Vinyl cations in solvolysis reactions

Small-Ring Compounds. VIII. Some Nucleophilic Displacement Reactions of Cyclopropyl, Cyclobutyl, Cyclopentyl and Cyclohexyl p-Toluenesulfonates and Halides

1951 • 113 citations

Preparation and solvolysis of vinyl trifluoromethanesulfonates. I. Evidence for simple alkylvinyl cation intermediates

1969 • 101 citations

Perfluoroalkanesulfonate Esters as Alkylating Agents

1965 • 88 citations

Die Solvolyse von α‐Bromstyrolen Substitution am ungesättigten trigonalen Kohlenstoffatom

1964 • 80 citations

Kinetics and Isotope Effects in Solvolyses of Ethyl Trifluoromethanesulfonate

1968 • 72 citations

Solvolysis of highly unreactive substrates using the trifluoromethanesulfonate (triflate) leaving group

1969 • 66 citations

Nitrosation Reactions of Primary Vinylamines. Possible Divalent Carbon Intermediates¹

1965 • 58 citations

Neighboring‐Group Effects and Rearrangements in Reactions of Cyclopropylmethyl, Cyclobutyl, and Homoallyl Systems

1967 • 54 citations

Aspects of hybridization

1950 • 47 citations

Synthesis and solvolysis of 1-cyclopropyl-1-iodoethylene. Generation of an unusually stable vinyl cation

1969 • 47 citations

Die solvoltische Decarboxylierung von α, β‐ungesättigeten β‐Halogensäuren Fragmentierungsreaktionen, 9. Miteilung

1964 • 45 citations

Progress in the Chemistry of Allene

1966 • 44 citations

Two mechanisms for the acid-catalyzed hydrolysis of enol acetates

1969 • 39 citations

Solvents of Low Nucleophilicity. VIII. Possible Vinyl Cation Intermediates, a 1,4-Chlorine Shift, and Novel Substituent Cleavages in the Reaction of Trifluoroacetic Acid with Alkynes¹

1966 • 38 citations

Stable halo enamines. Possible SN1-type solvolysis

1968 • 35 citations

Preparation and solvolysis of vinyl triflates. IV. Rearrangements involving simple vinyl cations generated by solvolysis

1970 • 35 citations

Solvolysis of sulfonic acid esters of triphenylvinyl alcohol by a heterolytic mechanism

1969 • 34 citations

Nachbargruppeneffekte und Umlagerungen bei Reaktionen von Cyclopropylmethyl‐, Cyclobutyl‐ und Homoallyl‐Systemen

1967 • 33 citations

Solvolysis of triaryliodoethylenes. Structure and selectivity of vinyl cations

1968 • 32 citations

The Decomposition of Cyclopropyldiazonium Ions

1967 • 27 citations

Untersuchungen an Cyclopropanverbindungen, IX. Cyclopropylketone durch Umlagerung von Allenverbindungen

1966 • 26 citations

Vinylic cations from solvolysis. II. Stereochemistry of the SN1 reaction of 1,2-dianisyl-2-phenylvinyl halides

1969 • 26 citations

Säurekatalysierte Cyclodimerisierungen über Vinylkationen als Zwischenstufen

1969 • 23 citations

Effect of substitution on homoallenic participation in solvolyses

1969 • 23 citations

Nitrosation Reactions of Primary Vinylamines. 3-Amino-2-phenylindenone¹

1965 • 22 citations

The Tripropynylcarbonium Ion. Charge Delocalization in Ethynyl- and Propynylcarbonium Ions

1965 • 21 citations

Kinetically linear vinyl cations in the solvolysis of stereoisomeric 1-iodo-1-cyclopropylpropenes

1970 • 20 citations

Possible Vinyl Cation Intermediates, a 1,4-Chlorine Shift, and a Trimerization in the Reaction of Trifluoroacetic Acid with Alkynes

1963 • 20 citations

Synthesis of enol sulphonates from carbonyl compounds

1969 • 20 citations

Preparation and reactivity under SNl solvolytic conditions of vinyl tosylates and brosylates

1968 • 19 citations

Vinyl cations. The solvolysis of vinyl sulfonates

1969 • 19 citations

Hydration vs. solvolysis of an activated vinyl halide

1970 • 18 citations

1‐tert.‐Butyl‐vinyl‐trifluormethansulfonat: Solvolyse und Umlagerung über ein Vinylkation

1970 • 18 citations

1,2-Methyl shift to a vinyl cation

1970 • 17 citations

Reaction of silver nitrate with vinyl bromides

1969 • 16 citations

Mesomeric vinyl cations

1969 • 14 citations

Photochemistry of organic nitrogen compounds. Part III. The formation of allenes and 1,3-dienes from pyrazolenines: a photochemical reaction involving ion-pairs

1967 • 8 citations

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