Hydrogen abstraction reactions by atomic fluorine. III. Temperature dependence of the intermolecular kinetic isotope effect for the thermal F+H2 reaction

Spectra of diatomic molecules

1950 • 5,975 citations

Unimolecular reactions

1975 • 1,997 citations

Theory of Unimolecular Reactions

1973 • 1,377 citations

Gas Phase Reaction Rate Theory

1966 • 1,119 citations

Exchange Reactions with Activation Energy. I. Simple Barrier Potential for (H, H2)

1965 • 975 citations

Monte Carlo Calculations of Energy Partitioning and Isotope Effects in Reactions of Fluorine Atoms with H2, HD, and D2

1971 • 320 citations

Energy Distribution Among Reaction Products. VI. F+H2, D2

1972 • 255 citations

Classical Dynamics of the Reaction of Fluorine Atoms with Hydrogen Molecules. II. Dependence on the Potential Energy Surface

1972 • 245 citations

F + H2, D2, HD reactions: Chemical laser determination of the product vibrational state populations and the F + HD intramolecular kinetic isotope effect

1973 • 205 citations

Crossed Molecular Beam Study of F+D2

1970 • 195 citations

Potential Energy Surface Including Electron Correlation for F + H ₂ → FH + H: Refined Linear Surface

1972 • 163 citations

Monte Carlo trajectories: Dynamics of the reaction F+D2 on a semiempirical valence-bond potential energy surface

1973 • 149 citations

Classical Trajectory Analysis of the Reaction F+H2→HF+H

1971 • 135 citations

Potential Energy Surface Including Electron Correlation for the Chemical F + H2 → FH + H I. Preliminary Surface

1972 • 127 citations

Monte Carlo Calculations of Reaction Rates and Energy Distributions Among Reaction Products. I. F+H2→HF+H

1972 • 111 citations

Classical Dynamics of the Reaction of Fluorine Atoms with Hydrogen Molecules. III. The Hot-Atom Reactions of 18F with HD

1972 • 107 citations

Eine Methode zur Erzeugung von Fluoratomen in inerter Atmosphäre

1970 • 100 citations

Dynamics of the Molecular and Atomic Mechanisms for the Hydrogen-Iodine Exchange Reaction

1972 • 94 citations

Dealing with data

1970 • 93 citations

Variational theory of reaction rates: Application to F+H2⇄HF+H

1973 • 79 citations

Reaction Kinetics of Ground State Fluorine, F(²P), Atoms. I. Measurement of Fluorine Atom Concentrations and the Rates of Reactions F + CHF₃ and F + Cl₂ using Mass Spectrometry

1973 • 66 citations

On the H+F2→HF+F reaction. An ab initio potential energy surface

1973 • 61 citations

Theoretical Studies of Hot-Atom Reactions. I. General Formulation

1966 • 56 citations

Kinetic isotope effects in the reaction of fluorine atoms with molecular hydrogen. I H2/D2 kinetic isotope effect

1973 • 52 citations

Saddle point geometry and barrier height for H + F2 → HF + F

1974 • 52 citations

Hydrogen atom abstraction by fluorine atoms

1973 • 52 citations

Simple kinetic models from Arrhenius to the computer

1974 • 49 citations

Steady state theory of hot atom reactions

1973 • 48 citations

Barrier Height for the Exchange Reaction F + HF → FH + F

1974 • 43 citations

Reactions of Photochemically Produced Hot Hydrogen Atoms. II. Reaction and Moderation Probabilities for 3-eV H Atoms in D2, CD4, and C2D6 and for 3-eV D Atoms in H2, CH4, and C2H6

1964 • 43 citations

The Gas-Phase Fluorination of Hydrogen-Methane Mixtures

1959 • 40 citations

Hydrogen abstraction by fluorine atoms under conditions of thermal initiation: Hydrocarbons and fluorinated hydrocarbons

