Hydrotalcite-type anionic clays: Preparation, properties and applications.

Anion-Exchange Properties of Hydrotalcite-Like Compounds

1983 • 1,618 citations

The Syntheses of Hydrotalcite-Like Compounds and Their Structures and Physico-Chemical Properties—I: the Systems Mg²⁺-Al³⁺-NO₃⁻, Mg²⁺-Al³⁺-Cl⁻, Mg²⁺-Al³⁺-ClO₄⁻, Ni²⁺-Al³⁺-Cl⁻ and Zn²⁺-Al³⁺-Cl⁻

1975 • 958 citations

Synthesis of anionic clay minerals (mixed metal hydroxides, hydrotalcite)

1986 • 820 citations

Physico-Chemical Properties of Synthetic Hydrotalcites in Relation to Composition

1980 • 807 citations

Catalytic synthesis of methanol from CO/H2I. Phase composition, electronic properties, and activities of the Cu/ZnO/M2O3 catalysts

1979 • 575 citations

The crystal structure of pyroaurite

1968 • 539 citations

Catalytic reactions by thermally activated, synthetic, anionic clay minerals

1985 • 524 citations

The nature of the thermal decomposition of a catalytically active anionic clay mineral

1986 • 520 citations

Crystal structures of some double hydroxide minerals

1973 • 501 citations

Selective Oxidation and Ammoxidation of Propylene by Heterogeneous Catalysis

1981 • 397 citations

Synthesis of isopolymetalate-pillared hydrotalcite via organic-anion-pillared precursors

1988 • 395 citations

IR characteristics of hydrotalcite-like compounds

1985 • 376 citations

Synthesis of Hydrotalcite-Like Compounds and their Physico-Chemical Properties—The Systems Mg2+-Al3+-SO42− and Mg2+-Al3+-CrO42−

1977 • 308 citations

Methane-Steam Reforming

1980 • 299 citations

Synthesis of hydrotalcite-like compounds and their physico-chemical properties

1988 • 295 citations

Pillaring of layered double hydroxides (LDH's) by polyoxometalate anions

1988 • 288 citations

C1-C6 alcohols from synthesis gas on copper-cobalt catalysts

1982 • 265 citations

The influence of lanthanum oxide on the thermal stability of gamma alumina catalyst supports

1983 • 262 citations

SYNTHESIS OF NEW HYDROTALCITE-LIKE COMPOUNDS AND THEIR PHYSICO-CHEMICAL PROPERTIES

1973 • 227 citations

The crystal structures of sjögrenite and pyroaurite

1967 • 206 citations

Crystal-Chemical Study of Layered [Al₂Li(OH)₆]⁺X⁻·nH₂O

1982 • 188 citations

Catalysts for low-temperature methanol synthesis. Preparation of Cu$z.dbnd;Zn$z.dbnd;Al mixed oxides via hydrotalcite-like precursors

1984 • 188 citations

Segregation and cation-ordering in sjögrenite and pyroaurite

1969 • 187 citations

Adsorption of various anions by magnesium aluminum oxide of (Mg0.7Al0.3O1.15)

1986 • 184 citations

Mixed magnesium-aluminiun hydroxides. I. Preparation and characterization of compounds formed in dialysed systems

1967 • 182 citations

The system MgO-Al 2 O 3 -H 2 O and influence of carbonate and nitrate ions on the phase equilibria

1953 • 173 citations

Coprecipitated nickel–alumina catalysts for methanation at high temperature. Part 1.—Chemical composition and structure of the precipitates

1981 • 172 citations

The rapid formation of crystalline double hydroxy salts and other compounds by controlled hydrolysis

1984 • 167 citations

A chain growth scheme for the higher alcohols synthesis

1984 • 154 citations

The higher alcohol synthesis over promoted Cu/ZnO catalysts

1983 • 151 citations

Syntheses of Disordered and Al-Rich Hydrotalcite-Like Compounds

1986 • 144 citations

A new synthesis and characterization of magnesium-aluminium hydroxides

1980 • 143 citations

Methanol and C2 oxygenate synthesis over cesium doped Cu/ZnO and Cu/ZnO/Al2O3 catalysts: A study of selectivity and 13C incorporation patterns

