The thermodynamic driving force for CH activation at iridium

Principles and applications of organotransition metal chemistry

1980 • 1,561 citations

The organometallic chemistry of alkanes

1985 • 1,197 citations

Carbon-hydrogen and hydrogen-hydrogen activation in transition metal complexes and on surfaces

1984 • 589 citations

The direct conversion of methane to methanol by controlled oxidation

1985 • 376 citations

Aliphatic hydroxylation catalyzed by iron porphyrin complexes

1983 • 369 citations

Relative metal-hydrogen, -oxygen, -nitrogen, and -carbon bond strengths for organoruthenium and organoplatinum compounds; equilibrium studies of Cp*(PMe3)2RuX and (DPPE)MePtX systems

1987 • 320 citations

The mechanism and thermodynamics of alkane and arene carbon-hydrogen bond activation in (C5Me5)Rh(PMe3)(R)H

1984 • 301 citations

Thermochemical studies of organo-transition metal carbonyls and related compounds

2006 • 273 citations

Iridium complexes in alkane dehydrogenation

1979 • 249 citations

The transition-metal-hydrogen bond

1985 • 219 citations

A structural, kinetic and thermodynamic study of the reversible thermal carbon-hydrogen bond activation/reductive elimination of alkanes at iridium

1986 • 217 citations

Alkane dehydrogenation by iridium complexes

1982 • 201 citations

Determination and significance of transition metal-alkyl bond dissociation energies

1982 • 199 citations

Dihydrido olefin and solvento complexes of iridium and the mechanisms of olefin hydrogenation and alkane dehydrogenation

1982 • 187 citations

Activation of carbonhydrogen bonds by metal complexes: Mechanistic, kinetic and thermodynamic considerations

1985 • 173 citations

P-450-tpye dioxygen activation using hydrogen/colloidal platinum as an effective electron donor

1981 • 164 citations

Free-radical chain reactions

1970 • 153 citations

Hydrocarbon functionalization by the (iodosylbenzene)manganese(IV) porphyrin complexes from the (tetraphenylporphinato)manganese(III)-iodosylbenzene catalytic hydrocarbon oxidation system. Mechanism and reaction chemistry

1983 • 152 citations

Kinetic determination of transition metal-alkyl bond dissociation energies: application to organocobalt compounds related to B12 coenzymes

1982 • 143 citations

Periodic trends in transition metal-hydrogen, metal-carbon, and metal-oxygen bond dissociation energies. Correlation with reactivity and electronic structure

1981 • 137 citations

Theoretical study on the relative strengths of the metal-hydrogen and metal-methyl bonds in complexes of middle to late transition metals

1987 • 132 citations

Mechanistic studies on the oxidative coupling of methane

1987 • 130 citations

Intramolecular reductive elimination of alkanes from cis-hydridoalkylbis(phosphine)platinum(II) complexes

1978 • 129 citations

Organo-f-element thermochemistry. Metal-ligand bond dissociation enthalpies in (pentamethylcyclopentadienyl)thorium hydrocarbyls, metallacycles, hydrides, and dialkylamides

1983 • 127 citations

The selective catalytic conversion of cycloalkanes into cycloalkenes using a soluble rhenium polyhydride system

1983 • 126 citations

Ion beam studies of the reactions of atomic cobalt ions with alkanes: determination of metal-hydrogen and metal-carbon bond energies and an examination of the mechanism by which transition metals cleave carbon-carbon bonds

1981 • 116 citations

Dry ozonation. Method for stereoselective hydroxylation of saturated compounds on silica gel

1975 • 115 citations

Entropy, Binding Energy, and Enzymic Catalysis

1977 • 114 citations

Activation of C-H bonds in saturated hydrocarbons. The catalytic functionalisation of cycloöctane by means of some soluble iridium and ruthenium polyhydride systems

1984 • 114 citations

Ligand effects on transition metal-alkyl bond dissociation energies

1982 • 112 citations

Carbon-hydrogen bond activation by ruthenium for the catalytic synthesis of indoles

1986 • 107 citations

A new procedure for the oxidation of saturated hydrocarbons

1983 • 105 citations

Insertion of iridium into the carbon-hydrogen bonds of alkenes: the .pi.-complex cannot be an intermediate

1985 • 105 citations

Enthalpy of formation of acyl-, alkyl- and hydridopentacarbonyl-manganese complexes. The enthalpy contributions of manganese-hydrogen and manganese-carbon bonds in these molecules. Thermochemical aspects of models in Fischer-Tropsch reactions

1982 • 96 citations

Mono-oxigenase-like dioxygen activation leading to alkane hydroxylation and olefin epoxidation by an Mn^III(porphyrin)–ascorbate biphasic system

