Peroxyl Radical Clocks

Mechanisms of free radical oxidation of unsaturated lipids

1995 • 1,158 citations

Free Radicals in Solution.

1958 • 957 citations

Free-radical clocks

1980 • 758 citations

Competition Methods and Scales for Alkyl Radical Reaction Kinetics

1993 • 610 citations

Peroxy radicals

1969 • 420 citations

Mechanisms for the autoxidation of polyunsaturated lipids

1986 • 399 citations

Unified mechanism for polyunsaturated fatty acid autoxidation. Competition of peroxy radical hydrogen atom abstraction, .beta.-scission, and cyclization

1981 • 313 citations

Hypersensitive Radical Probes and the Mechanisms of Cytochrome P450-Catalyzed Hydroxylation Reactions

2000 • 267 citations

Absolute rate constants for hydrocarbon autoxidation. VI. Alkyl aromatic and olefinic hydrocarbons

1967 • 258 citations

Hydroxylamines as Oxidation Catalysts: Thermochemical and Kinetic Studies

2003 • 253 citations

Theoretical Calculations of Carbon−Oxygen Bond Dissociation Enthalpies of Peroxyl Radicals Formed in the Autoxidation of Lipids

2003 • 156 citations

Mechanisms of the Aerobic Oxidation of Alcohols to Aldehydes and Ketones, Catalysed under Mild Conditions by Persistent and Non‐Persistent Nitroxyl Radicals and Transition Metal Salts − Polar, Enthalpic, and Captodative Effects

2003 • 145 citations

Autoxidation of polyunsaturated fatty acids, an expanded mechanistic study

1984 • 141 citations

Factors Influencing the Autoxidation of Fatty Acids: Effect of Olefin Geometry of the Nonconjugated Diene

2004 • 86 citations

Kinetic Products of Linoleate Peroxidation: Rapid β-Fragmentation of Nonconjugated Peroxyls

2001 • 84 citations

Do Peroxyl Radicals Obey the Principle That Kinetic Solvent Effects on H-Atom Abstraction Are Independent of the Nature of the Abstracting Radical?

1998 • 41 citations

Thioimidate N-oxides: nitrones of thio esters

1986 • 37 citations

THE KINETICS OF THE INHIBITED AUTOXIDATION OF TETRALIN. II

1965 • 36 citations

Vanderbilt University

1979 • 28 citations

Mechanism of 1,3-Migration in Allylperoxyl Radicals: Computational Evidence for the Formation of a Loosely Bound Radical−Dioxygen Complex

2003 • 23 citations

The determination of the oxygen consumption in autoxidation studies by means of EPR spectroscopy

1996 • 20 citations

A new method for the determination of oxygen solubilities by EPR

1992 • 15 citations