1988 • 143 citations

Anion exchange in lithium aluminate hydroxides

1989 • 135 citations

Anion-exchange in takovite : applications to other hydroxide minerals

1980 • 135 citations

Evidence for the participation of surface nickel aluminate sites in the steam reforming of methane over nickel/alumina catalysts

1978 • 135 citations

Preparation and thermal reactivity of nickel/chromium and nickel/aluminium hydrotalcite-type precursors

1991 • 133 citations

Pillaring of a layered double hydroxide by polyoxometalates with Keggin-ion structures

1989 • 129 citations

New Members of the Hydrotalcite-Manasseite Group

1987 • 128 citations

Anion-exchanged clay (hydrotalcite-like compounds) modified electrodes

1987 • 128 citations

Zur Kenntnis der Doppelhydroxyde und basischen Doppelsalze III. Über Magnesium‐Aluminiumdoppelhydroxyd

1942 • 126 citations

Mixed magnesium-aluminium hydroxides. II. Structure and structural chemistry of synthetic hydroxycarbonates and related minerals and compounds

1967 • 123 citations

Coprecipitated nickel–alumina catalysts for methanation at high temperature. Part 2.—Variation of total and metallic areas as a function of sample composition and method of pretreatment

1981 • 120 citations

Thermal Behavior of Hydrotalcite and of Anion-Exchanged Forms of Hydrotalcite

1980 • 119 citations

Aldol Condensation Reaction between Formaldehyde and Acetone over Heat-Treated Synthetic Hydrotalcite and Hydrotalcite-Like Compounds

1988 • 118 citations

Pulse microreactor examination of the vapor-phase aldol condensation of acetone

1980 • 113 citations

Preparation and Characterization of Al-Rich Zn-Al Hydrotalcite-Like Compounds

1989 • 112 citations

[Zn₂Cr(Oh)₆]X·2H₂O, New Layer Compounds Capable of Anion Exchange and Intracrystalline Swelling

1977 • 111 citations

Catalytic SOx abatement: the role of magnesium aluminate spinel in the removal of SOx from fluid catalytic cracking (FCC) flue gas

1988 • 110 citations

The crystal chemistry and paragenesis of honessite and hydrohonessite: the sulphate analogues of reevesite

1981 • 107 citations

Über die Bildung von Doppelhydroxyden zwischen zwei‐ und dreiwertigen Metallen

1942 • 106 citations

Preparation and chemical properties of magnesium aluminium oxide solid solutions

1986 • 97 citations

Anion‐Aluminum Hydroxide Gel Interactions

1977 • 95 citations

The Polymerization of β-Propiolactone by Calcined Synthetic Hydrotalcite

1979 • 92 citations

Layered double hydroxides as supported anionic reagents. Halide-ion reactivity in zinc chromium hexahydroxide halide hydrates [Zn2Cr(OH)6X.nH2O] (X = Cl, I)

1986 • 91 citations

Interlamellar chemistry of hydrotalcites

1987 • 87 citations

The formation of ketones in the presence of carbon monoxide over CuO/ZnO/Al2O3

1989 • 87 citations

Anionic photocatalysts supported in layered double hydroxides: intercalation and photophysical properties of a ruthenium complex anion in synthetic hydrotalcite

1987 • 87 citations

Reactions of CO and CO2 on Ni/SiO2 above 373 K as studied by infrared spectroscopic and magnetic methods

1978 • 85 citations

Structure and reactivity of oxovanadate anions in layered lithium aluminate materials

1989 • 83 citations

Desirable catalyst properties in selective oxidation reactions

1986 • 82 citations

Higher alcohol and oxygenate synthesis over Cs/Cu/ZnO/M2O3 (M $z.dbnd; Al, Cr) catalysts

1989 • 82 citations

Mechanism of the steam reforming of methane over a coprecipitated nickel-alumina catalyst

1973 • 79 citations

Anion intercalation and exchange in Al(OH)3-derived compounds

1985 • 78 citations

Hydrolysis of Aluminum-Tri-(Sec-Butoxide) in Ionic and Nonionic Media

1977 • 78 citations

Preparation and characterization of stable copper/zinc oxide/alumina catalysts for methanol systhesis