1983 • 87 citations

Ion beam studies of the reactions of Group VIII metal ions with alkanes: correlation of thermochemical properties and reactivity

1982 • 80 citations

Catalytic replacement of unactivated alkane carbon-hydrogen bonds with carbon-X bonds (X = nitrogen, oxygen, chlorine, bromine, or iodine). Coupling of intermolecular hydrocarbon activation by MnIIITPPX complexes with phase-transfer catalysis

1983 • 79 citations

Heats of reaction of Cp(PMe3)Ir(R)(H) (R = C6H5, C6H11, H) with HCl, CCl4, CBr4, and MeI. A solution thermochemical study of the C-H insertion reaction

1987 • 77 citations

Carbon-hydrogen bond activation using a bis(phosphine)iridium carbonyl hydride and the carbonylation of benzene

1983 • 76 citations

The activation of carbon-hydrogen bonds

1985 • 74 citations

The activation of C–H bonds in cyclopentane by bis(phosphine)rhenium heptahydrides

1980 • 73 citations

Superacid‐Catalyzed Oxygenation of Alkanes. [New synthetic methods (26)]

1978 • 71 citations

Metal-alkyl bond dissociation energies in organocobalt compounds related to vitamin B12 coenzymes

1979 • 69 citations

The enthalpies of formation of CH3Mn(CO)5 and of CH3Re(CO)5, and the strengths of the CH3Mn and CH3Re bonds

1974 • 53 citations

The selective conversion of n-pentane into pent-1-ene via trihydrido(trans-penta-1,3-diene)bis(triarylphosphine)rhenium

1982 • 53 citations

A+A+F

1964 • 50 citations

The determination of the manganese-manganese bond strength in Mn2(CO)10 using pulsed time-resolved photoacoustic calorimetry

1986 • 47 citations

Haptotropic rearrangements and carbon-hydrogen bond activation in indan, indenyl, and naphthalene complexes of iridium

1984 • 45 citations

Activation of C-H bonds in saturated hydrocarbons. The formation of bis(triphenylphospine)(η-alkadiene)rhenium trihydrides from n-Alkanes, and their selective conversion into the corresponding 1-alkenes

1984 • 45 citations

Steric influences on cobaltalkyl bond dissociation energies

1983 • 43 citations

Mechanism of reductive elimination of 1,1,1-trifluoroethane from cis-hydrido(2,2,2-trifluoroethyl)bis(triphenylphosphine)platinum(II)

1983 • 42 citations

Low-temperature oxidation of n-alkanes by cobaltic acetate activated by strong acids

1972 • 41 citations

Diverse mechanisms of carbon-hydrogen bond formation through binuclear reductive elimination reactions

1982 • 41 citations

The hydroxylation of alkanes and alkyl chains

1977 • 39 citations

Further studies on the activation of the CH bond in saturated hydrocarbons

1983 • 38 citations

Arylkomplexe des typs trans-[Ir(Ar)(CO)(PPh3)2]

1976 • 32 citations

Five-co-ordinate aryl- and alkyl-ruthenium(<scp>III</scp>) porphyrin complexes, and ruthenium–carbon bond strengths

1987 • 32 citations

Thermochemistry of molybdenum tricarbonyl complexes of arenes and cyclic polyolefins

1985 • 30 citations

Remote and selective electrophilic fluorinations at the carbon-hydrogen single bond

1980 • 27 citations

Enthalpy changes in oxidative addition reactions of organic iodides with trans-chlorocarbonylbis(trimethylphosphine)iridium(I)

1981 • 26 citations

Synthesis and characterization of some trans-hydridomethylbis(phosphine)-platinum(II) and -palladium(II) complexes

1981 • 23 citations

Heats of reaction of RMo(CO)3C5H5 (R = H, Me, Et) with phosphines and phosphites: thermodynamic study of the carbonyl-insertion reaction

1986 • 19 citations

Molekülstruktur von bromo-carbonyl-hydrido-phenyl-bis (triäthylphosphin)iridium(III), [Ir(H)(Br)(C6H5)(CO)(PEt3)2]

1976 • 19 citations

HYDROGEN AND CARBON MONOXIDE AS LIGAND COMBINATION FOR TRANSITION ELEMENTS*

1983 • 15 citations

Regioselective oxidation of unactivated methylene and methine groups by dry ozonation: similarity to microbiological oxidation

1978 • 15 citations

Enthalpies of formation of [M(η-C₅H₅)₂(OOCR)₂] complexes; M = Mo, W, or Ti and R = C₆H₅or CF₃

1981 • 13 citations