The Contribution of Organometallic Chemistry and Homogeneous Catalysis to the Understanding of Surface Reactions

Advanced inorganic chemistry

1999 • 14,227 citations

Catalysis By Metals

1962 • 1,148 citations

Infrared spectroscopy in surface chemistry

1968 • 670 citations

Infrared spectroscopy in surface chemistry

1967 • 631 citations

Hydride complexes of the transition metals

1972 • 577 citations

Introduction to the Principles of Heterogeneous Catalysis

1967 • 550 citations

Reversible activation of covalent molecules by transition-metal complexes. The role of the covalent molecule

1968 • 360 citations

Intramolecular aromatic substitution in transition metal complexes

1970 • 351 citations

Dioxygen ligand in mononuclear Group VIII transition metal complexes

1973 • 325 citations

The influence of crystallite size on the adsorption of molecular nitrogen on nickel, palladium and platinum

1966 • 312 citations

Oxidative-addition reactions of transition metal complexes

1970 • 300 citations

On the specific activity of platinum catalysts

1966 • 286 citations

Cyclooligomerization of Butadiene and Transition Metal π‐Complexes

1963 • 277 citations

Aspects of Homogeneous Catalysis

1978 • 276 citations

Reversible oxygen adduct formation in ferrous complexes derived from a picket fence porphyrin. Model for oxymyoglobin

1973 • 264 citations

Transition metal basicity

1970 • 262 citations

Olefin Coordination Compounds of Rhodium: The Barrier to Rotation of Coordinated Ethylene and the Mechanism of Olefin Exchange

1964 • 241 citations

154. The tautomerism of arene and ditertiary phosphine complexes of ruthenium(0), and the preparation of new types of hydrido-complexes of ruthenium(II)

1965 • 231 citations

.sigma.-Aryl compounds of nickel, palladium, and platinum. Synthesis and bonding studies

1974 • 202 citations

Olefin and acetylene complexes of platinum and palladium

1969 • 197 citations

Chlorotris(triphenylphosphine)iridium(I) and related complexes. Oxidative addition reactions and hydrogen abstraction from the coordinated ligand

1969 • 193 citations

Fluxional organometallic molecules

1968 • 192 citations

Activation of Hydrogen by a Transition Metal Complex at Normal Conditions Leading to a Stable Molecular Dihydride

1962 • 189 citations

Thermodynamic data for olefin and acetylene complexes of transition metals

1973 • 187 citations

Low-Energy Electron-Diffraction Studies of the Adsorption of Unsaturated Hydrocarbons and Carbon Monoxide on the Platinum (111) and (100) Single-Crystal Surfaces

1969 • 181 citations

Homogeneous Hydrogenation

1973 • 179 citations

Transition metal hydrides

1972 • 169 citations

Identification of oxygen species adsorbed on reduced titanium dioxide

1971 • 167 citations

Direct evidence from carbon-13 nuclear magnetic resonance for intramolecular scrambling of carbonyl groups in a metal atom cluster carbonyl, tetrarhodium dodecacarbonyl

1972 • 165 citations

Proton Magnetic Resonance Studies of Structure, Diffusion, and Resonance Shifts in Titanium Hydride

1961 • 161 citations

Organometallic Compounds

1968 • 161 citations

Acetylene Complexes of Iridium and Rhodium

1967 • 153 citations

Structure of and Bonding in an Alkyne-Nonacarbonyltriiron Complex. A New Type of Iron-Acetylene Interaction

1966 • 147 citations

Reactivity of trialkylphosphine complexes of platinum(O)

1971 • 146 citations

Hydride derivatives of niobocene and tantalocene

1971 • 137 citations

Zerovalent platinum chemistry. Part VI. The reactions of bis- and tris-triphenylphosphineplatinum(0) with hydrogen sulphide, hydrogen selenide, sulphur, and related molecules

1971 • 134 citations

Temperature-dependent carbon-13 nuclear magnetic resonance spectra of the h5-cyclopentadienyliron dicarbonyl dimer, an application of a shiftless relaxation reagnet

1972 • 131 citations

Chemisorption and Reactions on Metallic Films

1971 • 130 citations

Fourier-transform carbon-13 nuclear magnetic resonance study of (arene)tricarbonylchromium complexes