1986 • 68 citations

Carbonaceous deposition associated with the catalytic steam-reforming of hydrocarbons over nickel alumina catalysts

1981 • 68 citations

Adsorption of N2, O2, CO2 and H2 on Hydrotalcite-Like System: Mg2+-Al3+-(Fe(CN)6)4−

1978 • 67 citations

Copper oxide-zinc oxide-alumina catalyst: The structure of a copper oxide-zinc oxide-alumina catalyst for methanol synthesis

1978 • 65 citations

Catalysts for low-temperature methanol synthesis

1985 • 63 citations

Alkali promotion of nickel catalysts for carbon monoxide methanation

1978 • 63 citations

Decavanadate ion-pillared hydrotalcite: spectroscopic studies of the thermal decomposition process

1990 • 63 citations

Physico-chemical Properties and Structure of Magnesia-alumina

1971 • 61 citations

Cobalt mixed spinels as catalysts for the synthesis of hydrocarbons

1987 • 61 citations

Alkali-Promoted Copper-Zinc Oxide Catalysts for Low Alcohol Synthesis

1985 • 57 citations

Structural Survey of Carbonate-Containing Antacids

1978 • 56 citations

Characterization and catalytic activity of cobalt-chromium mixed oxides

1990 • 56 citations

High temperature methanation in the long-distance nuclear energy transport system

1981 • 55 citations

Mechanism of ethanol formation from synthesis gas over CuO/ZnO/Al2O3

1988 • 55 citations

Structure and reactivity of zinc–chromium mixed oxides. Part 1.—The role of non-stoichiometry on bulk and surface properties

1988 • 54 citations

Some aspects of the control of selectivity in catalytic oxidation on mixed oxides:a review

1984 • 53 citations

The influence of high partial steam pressures on the sintering of lanthanum oxide doped gamma alumina

1984 • 51 citations

Thermal stability of aluminium hydroxycarbonates with monovalent cations

1985 • 48 citations

Synthesis of alcohols from carbon oxides and hydrogen. 4. Lumped kinetics for the higher alcohol synthesis over a zinc-chromium-potassium oxide catalyst

1987 • 47 citations

The effect of Ni-Al ratio on the properties of coprecipitated nickel-alumina catalysts with high nickel contents

1986 • 44 citations

Structure and reactivity of Zn-Cr mixed oxides. Role of non-stoichiometry in the catalytic synthesis of methanol

1989 • 44 citations

Thermal stability of Ni, Al double hydroxides with various interlayer anions

1984 • 43 citations

Hydrohonessite—a new hydrated Ni-Fe hydroxy-sulphate mineral; its relationship to honessite, carrboydite, and minerals of the pyroaurite group

1981 • 42 citations

Cobalt catalysts for the production of alcohols in the F.T. Synthesis

1989 • 42 citations

Über die katalytischen Wirkungen des nickelierten Tonerde‐Hydrats

1924 • 42 citations

Structural approach and conductivity of lamellar hydroxides Zn2Cr(OH)6X.nH2O (x = anion) by xanes, exafs and X-ray diffraction

1985 • 42 citations

Non-stoicheiometric Zn–Cr spinel as active phase in the catalytic synthesis of methanol

1984 • 39 citations

Meixnerite, Mg6Al2(OH)18�4H2O, a new magnesium-aluminum-hydroxide mineral

1975 • 39 citations

Polymerization of propylene oxide by calcined synthetic hydrotalcite

1981 • 38 citations

Structure and reactivity of zinc–chromium mixed oxides. Part 2.—Study of the surface reactivity by temperature-programmed desorption of methanol

1988 • 37 citations

Sintering of nickel-alumina catalysts

1972 • 36 citations

Paracrystallinity in a coprecipitated nickel/alumina catalyst

1982 • 34 citations

X-ray absorption spectroscopy study of copper-based methanol catalysts. 1. Calcined state

1985 • 34 citations

Structure and reactivity of zinc–chromium mixed oxides. Part 3.—The surface interaction with carbon monoxide

