Rate Constants for the Reactions of Atomic Oxygen (O 3P) with Organic Compounds in the Gas Phase

Atomic and Free Radical Reactions.

1946 • 361 citations

Atom—Molecule Kinetics at High Temperature Using ESR Detection. Technique and Results for O +H2, O +CH4, and O +C2H6

1967 • 129 citations

Collisional Deactivation of the Excited Singlet Oxygen Atoms and Their Insertion into the CH Bonds of Propane

1964 • 117 citations

Mass-spectrometric study of the reactions of the hydroxyl radical with ethylene, propylene, and acetaldehyde in a discharge-flow system

1971 • 115 citations

Chemical Reaction and Diffusion in a Catalytic Tubular Reactor

1961 • 107 citations

Mechanism of the Acetylene—Oxygen Reaction in Shock Waves

1965 • 100 citations

MOLECULAR REARRANGEMENTS IN THE REACTIONS OF OXYGEN ATOMS WITH OLEFINS

1958 • 99 citations

Flash Photolysis Measurement of the Kinetics of CF2 Reactions

1964 • 96 citations

Direct identification of the reactive channels in the reactions of oxygen atoms and hydroxyl radicals with acetylene and methylacetylene

1974 • 89 citations

Decomposition of Tertiary Alkyl Hypochlorites¹

1963 • 89 citations

RATE OF REACTION OF METHANE WITH H ATOMS AND OH RADICALS IN FLAMES

1961 • 85 citations

Reaction of Oxygen Atoms with Ethylene

1955 • 77 citations

Direct observation of the products produced by the O-atom reactions with ethylene and propylene studied in high-intensity molecular beams

1972 • 64 citations

Radical rearrangement in gas-phase oxidation and related processes

1964 • 62 citations

REACTION OF OXYGEN ATOMS WITH BENZENE

1961 • 61 citations

ABSOLUTE RATE MEASUREMENTS OF O-ATOM REACTIONS WITH ETHYLENE AND WITH BUTANE

1960 • 55 citations

Mechanism of the Interaction of Oxygen Atoms with Olefins

1956 • 55 citations

Detection of steady-state free-radical concentrations by photoionization

1972 • 53 citations

Reaction of atomic oxygen with aromatic hydrocarbons

1970 • 53 citations

Pyrolysis of Ethylene Oxide. A Hot Molecule Reaction

1964 • 50 citations

FORMATION OF CARBON MONOXIDE IN METHANE FLAMES BY REACTION OF OXYGEN ATOMS WITH METHYL RADICALS

1961 • 44 citations

Mass Spectrometric Studies of Atom–Molecule Reactions Using High-Intensity Crossed Molecular Beams

1970 • 43 citations

Reaction Rates of Hydrogen, Ammonia, and Methane with Mixtures of Atomic and Molecular Oxygen

1963 • 42 citations

Temperature Dependence of the Rates of Addition of Oxygen Atoms to Olefins

1960 • 41 citations

Reaction of Ketene with Atomic Hydrogen and Oxygen

1968 • 39 citations

Kinetics of the Reaction of O(3P) Atoms with Benzene

1972 • 38 citations

Electronic Structure and Reactivities of Monoölefins

1959 • 38 citations

Reactions of oxygen atoms with acetylene

1969 • 37 citations

Reactions of cyclic alkyl radicals. Part 2.—Photolysis of cyclopropane carboxaldehyde

1967 • 36 citations

Rate parameters for reaction of oxygen atoms with C2F4, CF2CFCl and CF2CCl2

1969 • 34 citations

Biradical intermediate in the addition of the ground state oxygen atoms, O(3P), to olefins

1970 • 34 citations

Reaction of Atomic Oxygen with Methyl Radicals

1968 • 33 citations

Kinetics of the Reaction of O(³P) with Methane in Oxygen, Nitrogen, and Argon-Oxygen Mixtures

1965 • 31 citations

The Reaction of Oxygen Atoms with Tetrafluoroethylene¹

1965 • 30 citations

Detection of oxygen (3P) atoms in pulsed vacuum UV photolysis of NO and its application to O atom reactions

1970 • 30 citations

REACTION OF OXYGEN ATOMS WITH TOLUENE

1961 • 25 citations

Mass spectrometric study of the kinetics and mechanism of the ethylene-atomic oxygen reaction by the discharge-flow technique at 300°K

