Thermodynamics of metastable intermediates in solution

Chemical and Electrochemical Electron-Transfer Theory

1964 • 4,224 citations

Comprehensive Inorganic Chemistry

1973 • 3,014 citations

Comprehensive Chemical Kinetics

1990 • 1,708 citations

Hydrolysis of esters of oxy acids: pK_a values for strong acids; Brønsted relationship for attack of water at methyl; free energies of hydrolysis of esters of oxy acids; and a linear relationship between free energy of hydrolysis and pK_a holding over a range of 20 pK units

1978 • 350 citations

The Organic Chemistry of Phosphorus

1967 • 348 citations

Unsaturated water flow within porous materials observed by NMR imaging

1979 • 304 citations

"Diffraction" and microscopy in solids and liquids by NMR

1975 • 270 citations

Slope of free energy plots in chemical kinetics

1968 • 232 citations

Basicity. Comparison of hydrogen bonding and proton transfer to some Lewis bases

1974 • 216 citations

Unusual slopes of free energy plots in kinetics

1969 • 180 citations

Carbonyl Addition Reactions: Factors Affecting the Hydrate–Hemiacetal and Hemiacetal–Acetal Equilibrium Constants

1975 • 171 citations

A Nuclear Magnetic Resonance Study of the Reversible Hydration of Aliphatic Aldehydes and Ketones. I. Oxygen-17 and Proton Spectra and Equilibrium Constants

1967 • 164 citations

Zeugmatographic high resolution nuclear magnetic resonance spectroscopy. Images of chemical inhomogeneity within macroscopic objects

1975 • 135 citations

Statistical Factors in the Correlation of Rate Constants and Equilibrium Constants

1958 • 121 citations

Tautomerization equilibria for phosphorous acid and its ethyl esters, free energies of formation of phosphorous and phosphonic acids and their ethyl esters, and pK_a values for ionization of the P—H bond in phosphonic acid and phosphonic esters

1979 • 105 citations

Nature of the semipolar XO bond. Comparative ab initio study of H3NO, H2NOH, H3PO, H2POH, H2P(O)F, H2SO, HSOH, HClO, ArO, and related molecules

1979 • 103 citations

Hydration of carboxamides. Evaluation of the free energy change for addition of water to acetamide and formamide derivatives

1974 • 94 citations

Equilibrium constants for a series of simple aldol condensations, and linear free energy relations with other carbonyl addition reactions

1978 • 87 citations

Rate-equilibriums relations and proton-transfer reactions

1972 • 86 citations

31P spectroscopic zeugmatography of phosphorus metabolites

1980 • 80 citations

THE PEROXIDE EFFECT IN THE ADDITION OF REAGENTS TO UNSATURATED COMPOUNDS. XVIII. THE ADDITION AND SUBSTITUTION OF BISULFITE^*

1938 • 75 citations

Imaging of paramagnetic centres in diamond

1979 • 71 citations

Kinetics and thermodynamics of keto-enol tautomerism of simple carbonyl compounds: an approach based on a kinetic study of halogenation at low halogen concentrations

1981 • 69 citations

Velocity measurements in flowing fluids by MNR

1974 • 69 citations

The enol content of simple carbonyl compounds: an approach based upon pK_a estimation

1979 • 68 citations

Simple enols. 1. The generation of vinyl alcohol in solution and its detection and characterization by NMR spectroscopy

1981 • 65 citations

Hydration of acetaldehyde. I. Equilibrium thermodynamic parameters

1967 • 63 citations

Simple enols. 2. Kinetics and mechanism of the ketonization of vinyl alcohol

1982 • 61 citations

Hydration of carboxylic acids and esters. Evaluation of the free energy change for addition of water to acetic and formic acids and their methyl esters

1973 • 61 citations

Hydration of thioesters. Evaluation of the free-energy changes for the addition of water to some thioesters, rate-equilibrium correlations over very wide ranges in equilibrium constants, and a new mechanistic criterion

1978 • 59 citations

Direct observation of simple tetrahedral intermediates

1981 • 56 citations

Effect of the acyl substituent on the equilibrium constant for hydration of esters

1980 • 54 citations

ON THE NATURE OF SULPHUROUS ACID

1958 • 51 citations

Acidity of Acetophenone Enol in Aqueous Solution

1979 • 50 citations

The enol content of simple carbonyl compounds: a thermochemical approach

1979 • 49 citations

Acetal Formation for Ketones and Aromatic Aldehydes with Methanol¹

1965 • 46 citations

Ketonization of enols. Enol content and acid dissociation constants of simple carbonyl compounds

1982 • 42 citations

The Calculation of the Ionization Constants of Inorganic Oxygen Acids from their Structures

1938 • 39 citations

Direct observation of a hydroxyphosphorane in equilibrium with a phosphate ester

1977 • 38 citations

Electron spin resonance imaging of paramagnetic centres in solids

1981 • 33 citations

A phosphoranoxide anion - direct observation and isolation of a stable model for the postulated intermediate in nucleophilic substitution at tetracoordinated phosphinoyl phosphorus

1978 • 31 citations

Tautomeric equilibria and pK_a values for 'sulfurous acid' in aqueous solution: a thermodynamic analysis

1979 • 27 citations

Equilibrium in the addition of hydrogen peroxide, water, and methanol to acetone

1970 • 26 citations

Estimation of the free energies of addition of nucleophiles to conjugated carbonyl compounds and to acyl derivatives

1977 • 25 citations

Peroxide route to pentaoxyphosphoranes

1969 • 24 citations

The enol content of simple carbonyl compounds: a kinetic approach

1979 • 23 citations

The pKa of acetophenone in aqueous solution

1977 • 21 citations

General acid catalyzed breakdown of ketone bisulfites

1978 • 20 citations

From Molecules to Man

1981 • 20 citations

Thermodynamics of ester and orthoester formation from trifluoroacetic acid

1976 • 18 citations

Mechanism of the acid-catalyzed hydrolysis of methyl thiolformate

1972 • 17 citations

Über die Konstitution der sauren Sulfite. II. Die Gleichgewichte der sauren Sulfite in wäßrigen Lösungen auf Grund der R<scp>AMAN</scp>‐Spektren der in Wasser und in Methanol gelösten sowie der kristallisierten Alkalisalze

1955 • 16 citations

Cyclization of glycol monoesters to give hemiorthoesters: a test of the thermochemical method for determining free energies of tetrahedral intermediates

1977 • 16 citations

Intramolecular addition of hydroxy groups to the carbonyl groups of trihaloacetate esters

1973 • 13 citations

Bond-bond Interactions in Organic Oxygen Compounds. Part IV. An Extension of the Bond-bond Interaction Scheme for Aliphatic Alcohols and Ethers to Acetals and Orthoesters. Correlation between the Enthalpies of Formation and Numbers of Carbon Atoms for Normal Alkanols. Ring Strain in Cyclic Ethers and Acetals.

1971 • 12 citations

Carbonyl oxygen exchange of glycol monoesters. Rate and equilibrium constants for the formation of a tetrahedral intermediate

1979 • 11 citations

Bond-Bond Interaction in Organic Oxygen Compounds. Part I. A Bond-Bond Interaction Scheme for Aliphatic Alcohols, Ethers, and Acetals.

1969 • 10 citations

Generation and detection by nuclear magnetic resonance spectroscopy of a simple tetrahedral intermediate, dimethyl hemiorthoformate

1976 • 10 citations

Rate and equilibrium constants for the formation and decomposition of the tetrahedral intermediate of the methanolysis of methyl benzoates

1981 • 9 citations