1974 • 129 citations

Transition Metals in Homogeneous Catalysis

1972 • 126 citations

Interaction of an aliphatic carbon-hydrogen bond with a metal atom. Structure of (diethyldi-1-pyrazolylborato)(trihapto-2-phenylallyl)(dicarbonyl)molybdenum

1974 • 121 citations

Organometallic Chemistry of the Transition Metals. XIII. Aπ-Benzyl Derivative of Molybdenum with a Temperature-Dependent Proton Nuclear Magnetic Resonance Spectrum¹

1966 • 115 citations

Studies in contact potentials. Part I.—The adsorption of some gases on evaporated nickel films

1950 • 113 citations

Recent developments in transition metal nitrosyl chemistry

1972 • 112 citations

Oxidative addition reactions of triphenylphosphine with dodecacarbonyltriosmium(0) : benzyne-, phenyl-, and related complexes of osmium

1972 • 108 citations

The chemistry of transition-metal carbonyls: structural considerations

1969 • 102 citations

Dinitrogen complexes of the transition metals

1973 • 100 citations

Electron Spin Resonance in Catalysis

1972 • 99 citations

Ligand-metal hydrogen-transfer reactions in triphenyl phosphite and triphenylphosphine complexes

1969 • 93 citations

Molecular Structure of a π‐Dinitrogen‐Nickel‐Lithium Complex

1973 • 90 citations

The Structure and Stability of Hydrocarbon Intermediates on the Surface of Catalysts

1972 • 89 citations

Linkage isomerization in nitrogen-labeled [Ru(NH3)5N2]Br2

1970 • 89 citations

Kinetic investigation of some electronic and steric factors in oxidative addition reactions to Vaska's compound

1972 • 81 citations

Comparison of the bonding in zero- and divalent platinum-olefin and -acetylene complexes from carbon-13 nuclear magnetic resonance parameters. XXII

1972 • 79 citations

Reactions of dodecacarbonyl-triangulo-triosmium with alkenes and benzene; fluxional behaviour of µ₃-(ethan-1-yl-2-ylidyne)-di-µ-hydrido-triangulo-tris(tricarbonylosmium)(3Os–Os)

1974 • 79 citations

Oxidative addition reactions in cluster complexes of osmium: Intracluster reactions of benzyne and a novel 'phenyl' complex

1972 • 78 citations

Cyclopropane complexes of platinum: some sunthetic studies and the reactivity and crystal structure of 1,6-dichloro-2,3-trimethylene-4,5-bis(pyridine)platinum(IV)

1971 • 78 citations

Chemistry of the metal carbonyls. Part LXV. Reactions between dodecacarbonyltriruthenium and tertiary phosphines or arsines

1972 • 77 citations

Reactions of iron atoms with unsaturated hydrocarbons

1972 • 77 citations

Transition metal–carbon bonds. Part XXIX. Some internal metallation reactions of tertiary phosphine ligands with bulky substituents

1971 • 76 citations

Infra-red studies of carbon monoxide and hydrocarbons adsorbed on silica-supported nickel

1966 • 74 citations

Interactions between Lewis bases chemisorbed on transition metal surfaces. Infrared spectroscopic studies

1972 • 70 citations

Definitive identification of the structures of dicyclopentadienyldiiron tetracarbonyl in solution

1970 • 69 citations

Oxidative addition reactions of triphenylphosphine with dodecacarbonyltriosmium

1973 • 68 citations

The importance of $pi;-bonded intermediates in hydrocarbon reactions on transition metal catalysts

1964 • 68 citations

Intramolecular redox equilibriums of cobalt-nitrosyl complexes

1971 • 67 citations

Reactions of tungsten and molybdenum atoms with 1,3-butadiene. Tris (butadiene)tungsten and -molybdenum

1974 • 67 citations

Catalytic exchange of alkylbenzenes with deuterium on nickel films

1962 • 66 citations

The decarbonylation of aldehydes by tris(triphenylphosphine)chlororhodium(I)

1968 • 64 citations

Butadienic derivatives and metal carbonyls II. Some rearrangements of butadienic ligands in reactions with dodecacarbonyltriruthenium

1974 • 63 citations

Nature and reactivity of intermediates in hydrogenation of buta-1,3-diene catalyzed by cobalt and palladium-gold alloys

1966 • 60 citations

Dehydrogenation of organic and inorganic molecules by reaction with Os3 (CO)12

1972 • 59 citations

Reduction of coordinated dinitrogen to the coordinated hydrazido dianion. Structural characterization of the 1-.eta.-hydrazido (2-)chlorobis[1,2-bis(diphenylphosphino)ethane]tungsten(IV) cation

