydroxyl Groups of Carbohydrates

1953 • 92 citations

THE ISOMERIC TETRACETATES OF XYLOSE, AND OBSERVATIONS REGARDING THE ACETATES OF MELIBIOSE, TREHALOSE AND SUCROSE.

1915 • 87 citations

Crystalline α-Methyl-D-altroside and Some New Derivatives of D-Altrose1

1941 • 86 citations

THE MERCAPTOLYSIS OF GLUCOSE AND GALACTOSE PENTAACETATES

1951 • 86 citations

A CHEMICAL SYNTHESIS OF SUCROSE

1953 • 83 citations

The Role of Neighboring Groups in Replacement Reactions. XIII.1 General Theory of Neighboring Groups and Reactivity

1948 • 79 citations

1,5-Anhydro-xylitol

1947 • 74 citations

Ueber die isomeren Acetohalogen‐Derivate des Traubenzuckers und die Synthese der Glucoside1

1901 • 72 citations

A PROPOSED INVERSION MECHANISM FOR THE FORMATION OF LEVOGLUCOSAN FROM PHENYL β-D-GLUCOSIDE AND TRIMETHYLGLUCOSYLAMMONIUM COMPOUNDS

1945 • 72 citations

The Role of Neighboring Groups in Replacement Reactions. XI. Some Reactivities Involving Neighboring Groups1

1948 • 58 citations

The theory of resonance and its application to organic chemistry

1945 • 57 citations

Alpha and beta methyl lyxosides, mannosides, gulosides, and heptosides of like configuration

1940 • 57 citations

Sugar acetates, acetylglycosyl halides and orthoacetates in relation to the Walden inversion

1941 • 55 citations

The theory of resonance and its application to organic chemistry

1944 • 55 citations

A NEW SYNTHESIS OF β-GLUCOPYRANOSIDES

1953 • 54 citations

THE ALPHA AND BETA 1,3,4,6-TETRAACETYL-<scp>D</scp>-GLUCOPYRANOSES AND THEIR CHLOROACETYL DERIVATIVES

1953 • 53 citations

Kinetic Evidence for a Termolecular Mechanism in Displacement Reactions of Triphenylmethyl Halides in Benzene Solution

1948 • 53 citations

Über die Einwirkung von Titan (IV)‐chlorid auf Zucker‐Derivate, I.: Neue Methode zur Darstellung der α‐Aceto‐chlor‐zucker und Umlagerung des β‐Methyl‐glucosids in seine α‐Form

1928 • 49 citations

400. Deoxy-sugars. Part V. A reinvestigation of the glycal method for the synthesis of 2-deoxy-D- and -L-ribose

1949 • 48 citations

N-(3,4,6-Triacetyl-D-glucosyl)-piperidine and Its Use in Preparing 2-Substituted Glucose Derivatives

1952 • 46 citations

Syntheses of Epi-lactose and Lactose

1942 • 45 citations

Chemistry of the Carbohydrates and Glycosides

1940 • 44 citations

Über Fluor‐Derivate von Kohlehydraten

1929 • 42 citations

Carbohydrate Orthoesters

1945 • 41 citations

Einwirkung von Quecksilbersalzen auf Aceto‐halogenzucker, IV. Mitteil.: Direkte Darstellung der Alkylbioside der α‐Reihe

1930 • 40 citations

Eine neue Methode zur Gewinnung von Anhydrozuckern

1921 • 40 citations

Mechanisms for the formation of acetylglycosides and orthoesters from acetylglycosyl halides

1949 • 40 citations

THE MECHANISMS OF GLUCOSE PENTAACETATE ANOMERIZATION AND LEVOGLUCOSAN FORMATION

1952 • 40 citations

Action of Strong Acids on Acetylated Glycosides. I. Transformation of some Aliphatic Tetraacetyl-beta-Glucosides to the a-Form.

1948 • 40 citations

Action of Strong Acids on Acetylated Glucosides. III. Strong Acids and Aliphatic Glucoside Tetraacetates in Acetic Anhydride-Acetic Acid Solutions.

1949 • 39 citations

Reductive Cleavage of Benzyl Glycosides for Relating Anomeric Configurations. Preparation of Some New Benzyl Pentosides1

1951 • 39 citations

Darstellung der β‐Tetraacetyl‐ribofuranose

1950 • 38 citations

New Tribenzoyl-D-ribopyranosyl Halides and Their Reactions with Methanol

1951 • 37 citations

The Role of Neighboring Groups in Replacement Reactions. X.1 Kinetics of Solvolysis of trans-2-Acetoxycyclohexyl p-Toluenesulfonate2

1948 • 36 citations

ACETYL MONOSES

1931 • 36 citations

CCCCXV.—Glucosides. Part I. The formation of glucosides from 3 : 4 : 6-triacetyl glucose 1 : 2-anhydride

