Enzyme-bound pentadienyl and peroxyl radicals in purple lipoxygenase

On the Specificity of the Oxygenation of Unsaturated Fatty Acids Catalyzed by Soybean Lipoxidase

1967 • 660 citations

Mechanisms for the autoxidation of polyunsaturated lipids

1986 • 399 citations

Free-radical and molecule thermochemistry from studies of gas-phase iodine-atom reactions

1969 • 321 citations

Demonstration by EPR spectroscopy of the functional role of iron in soybean lipoxygenase-1

1975 • 300 citations

Energetics of interconversion reactions of oxyradicals

1985 • 277 citations

Homopolar‐ and Heteropolar Bond Dissociation Energies and Heats of Formation of Radicals and Ions in the Gas Phase. I. Data on organic molecules

1973 • 214 citations

The detection of linoleic acid radicals in the anaerobic reaction of lipoxygenase

1973 • 149 citations

Lipid Peroxyl Radical Intermediates in the Peroxidation of Polyunsaturated Fatty Acids by Lipoxygenase

1989 • 136 citations

Product yield in oxygenation of linoleate by soybean lipoxygenase: The value of the molar extinction coefficient in the spectrophotometric assay

1987 • 123 citations

Magnetic interaction between the tyrosyl free radical and the antiferromagnetically coupled iron center in ribonucleotide reductase

1987 • 123 citations

Catecholate complexes of ferric soybean lipoxygenase 1

1988 • 101 citations

Evidence in favor of an organoiron-mediated pathway for lipoxygenation of fatty acids by soybean lipoxygenase

1987 • 97 citations

Absolute rate constants for metathesis reactions of allyl and benzyl radicals with hydriodic acid (hydriodic acid-d). Heat of formation of allyl and benzyl radicals

1979 • 86 citations

On the interaction of soybean lipoxygenase‐1 and 13‐L‐hydroperoxylinoleic acid, involving yellow and purple coloured enzyme species

1975 • 83 citations

C-11 H-abstraction from linoieic acid, the rate-limiting step in lipoxygenase catalysis

1973 • 73 citations

Location and magnetic relaxation properties of the stable tyrosine radical in photosystem II

1989 • 67 citations

Magnitude of intrinsic isotope effects in the dopamine .beta.-monooxygenase reaction

1983 • 66 citations

An electron spin resonance study of pentadienyl and related radicals: homolytic fission of cyclobut-2-enylmethyl radicals

1981 • 56 citations

Circular dichroism of lipoxygenase-1 from soybeans

1979 • 52 citations

Biological consequences of fatty acid oxygenase reaction mechanisms

1984 • 49 citations

Substrate fatty acid activation in soybean lipoxygenase-1 catalysis

1985 • 41 citations

Absolute rate constants for hydrocarbon autoxidation. 28. A low temperature kinetic electron spin resonance study of the self-reactions of isopropylperoxy and related secondary alkylperoxy radicals in solution

1980 • 38 citations

Observation of a peroxyl radical in samples of "purple" lipoxygenase

1990 • 38 citations

Oxygenation of trans polyunsaturated fatty acids by lipoxygenase reveals steric features of the catalytic mechanism

1987 • 37 citations

A quantitative optical and epr study onthe interaction between soybean lipoxygenase-1 and 13-l-hydroperoxilinoleic acid

1983 • 36 citations

Stereochemistry and mechanism of the biosynthesis of leukotriene A4 from 5(S)-hydroperoxy-6(E),8,11,14(Z)-eicosatetraenoic acid. Evidence for an organoiron intermediate

1989 • 34 citations

Low-temperature autoxidation in unsaturated lipids: an electron spin resonance study

1987 • 31 citations

E.s.r. observation of pentadienyl and allyl radicals on hydrogen abstraction from unsaturated lipids

1982 • 30 citations

Pentadienyl‐Radikale — Struktur und Spindichteverteilung

1979 • 26 citations

Rotational barriers in pentadienyl and pent-2-en-4-ynyl radicals

1985 • 23 citations

The synthesis of 11,11‐dideuterolinoleic acid

1971 • 20 citations

1H-NMR spectroscopic study on the binding of alcohols to soybean lipoxygenase-1

1982 • 15 citations

An electron spin resonance investigation of the motion of lipid peroxyl radicals

1987 • 13 citations

Radical intermediates in the vacuum ultraviolet photolysis of cyclohexane and cyclohexene vapors

1970 • 11 citations

AB initio molecular orbital calculations on the pentadienyl radical

1974 • 9 citations