1989 • 33 citations

Zinc Oxide–Chromium Oxide Catalysts for Methanol Synthesis

1935 • 33 citations

The promoting role of Cr and K in catalysts for high-pressure and high-temperature methanol and higher-alcohol synthesis

1987 • 32 citations

Synthesis of higher alcohols over promoted copper catalysts

1987 • 32 citations

The effect of sodium on the methanation activity of nickel/alumina coprecipitated catalysts

1981 • 32 citations

Thermal stability of Mg,Al double hydroxides modified by anionic exchange

1982 • 31 citations

The effect of lanthanum additives on the catalytic activities of Ni-Al2O3 coprecipitated catalysts for the methanation of carbon monoxide

1984 • 30 citations

Stereoselective exchange kinetics of L- and D-histidines for chloride ion in the interlayer of a hydrotalcite-like compound by the chemical relaxation method

1984 • 30 citations

Production of Methanol-Higher Alcohol Mixtures from Natural Gas via Syngas Chemistry

1990 • 29 citations

Motukoreaite, a new hydrated carbonate, sulphate, and hydroxide of Mg and Al from Auckland, New Zealand

1977 • 28 citations

Catalysts for low-temperature methanol synthesis. I. A study of the reduction process

1982 • 27 citations

The sintering of coprecipitated nickel alumina catalysts

1984 • 25 citations

Mountkeithite, a new pyroaurite-related mineral with an expanded interlayer containing exchangeable MgSO₄

1981 • 24 citations

Direct synthesis of higher alcohols using bimetallic copper/cobalt catalysts

1988 • 23 citations

Motukoreaite—additional data and comparison with related minerals

1979 • 22 citations

Magnetic Susceptibility Studies in the Dual Hydrous Oxide System NiO–Al₂O₃

1955 • 20 citations

The effect of preparation conditions on the activity and stability of copreciptitated Ni/Al2O3 catalysts for the methanation of carbon monoxide

1978 • 20 citations

Effect of temperature of reduction on the activity and selectivity of a coprecipitated Ni–Al₂O₃catalyst for the Fischer–Tropsch and methanation reactions

1977 • 20 citations

Granulometrie et masse metallique de catalyseurs ferromagnetiques finement divises calculees d'apres les courbes aimantation-champ magnetique

1973 • 19 citations

The removal of aluminum from the recovery system of a closed kraft pulp mill

1987 • 19 citations

Über Mischsalz‐Kontakte und ihre Anwendungen

1956 • 18 citations

Wermlandite, a new mineral from Långban, Sweden

1971 • 18 citations

The morphology of coprecipitated nickel-alumina catalysts

1983 • 18 citations

Thermal stability of lithium aluminium hydroxy salts

1986 • 17 citations

Kinetic study of the reduction of copper-zinc-aluminum mixed oxide catalysts

1986 • 17 citations

New data on woodwardite

1976 • 17 citations

The steam reforming of ethane over nickel/alumina catalysts

1981 • 15 citations

Magnesium oxide as a catalyst

1967 • 15 citations

Textural properties of hydrotalcite-like compounds

1986 • 15 citations

Discrimination between synthetic MgAl double hydroxides and related carbonate phases

1980 • 13 citations

Heterolytic dissociation of hydrogen on high-temperature methanol synthesis catalysts

1987 • 12 citations

Intestinal absorption of aluminium from antacids: A comparison between hydrotalcite and algeldrate

1986 • 12 citations

Chromite in pyroxenite from the Massif du Sud, southern New Caledonia

1977 • 12 citations

Evidence of the role of non-stoichiometry in Zn-Cr catalysts by thermal investigations

1988 • 10 citations

Charge stabilisation of very small particles of mixed oxides

1977 • 10 citations

Basic Properties of MgO Doped with Alkaline Metal Compounds

1985 • 9 citations

Hydrier‐ und Dehydrierkatalysatoren

1975 • 8 citations

Effects of various agents on prednisolone-induced gastric lesions in rats.

1985 • 7 citations

C Chemistry: Growing Field Despite Crude Oil Price Drop

1986 • 7 citations

[In vitro study of the antipeptic activity of antacid preparations].

1985 • 2 citations

Chemical Community Leaders Look At Change

1986 • 2 citations

Untitled

1984 • 1 citations