1969 • 24 citations

PHOTOOXIDATION OF BUTENES BY NITROGEN DIOXIDE AT DIFFERENT WAVE LENGTHS

1958 • 23 citations

Chemiluminescence from the reaction of oxygen atoms with dicyanoacetylene

1970 • 23 citations

The Reaction of Oxygen Atoms with Perfluoropropene

1965 • 22 citations

Errors in Determining the Rate Constant of a First-order Gaseous Reaction by the Flow Method

1963 • 22 citations

Reaction of oxygen atoms with cyclopentene

1971 • 21 citations

REACTIONS OF OXYGEN ACTIVATED BY ELECTRICAL DISCHARGE WITH BUTENE-1

1959 • 21 citations

Use of the nitrogen dioxide titration technique for oxygen atom determination at pressures above 2Torr

1970 • 19 citations

Reaction of oxygen atoms with ethanol

1967 • 19 citations

Perfluorocyclopropene and its isomers

1968 • 18 citations

Reaction of oxygen atoms with alkynes. Part 1.—The butyne-2 reaction

1972 • 17 citations

Some Aspects of Acetylene Oxidation

1969 • 16 citations

Molecular Beam Analyzer for Identifying Transient Intermediates in Gaseous Reactions

1971 • 16 citations

Reaction of oxygen atoms with 2-(trifluoromethyl)-propene

1968 • 16 citations

Reaction of Oxygen Atoms with Tetrafluoroethylene in the Presence of Molecular Oxygen¹

1966 • 16 citations

Reaction of Methylene Radicals with Acetylene in the Gas Phase

1963 • 15 citations

Addition reactions of oxygen atoms at high pressures

1973 • 15 citations

Phenol Synthesis by Direct Oxidation of Benzene

1953 • 15 citations

Measurement of the Rate Parameters for Reaction of O(23P) with Carbon Disulphide and Olefines, by Flash Spectroscopy

1967 • 14 citations

Some Reactions of Oxygen Atoms. III. Cyclopropane, Cyclobutane, Cyclopentane, and Cyclohexane

1967 • 14 citations

Addition of oxygen atoms to olefins at low temperature. IV. Rearrangements

1970 • 13 citations

Low-temperature oxygen atom addition to olefins. III. Transition state and the reaction with cis- and trans-2-butenes

1969 • 13 citations

THE REACTION OF OXYGEN ATOMS WITH CARBON TETRACHLORIDE

1962 • 12 citations

Reaction of Oxygen Atoms with Acetaldehyde

1965 • 11 citations

The Reaction of Oxygen Atoms with Dimethyl Ether

1966 • 10 citations

Reaction of 3 P oxygen atoms with dimethyl ether and trans-but-2-ene

1970 • 10 citations

The decomposition of ethylene and ethane in premixed hydrocarbon-oxygen-hydrogen flames

1963 • 9 citations

Totally inverted vibrational population of CO formed in the reaction of oxygen with acetylene

1972 • 7 citations

Direct-Reading Apparatus for Determining the Rate Constants of Atomic Reactions

1969 • 6 citations

Destruction of Acetylene in Flames with Oxygen

1964 • 6 citations

The ozone-induced oxidation of tetrafluoroethylene

1970 • 6 citations

Further Examination of the Reaction of Oxygen Atoms with Perfluoropropene

1967 • 5 citations

Reaction of Oxygen Atoms (3P) with Acetaldehyde

1968 • 4 citations

Application of the point source technique to the study of fast, second order, gas phase reactions

1968 • 4 citations

Rate constant and mechanism of the reaction of atomic oxygen with methyl alcohol

1961 • 3 citations

Rate constants and mechanism of reactions of oxygen atoms with ethanol and propionaldehyde

1967 • 3 citations

Rate constant and mechanism of the reaction of oxygen atoms with n-butane

1963 • 3 citations

Rate constants and mechanism of reactions of oxygen atoms with methane and ethane

1963 • 2 citations

Oxygen Atom Reactions with Condensed Olefins

1964 • 2 citations

The Study of Elementary Gas Reactions in Flow Systems

1968 • 2 citations

Mechanism and rate constant of the reaction of oxygen atoms with acetylene

1965 • 2 citations

Rate constants of reactions of oxygen atoms with cyclohexane and benzene

1965 • 2 citations

New method of determining rate constants of elementary reactions of atoms and radicals

1958 • 1 citations