Retention and inversion in bimolecular substitution reactions of methane

Super acids. III. Protonation of alkanes and intermediacy of alkanonium ions, pentacoordinated carbon cations of CH5+ type. Hydrogen exchange, protolytic cleavage, hydrogen abstraction; polycondensation of methane, ethane, 2,2-dimethylpropane and 2,2,3,3-tetramethylbutane in FSO3H-SbF5

1969 • 272 citations

Chemistry in super acids. I. Hydrogen exchange and polycondensation of methane and alkanes in FSO3H-SbF5 ("magic acid") solution. Protonation of alkanes and the intermediacy of CH5+ and related hydrocarbon ions. The high chemical reactivity of "paraffins" in ionic solution reactions

1968 • 262 citations

Electronic structure of large molecular systems

1966 • 199 citations

A comparison of different contractions for molecular calculations with gaussian-type functions

1968 • 196 citations

Study of the Electronic Structure of Molecules. III. Pyrrole Ground-State Wavefunction

1967 • 145 citations

One-Center Expansion Wavefunctions for CH3−, CH4, and CH5+

1965 • 75 citations

Nonempirical Molecular-Orbital Calculations for Protonated Formaldehyde, Acetaldehyde, and Formic Acid

1968 • 61 citations

Chemistry and spectroscopy in strongly acidic solutions. Part XXIV: Electrophilic substitution at alkanes

1969 • 47 citations

An investigation of the geometry of the CH+5 ion by the CNDO method

1969 • 46 citations

Electrophilic Substitution at methane: Short communication

1968 • 42 citations

Trapping of the methyl cation by carbon monoxide; formation of acetic acid from methane

1969 • 41 citations

Electronic structure of carbonium ions. Alkyl cations and protonated hydrocarbons

1968 • 33 citations

Electrophilic substitution at saturated carbon. XLII. Trimethylene keto carbanions as intermediates in base-catalyzed epimerization, racemization, and cleavage reactions of optically active diastereomers of 1,2-dimethyl-2-phenylcyclopentanols

1969 • 16 citations

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