1975 • 38 citations

Temperature and Pressure Effects in the Addition of H Atoms to Propylene

1971 • 37 citations

218. The reactions of fluorine atoms with alkanes

1960 • 35 citations

Infrared and Raman Spectra of Fluorinated Ethylenes. V. Hexafluoropropene

1952 • 33 citations

Elementary rate constants in atomic chlorination reactions. Part 1.—Experiments in intermittent light

1961 • 31 citations

Least square regression lines: Calculations assuming a constant percent error

1967 • 29 citations

Transition-State Models and Hydrogen-Isotope Effects

1967 • 29 citations

Abstraction of Hydrogen Atoms by Energetic Recoil Tritium Atoms: Correlation with C–H Bond-Dissociation Energies in Hydrocarbons

1965 • 27 citations

A study of the kinetics of the reaction between H2 and F2 by EPR methods

1972 • 26 citations

Chemistry of Nuclear Recoil 18F Atoms. IV. Hot F-to-HF and F-to-F2 Abstraction in CH3CF3

1971 • 25 citations

Monte Carlo calculations of reaction rates and energy distribution among reaction products, fluorine + hydrogen deuteride .far. hydrogen fluoride + deuterium and fluorine + hydrogen deuteride .far. deuterium fluoride + hydrogen

1973 • 25 citations

ChemInform Abstract: HYDROGEN ABSTRACTION BY FLUORINE ATOMS UNDER CONDITIONS OF THERMAL INITIATION, HYDROCARBONS AND FLUORINATED HYDROCARBONS

1975 • 24 citations

High Velocity Fragments in Secondary Photochemical Processes

1945 • 23 citations

Chemistry of Nuclear Recoil 18F Atoms. V. Mechanism and Systematics in CH3CF3

1971 • 22 citations

Dynamics of reaction of monoenergetic atoms in a thermal gas

1967 • 20 citations

Gas to condensed phase transition in hot atom chemistry

1970 • 20 citations

Reactions of fluorine-18 atoms with ethylene

1972 • 19 citations

Kinetic hydrogen isotope effect in the fluorination of H2, CH4 and CHCl3

1972 • 19 citations

On a Time Dependent Theory of Hot-Atom Reactions

1972 • 19 citations

Relative rates of hydrogen atom abstraction by near-thermal fluorine-18 atoms

1971 • 19 citations

New hydrogen fluoride chemical lasers

1969 • 19 citations

Competitive addition of near-thermal fluorine-18 atoms to olefins

1972 • 17 citations

Reaction of hot and thermal hydrogen atoms with hydrogen bromide and bromine

1970 • 16 citations

Abstraction fraction in the reaction of deuterium atoms with HBr and HI

1974 • 16 citations

Recoil Tritium Reactions: Variations in Hot Abstraction Yield with C–H Bond Type

1963 • 15 citations

Ratio of terminal to central addition of fluorine atoms to propylene

1972 • 14 citations

Isotope effect for the thermal F + H2 reaction: An Arrhenius kinetics experiment based upon nuclear recoil techniques

1974 • 13 citations

Reactions of energetic fluorine-18 atoms with tetrafluoroethylene

1970 • 13 citations

Chemistry of nuclear recoil fluorine-18 atoms. II. Energetic F-for-F and ring-attack reactions in perfluorocyclanes

1969 • 12 citations

Significance of limiting low pressure product yields from energetic atomic exchange reactions

1975 • 11 citations

Chemistry of nuclear recoil fluorine-18 atoms. VII. Detection of caging reactions in liquid phase 1,1,1-trifluoroethane and 1,1-difluoroethane

1975 • 9 citations

Hot-Atom Reactions in the Photolysis of Deuterium Chloride at 1849 Å

1970 • 8 citations

Temperature dependence of simple hot atom reactions

1971 • 4 citations

Moderation of photochemically produced hot deuterium atoms

1973 • 4 citations