1928 • 35 citations

Glucoside und β‐1,3,4,6‐Tetraacetyl‐glucose aus Triacetyl‐glucosan‐α&lt;1,2&gt;β&lt;1,5&gt;

1948 • 35 citations

598. Deoxy-sugars. Part VII. A study of the reactions of some derivatives of 2-deoxy-<scp>D</scp>-glucose

1949 • 35 citations

The Reaction of Tribenzoyl-β-D-arabinopyranosyl Bromide and Tribenzoyl-α-D-xylopyranosyl Bromide with Methanol

1950 • 35 citations

Reactions of halides in solution

1951 • 35 citations

1,5-Anhydroribitol

1948 • 34 citations

Action of Strong Acids on Acetylated Glycosides. V. Synthesis of beta-Isomaltose Octaacetate.

1949 • 33 citations

Keto-Fructose Pentaacetate

1934 • 33 citations

Synthesis of 2-Naphthyl β-D-Glucopyruronoside and 2-Naphthyl β-D-Glucofururonolactone and their Behavior toward β-D-Glucuronidase1

1952 • 33 citations

Notiz über die Acetohalogen‐glucosen und die p‐Bromphenylosazone von Maltose und Melibiose

1911 • 32 citations

Crystalline Acetal Derivatives of d-Arabinose1

1937 • 32 citations

A CHEMICAL SYNTHESIS OF OCTA-O-ACETYL-β-<scp>D</scp>-MALTOSE

1953 • 32 citations

ACETYL MONOSES

1931 • 31 citations

beta-d-Talose and d-talose acetates and orthoesters

1937 • 31 citations

The Alkaline Hydrolysis of Phenyl beta-Glucosides. A Kinetic Investigation.

1950 • 31 citations

Über die isomere, linksdrehende Aceto‐chlor‐glucose

1926 • 31 citations

The Synthesis of Oligosaccharides

1951 • 30 citations

Concerted Displacement Reactions. II. Termolecular Displacement Reactions of Methyl Halides in Benzene Solution1

1948 • 29 citations

Cyclische Acetate in der Zucker‐Gruppe. 22. Mitteilung über Aceton‐Zucker und andere Verbindungen der Kohlehydrate

1930 • 28 citations

The Reaction of Tetraacetylglucosyl Chloride with Aromatic Hydrocarbons in the Presence of Aluminum Chloride

1945 • 28 citations

Über Schwefelsäure‐Verbindungen der Zucker, II. Mitteil.: Eine Reaktion zur Unterscheidung ring‐isomerer acylierter Halogenzucker

1929 • 26 citations

The Role of Neighboring Groups in Replacement Reactions. XX. Some Conversions of Cyclopentane and Indan Derivatives1

1953 • 26 citations

Synthesis of Phenyl β-D-Glucopyruronoside1

1953 • 26 citations

Zur Kenntnis der Konfiguration der α‐ und β‐ Formen in der Zucker‐Reihe

1930 • 26 citations

Notiz über Pentacetyldextrose

1889 • 25 citations

CCXXII.—Glucosides. Part II. The preparation of α-glucosides from β-glucosyl chlorides

1929 • 25 citations

Nomenclature of Cyclohexane Bonds

1954 • 24 citations

The Acid-catalyzed Anomerization of the D-Glucose Pentaacetates. A Kinetic Thermodynamic and Mechanistic Study1

1951 • 24 citations

The Anomerization of Sugar Acetates. Glucose Pentaacetates in Acetic Acid—Acetic Anhydride Mixtures Catalyzed by Sulfuric and Perchloric Acids

1953 • 23 citations

CCCXCVI.—Synthesis of a new disaccharide, neotrehalose

1931 • 22 citations

THE ISOMERIC TETRACETATES OF l-ARABINOSE AND BETA-TRIACETYL-METHYL-l-ARABINOSIDE.

1918 • 22 citations

CONVERSION OF GALACTOSE PENTACETATE TO AN ISOMERIC FORM.

1915 • 22 citations

Über die Umlagerung zwischen einigen isomeren Glukosederivaten und die Mutarotation der Zuckerarten

1905 • 21 citations

ACETYL MONOSES

1928 • 21 citations

Some Reactions of 2,3,4-Tribenzoyl-β-D-ribopyranosyl Bromide

1948 • 20 citations

The Beta to Alpha Transformation of Fully Acetylated Glycosides by Alkali.

1950 • 20 citations

Neighboring Carbon and Hydrogen. XII. Internal Rearrangement in Solvolysis of 3-Phenyl-2-butyl p-Toluenesulfonate1

1952 • 20 citations

The Formation of Anhydro Derivatives by the Action of Alkali upon Some Mononitrate-acetates of Glucose and Methylglucoside

1944 • 20 citations

MECHANISM OF THE FORMATION OF LEVOGLUCOSAN

1950 • 20 citations

Biose aus Methylbiosid. Synthese der 2‐(β‐Glucosido)‐glucose

1936 • 20 citations

THE ISOMERIC PENTACETATES OF MANNOSE.

