Acetylene: Isomerization and Dissociation

Hydrocarbon Bond Dissociation Energies

1982 • 1,961 citations

Electron correlation theories and their application to the study of simple reaction potential surfaces

1978 • 1,027 citations

Molecular Symmetry and Spectroscopy

1979 • 959 citations

The graphical unitary group approach to the electron correlation problem. Methods and preliminary applications

1979 • 363 citations

ANOMALOUS ROTATIONAL LINE INTENSITIES IN ELECTRONIC TRANSITIONS OF POLYATOMIC MOLECULES: AXIS-SWITCHING

1965 • 251 citations

Photodissociation of acetylene at 193.3 nm

1985 • 250 citations

Comprehensive theoretical study of isomers and rearrangement barriers of even-electron polyatomic molecules HmABHn (A, B = carbon, nitrogen, oxygen, and fluorine)

1983 • 217 citations

The 1,2 hydrogen shift: a common vehicle for the disappearance of evanescent molecular species

1979 • 210 citations

Selective vibrational excitation by stimulated emission pumping

1981 • 199 citations

Fluorescence and stimulated emission S1 → S spectra of acetylene: Regular and ergodic regions

1985 • 189 citations

Vinylidene: Potential energy surface and unimolecular reaction dynamics

1984 • 173 citations

The high-resolution visible overtone spectrum of acetylenea)

1983 • 155 citations

Chaos and dynamics on 0.5–300 ps time scales in vibrationally excited acetylene: Fourier transform of stimulated-emission pumping spectrum

1987 • 146 citations

Vinylidene: a very shallow minimum on the C2H2 potential energy surface

1981 • 140 citations

The vinylidene-acetylene isomerization barrier

1981 • 130 citations

Theoretical study of the relative stabilities of C2H2 and Si2H2 conformers

1984 • 125 citations

The vinylidene-acetylene rearrangement. A self-consistent electron pairs study of a model unimolecular reaction

1978 • 118 citations

Observation of X1A1 vinylidene by photoelectron spectroscopy of the C2H2− ion

1983 • 115 citations

Evidence of quantum ergodicity in stimulated emission pumping spectra of acetylene

1985 • 114 citations

Determination of the carbon-hydrogen bond dissociation energies of ethylene and acetylene by observation of the threshold energies of proton formation by synchrotron radiation

1987 • 104 citations

Tunneling in the unimolecular decomposition of formaldehyde: a more quantitative study

1981 • 95 citations

Ab initio studies of (1,2)-hydrogen migrations in open-shell hydrocarbons: vinyl radical, ethyl radical, and triplet methylcarbene

1981 • 90 citations

Absence of an energetically viable pathway for triplet 1,2 hydrogen shifts. A theoretical study of the vinylidene-acetylene isomerization

1978 • 47 citations

An unsuspected Fermi perturbation in the acetylene à 1A u 3ν3 level

1986 • 46 citations

Toward the spectroscopic identification of vinylidene, H2C=C

1981 • 34 citations