Periodic trends in gas phase MH and MC bond energies

Carbonhydrogen-transition metal bonds

1983 • 1,229 citations

Translational energy dependence of Ar++XY→ArX++Y (XY=H2,D2,HD) from thermal to 30 eV c.m.

1985 • 772 citations

Carbon-hydrogen and hydrogen-hydrogen activation in transition metal complexes and on surfaces

1984 • 589 citations

Reversible activation of covalent molecules by transition-metal complexes. The role of the covalent molecule

1968 • 360 citations

Determination and significance of transition metal-alkyl bond dissociation energies

1982 • 199 citations

Reaction mechanisms and thermochemistry of vanadium ions with ethane, ethene and ethyne

1986 • 192 citations

Activation of carbonhydrogen bonds by metal complexes: Mechanistic, kinetic and thermodynamic considerations

1985 • 173 citations

Kinetic energy dependence of Al++O2→AlO++O

1986 • 159 citations

Gas-phase photodissociation of organometallic ions. Bond energy and structure determinations

1986 • 144 citations

Periodic trends in transition metal-hydrogen, metal-carbon, and metal-oxygen bond dissociation energies. Correlation with reactivity and electronic structure

1981 • 137 citations

Theoretical study on the relative strengths of the metal-hydrogen and metal-methyl bonds in complexes of middle to late transition metals

1987 • 132 citations

Electronic effects in C-H and C-C bond activation. State-specific reactions of FE+ (6D,4F) with methane, ethane, and propane

1988 • 130 citations

Reaction of silicon ion (2P) with silane (SiH4, SiD4). Heats of formation of SiHn, SiHn+ (n = 1, 2, 3), and Si2Hn+ (n = 0, 1, 2, 3). Remarkable isotope exchange reaction involving four-hydrogen shifts

1987 • 120 citations

Ion beam studies of the reactions of atomic cobalt ions with alkanes: determination of metal-hydrogen and metal-carbon bond energies and an examination of the mechanism by which transition metals cleave carbon-carbon bonds

1981 • 116 citations

State-specific reactions of atomic transition-metal ions with molecular hydrogen, hydrogen deuteride, and molecular deuterium: effects of d orbitals on chemistry

1987 • 113 citations

Positive ions of the first- and second-row transition metal hydrides

1987 • 107 citations

Factors favoring an M...H-C interaction in metal-methyl complexes. An MO analysis

1985 • 100 citations

Determination of the metal-hydrogen and metal-methyl bond dissociation energies of the second-row, Group 8 transition metal cations

1984 • 99 citations

Theoretical studies of transition-metal hydrides. 1. Bond energies for MH+ with M = Ca, Sc, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, and Zn

1986 • 97 citations

Effect of kinetic and electronic energy on the reaction of vanadium(1+) (V+) with molecular hydrogen, hydrogen deuteride, and molecular deuterium

1985 • 95 citations

Effect of kinetic and electronic energy on the reactions of iron(1+) with hydrogen, deuterium hydride, and deuterium: state-specific cross sections for Fe+(6D) and Fe+(4F)

1986 • 94 citations

Energy dependence, kinetic isotope effects, and thermochemistry of the nearly thermoneutral reactions N+(3P)+H2(HD,D2)→NH+(ND+)+H(D)

1987 • 92 citations

Homolytic and heterolytic bond dissociation energies of the second row group 8, 9, and 10 diatomic transition-metal hydrides: correlation with electronic structure

1986 • 92 citations

Effect of kinetic and electronic energy on the reactions of Mn+ with H2, HD, and D2

1986 • 90 citations

Kinetics and mechanism of the reaction between dicobalt octacarbonyl and hydrogen

1972 • 88 citations

Gas-phase photodissociation of FeCH2+ and CoCH2+: determination of the carbide, carbyne, and carbene bond energies

1986 • 82 citations

Transition-metal hydride bond energies: first and second row

1986 • 80 citations

Ion beam studies of the reactions of Group VIII metal ions with alkanes: correlation of thermochemical properties and reactivity

1982 • 80 citations

Bonding in transition-metal-methylene complexes. 2. (RuCH2)+, a complex exhibiting low-lying methylidene-like and carbene-like states

1986 • 77 citations

C+(2P)+H2(D2,HD)→CH+(CD+)+H(D). I. Reaction cross sections and kinetic isotope effects from threshold to 15 eV c.m.

1986 • 74 citations

Bond energy-bond order relations in transition-metal bonds: vanadium

1984 • 73 citations

Effect of kinetic and electronic energy on the reactions of cobalt, nickel, and copper ions with hydrogen, hydrogen deuteride, and deuterium

1986 • 67 citations

Cobalt carbene ion: Reactions of Co+ with C2H4, cyclo-C3H6, and cyclo-C2H4O

1981 • 64 citations

Effect of kinetic and electronic energy on the reactions of Cr+ with H2, HD, and D2

1987 • 60 citations

Generation and reaction of atomic metal anions in the gas phase. Determination of the heterolytic and homolytic bond energies for the vanadium, chromium, iron, cobalt, and molybdenum hydrides VH, CrH, FeH, CoH, and MoH

1985 • 57 citations

Threshold behavior for chemical reactions: line-of-centers cross section for silicon(1+)(2P) + molecular hydrogen .fwdarw. silicon hydride(1+) (SiH+) + atomic hydrogen

1984 • 54 citations

Does ground state Fe+ (iron(1+)) react with hydrogen?

1986 • 53 citations

Correlation of electron and hydrogen atom binding energies for transition-metal atoms

1985 • 52 citations

Reactions of the pentacyanocobaltate(II) ion *1II. Liquid phase hydrogenation and decomposition

1962 • 51 citations

Theoretical studies of transition-metal methyl ions, MCH3+ (M = Sc, Cr, Mn, Zn, Y, Mo, Tc, Pd, Cd)

1987 • 50 citations

Neutral and ionic metal methyl bond energies: zinc

1986 • 50 citations

Activation of dihydrogen by scandium ions

1986 • 43 citations

Electronic and geometric structures of acandium hydride cations (ScH+ and ScH2+)

1985 • 42 citations

Mechanistic and kinetic study of alkane activation by titanium(I) and vanadium(I) in the gas phase. Lifetimes of reaction intermediates

1986 • 35 citations

Electronic and geometric structures of the chromium cations CrH+, CrCH3+, CrCH2+, and CrCH+

1985 • 34 citations

The gas phase structure of transition metal dihydrides

1980 • 27 citations

The electronic and geometric structures of the transition-metal carbyne cations ScCH+, TiCH+, VCH+, and CrCH+

1986 • 22 citations

High-spin electronic states of the experimentally observed molecular ions methylenemanganese (MnCH2+) and methylenechromium (CrCH2+)

1982 • 22 citations

Agostic bonds in (MCH3)+ fragments. Implications for M+-CH3 bond dissociation energies

1987 • 16 citations