1974 • 59 citations

Surface Potentials and Adsorption Process on Metals

1959 • 57 citations

Crystal structure and molecular geometry of octadecacarbonylhexaruthenium dihydride

1971 • 57 citations

¹H and¹³C nuclear magnetic resonance spectra and X-ray crystal structure of [1-methyl-3-ethyl-(σ-1,3-h²,π-1,2,3-h³)-allyl]nonacarbonyltriruthenium: the allyl group as a five-electron donor

1972 • 55 citations

General introduction—homogeneous catalysis of hydrogenation, oxidation and related reactions

1968 • 54 citations

Crystal and Ligand Field Models of Solid Catalysts

1972 • 53 citations

Infrared investigation of hydrogen adsorption on alumina-supported platinum

1973 • 53 citations

π Complex Adsorption in Hydrogen Exchange on Group VIII Transition Metal Catalysts

1966 • 53 citations

Crystal and Molecular Structure of Metal Ion-Aromatic Complexes. I. The Cuprous Ion-Benzene Complex, C₆H₆·CuAlCl₄

1963 • 53 citations

Reactions involving organometallic compounds of rhodium, iridium, palladium and platinum: A survey of NMR studies

1969 • 51 citations

Structure and dynamical properties of Rh4(CO)12 in solution: 13C nuclear magnetic resonance study

1973 • 51 citations

A tetranuclear cluster complex of copper(<scp>I</scp>) with bridging aryl ligands: the crystal structure of (4-methyl-2-cupriobenzyl)dimethylamine

1972 • 51 citations

π‐Allylhydridonickel Compounds

1970 • 50 citations

Oxidation of coordinated nitric oxide by free nitric oxide

1974 • 50 citations

Conversion and equilibration rates of hydrogen on nickel

1966 • 48 citations

A study of platinum-polyamide catalysts. Catalytic behaviour in the benzene hydrogenation reaction

1973 • 47 citations

Linear Correlations of Substrate Reactivity in Heterogeneous Catalytic Reactions

1967 • 45 citations

The activation of saturated hydrocarbons by transition-metal complexes in solution. Part I. Hydrogen–deuterium exchange in alkanes catalysed by potassium tetrachloroplatinate(<scp>II</scp>) in acetic acid

1971 • 44 citations

Transition metal hydrides

1971 • 44 citations

On the forms of nitrogen adsorbed on iron

1968 • 44 citations

The crystal and molecular structures of a novel μ-allyl palladium complex, μ-allyl-μ-iodo-bis(triphenylphosphinepalladium) benzene solvate

1972 • 44 citations

Coordination and olefin catalysis by transition metals

1967 • 42 citations

Hydrogen-deuterium exchange in a cobalt-nitrogen complex

1968 • 41 citations

Infra-red spectra of chemisorbed molecules - I. Acetylene and ethylene on silica-supported metals

1960 • 40 citations

Carbon–hydrogen cleavage reactions of some trimethyl- and triethyl-phosphine complexes of osmium

1973 • 39 citations

The reaction of dodecacarbonyltriruthenium with bicyclo[3.2.1]-2,6-octadiene

1972 • 39 citations

Stereoselectivity in the complexing of platinum(II) chloride with substituted cyclopropanes

1972 • 39 citations

Reaction of phosphine with some transition metal complexes

1973 • 38 citations

Zerovalent platinum chemistry. III Properties of Bistriphenylphosphineplatinum(0)

1970 • 37 citations

Platinum-acetylene complexes. II. Monosubstituted hydroxyacetylenes

1969 • 37 citations

Reactions of low-valent metal complexes with fluorocarbons. Part XXIX. Zerovalent nickel and platinum complexes with hexafluorobut-2-yne and hexakis(trifluoromethyl)benzene

1974 • 37 citations

Proton, carbon-13, and nitrogen-15 nuclear magnetic resonance studies of a dinitrogen complex of permethyltitanocene. Evidence for molecular nitrogen coordinated edge-on to a transition metal

1974 • 37 citations

Pentacarbonyls of ruthenium and osmium. IV. Synthesis of alkyl- and acetylosmium carbonyls

1969 • 36 citations

8 Catalytic Exchange and Deuteration of Benzene over Evaporated Metallic Films in a Static System

1957 • 36 citations

Activation of covalent molecules by some noble metal complexes: The role of the metal