1915 • 20 citations

Über die β′‐Aceto‐chlor‐glucose (II. Mitteilung)

1928 • 19 citations

�berf�hrung ein- und zweiwertiger Phenole in acetylierte?-d-Glucoside mit?-Pentaacetyl-d-glucose und Borfluorid

1949 • 19 citations

The Chemistry of Ribose

1951 • 19 citations

Umlagerung der β‐Glykoside und β‐Acetylzucker in ihre α‐Form

1928 • 18 citations

The Analytical Separation of Various Classes of Sugars

1938 • 17 citations

Friedel-Crafts and Grignard Processes in the Carbohydrate Series

1951 • 17 citations

157. Glucurone

1944 • 16 citations

Reactions of Polyacylglycosyl Halides with Organocadmium Reagents

1950 • 15 citations

Role of Neighboring Groups in Replacement Reactions. XIX. Polarimetric Acetolysis Rate of trans-2-Acetoxycyclohexyl p-Toluenesulfonate

1952 • 15 citations

Acetyl derivatives of certain heptoses, of gulose, and of lactulose

1945 • 15 citations

The Beta to Alpha Conversion of Fully Acetylated Sugars by Alkali

1937 • 15 citations

Opitcal rotation and atomic dimension - Halogeno-tetra-acetyl-derivatives of mannose. Their configurational peculiarities

1931 • 15 citations

Synthesen in der Kohlenhydrat‐Gruppe mit Hilfe von sublimiertem Eisenchlorid, I.: Darstellung der Bioside der α‐Reihe

1929 • 13 citations

Über die Halogenosen der β‐Reihe und ihre Verwendung zur Synthese, V.: Über die β‐Aceto‐chlor‐galaktose und die β‐Aceto‐chlor‐xylose

1930 • 13 citations

Action of Strong Acids on Acetylated Glycosides. IV. Investigation of Disaccharide Models.

1949 • 12 citations

CCCCI.—Walden inversion in the α-glucoheptose series. The preparation of new derivatives and the determination of the structure of methyl-α-glucoheptoside

1931 • 12 citations

DERIVATIVES OF GLUCURONIC ACID

1935 • 12 citations

The Preparation of Alpha Aldose Acetates from Acetylated Glycosides1

1934 • 11 citations

CLX.—The mechanism of tautomeric interchange and the effect of structure on mobility and equilibrium. Part IV. Further evidence relating to the mechanism of acid catalysis in the mutarotation of nitrogen derivatives of tetra-acetylglucose

1929 • 10 citations

The Effect of Mercuric Bromide on the Hydrolysis of Acetobromoglucose in Acetone.

1947 • 9 citations

Preparation of Methyl 2,3,4-Triacetyl-α-D-xyloside1

1951 • 9 citations

Krystallisierte Tetraacetyl‐α‐glucose

1929 • 9 citations

Action of Strong Acids on Acetylated Glycosides. II. Synthesis of Tetraacetyl-a-tertiary Butylglucoside.

1948 • 8 citations

Action of Strong Acids on Acetylated Glycosides. VI. Transglycosidation of Galactosides.

1950 • 8 citations

Notiz über die Einwirkung von Trimethylamin auf Aceto‐brom‐ l ‐rhamnose (Zucker‐anhydride, II. Mitteil.)

1930 • 8 citations

Action of Strong Acids on Acetylated Glycosides. VII. Transglycosidation of Xylosides.

1950 • 8 citations

Versuche zur Herstellung von 3,4‐Diacetyl‐d‐chinovosan‐α〈1,2〉 β〈1,5〉

1947 • 7 citations

THE ISOMERIC ALPHA AND BETA HEXACETATES OF α-GLUCOHEPTOSE.

1916 • 6 citations

318. Addition compounds of the carbohydrates. Part IV. Potassium hydroxide compounds of the methylglucosides, maltose, amylose, and cellulose

1938 • 6 citations

665. The chlorination of β-<scp>D</scp>-glucopyranose penta-acetate. Abnormal reactions of phosphorus pentachloride

1951 • 5 citations

RELATIONS BETWEEN ROTATORY POWER AND STRUCTURE IN THE SUGAR GROUP. IV. TWO ISOMERIC CRYSTALLINE HEXA-ACETATES OF DEXTRO-ALPHA-MANNOHEPTOSE

1924 • 2 citations

Alkali-sensitive Glycosides of 3-Phenyl-4-hydroxycoumarin

1949 • 2 citations

ABSTRACTS

1936 • 2 citations

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Some Implications in Carbohydrate Chemistry of Theories Relating to the Mechanisms of… (1954) – Advances in carbohydrate chemistry | Metascience Observatory Explorer