1971 • 35 citations

Auger spectroscopy and low-energy electron diffraction studies of the chemisorption of unsaturated molecules by the (100) surface of platinum

1972 • 34 citations

Transition metal bonding through a donor-acceptor interaction. (C5H5)2MoH2.Mo(CO)5 and related derivatives

1968 • 33 citations

The nature of the chemical bonding and crystallography of π-cyclopentadienyl-hexakis(trifluoromethyl)benzene rhodium

1966 • 32 citations

Anomalous Temperature Dependence in the Electron Spin Resonance Spectrum of Bis(trifluoromethyl) Nitroxide¹

1966 • 32 citations

Thermal decomposition of bis(triphenylphosphine)(carbonyl)octyliridium(I). New decomposition mechanism for transition metal long chain alkyls

1974 • 31 citations

Metal ion-aromatic complexes. XIV. Structural evidence for the Sn2Cl22+ species in Ar.SnCl(AlCl4)

1972 • 30 citations

Reactions of triruthenium dodecacarbonyl with diphenylacetylene in alkaline solution

1972 • 30 citations

Trivalent phosphorus derivatives of cobalt carbonyls. I. Infrared and N.M.R. studies of new substituted tetracobaltdodecacarbonyl complexes

1972 • 28 citations

Tautomerism and exchange in the boron hydrides; 11B and 1H NMR spectra

1961 • 27 citations

The reaction of deuterium with cyclopropane and methylcyclopropane over evaporated metal films

1967 • 26 citations

On the state of dinitrogen bound to rhenium

1970 • 26 citations

Catalysis by cobalto-cyano complexes in non-aqueous solvents

1968 • 26 citations

Lewis base behavior of einitrogen and carbonyl complexes of rhenium toward titanium tetrachloride and related species

1974 • 26 citations

Preparation and nuclear magnetic resonance investigation of some stereochemically non-rigid derivatives of dodecacarbonyltetrairidium

1974 • 25 citations

1142. Some halido- and hydrido-alkyl and -aryl complexes of ruthenium(II) and osmium(II)

1963 • 25 citations

The Use of Isotopic Tracers in Studying Catalysts and Catalytic Reactions

1972 • 24 citations

Far-infrared spectra of metal-olefin complexes. I. Potassium μ-1,3-butadiene-bis(trichloroplatinate(II))

1967 • 21 citations

An investigation of the high-frequency form of carbon monoxide chemisorbed on nickel oxide

1973 • 21 citations

X-Ray crystal and molecular structures of three methinyl tricobalt enneacarbonyl derivatives

1971 • 21 citations

π-Complexes of PdCl2 with 1,3-butadiene and 1,3-cyclooctadiene

1966 • 20 citations

Fluxional behaviour of some cluster complexes of osmium containing C6H4 as ligands

1972 • 20 citations

The isolation and crystal structure of azulenetriruthenium heptacarbonyl, a probable intermediate in the formation of tetrahedral azulene-ruthenium-carbonyl clusters

1971 • 19 citations

Reaction of tetrafluoroethylene and hexafluorobut-2-yne with nitrosyltris(triphenylphosphine)iridium: X-ray diffraction study of di-µ-hexafluorobut-2-enylene-bis-[cis-triphenylphosphinenitrosyliridium(<scp>I</scp>)]

1972 • 19 citations

A reinterpretation of the mechanism of the heterogeneous catalytic synthesis of ammonia

1969 • 18 citations

Chemisorption Complexes and Their Role in Catalytic Reactions on Transition Metals

1972 • 18 citations

¹³C nuclear magnetic resonance of triacontacarbonyldodecarhodate(2–): [Rh₁₂(CO)₂₀(µ₂-CO)₂-(µ₃-CO)₈]^2–

1974 • 18 citations

Reactions of alkali metal derivatives of metal carbonyls

1972 • 17 citations

Unexpected fluxional behaviour in hexacarbonyl-(π-cycloheptadienyl)-(π-cycloheptatrienyl)triruthenium

1974 • 16 citations

Fluoreszenzmessungen an dünnen Filmen aromatischer Kohlenwasserstoffe

1960 • 12 citations

An e.s.c.a. study of the dissociative and associative chemisorption of halogeno-alkenes and -alkynes on a Pt(100) surface

1974 • 12 citations