Nuclear, electronic, and frequency factors in electron transfer reactions

Chemical and Electrochemical Electron-Transfer Theory

1964 • 4,224 citations

On the Theory of Electron-Transfer Reactions. VI. Unified Treatment for Homogeneous and Electrode Reactions

1965 • 2,661 citations

The energy gap law for radiationless transitions in large molecules

1970 • 2,448 citations

Theoretical relations among rate constants, barriers, and Broensted slopes of chemical reactions

1968 • 1,061 citations

Reaction Rates in Ionic Solutions

1942 • 973 citations

Mixed-valence compounds

1976 • 899 citations

Electron Transfer Between Biological Molecules by Thermally Activated Tunneling

1974 • 894 citations

Homogeneous and heterogeneous optical and thermal electron transfer

1968 • 798 citations

Adiabatic theory of outer sphere electron-transfer reactions in solution

1961 • 794 citations

Exchange reactions and electron transfer reactions including isotopic exchange. Theory of oxidation-reduction reactions involving electron transfer. Part 4.—A statistical-mechanical basis for treating contributions from solvent, ligands, and inert salt

1960 • 780 citations

The effect of intramolecular quantum modes on free energy relationships for electron transfer reactions

1975 • 705 citations

Thermal electron transfer reactions in polar solvents

1974 • 673 citations

Application of the energy gap law to the decay of charge-transfer excited states

1982 • 646 citations

Estimation of excited-state redox potentials by electron-transfer quenching. Application of electron-transfer theory to excited-state redox processes

1979 • 468 citations

Lifetimes, spectra, and quenching of the excited states of polypyridine complexes of iron(II), ruthenium(II), and osmium(II)

1980 • 452 citations

Mechanism of the quenching of the emission of substituted polypyridineruthenium(II) complexes by iron(III), chromium(III), and europium(III) ions

1976 • 428 citations

A semiclassical treatment of electron-exchange reactions. Application to the hexaaquoiron(II)-hexaaquoiron(III) system

1980 • 330 citations

Light induced electron transfer reactions of metal complexes

1980 • 226 citations

A nonadiabatic description of electron transfer reactions involving large free energy changes

1974 • 207 citations

Electrogenerated chemiluminescence. 35. Temperature dependence of the ECL efficiency of tris(2,2'-bipyridine)rubidium(2+) in acetonitrile and evidence for very high excited state yields from electron transfer reactions

1979 • 206 citations

Theory of hydrogen-ion discharge on metals: Case of high overvoltages

1968 • 199 citations

A comparison of the rates of electron exchange reactions of ammine complexes of ruthenium(II) and -(III) with the predictions of adiabatic, outer-sphere electron transfer models

1979 • 196 citations

Spin conversion processes in solutions

1980 • 193 citations

Metal to metal interactions in weakly coupled mixed-valence complexes based on ruthenium ammines

1981 • 192 citations

Quantum effects for electron-transfer reactions in the "inverted region"

1981 • 188 citations

Time-resolved resonance Raman study of the lowest (d.pi.*,3CT) excited state of tris(2,2'-bipyridine)ruthenium(II)

1979 • 184 citations

The Exchange Reaction between the Two Oxidation States of Iron in Acid Solution

1952 • 180 citations

Theory of highly exothermic electron transfer reactions

1982 • 175 citations

Long range transfer of positive charge between dopant molecules in a rigid glassy matrix

1981 • 171 citations

Reactions of molecules at electrodes

1971 • 168 citations

Determination of the comproportionation constant for a weakly coupled mixed-valence system by titration of the intervalence transfer band: .mu.-(4,4'-bipyridyl)-bis(pentaammineruthenium)(5+)

1979 • 164 citations

Free energy correlation of rate constants for electron transfer quenching of excited transition metal complexes

1978 • 161 citations

Free energies, barriers, and reactivity patterns in oxidation-reduction reactions

1968 • 156 citations

Dynamics of the primary events in bacterial photosynthesis

1980 • 143 citations

Vibrational effects in outer-sphere electron-transfer reactions in polar media

1976 • 139 citations

Electron Exchange Reactions

1962 • 131 citations

Spectroscopic Studies of Ruthenium(II) Complexes. Assignment of the Luminescence

1968 • 123 citations

Vestiges of the "inverted region" for highly exergonic electron-transfer reactions

1977 • 97 citations

Measurement of rates of electron transfer between tris(2,2'-bipyridine)ruthenium(3+) and tris(1,10-phenanthroline)iron(2+) ions and between tris(1,10-phenanthroline)ruthenium(3+) and tris(2,2'-bipyridine)ruthenium(2+) ions by differential excitation flash photolysis

1977 • 92 citations

Distances of electron transfer to and from metalloprotein redox sites in reactions with inorganic complexes

1980 • 90 citations

Excited states of mixed-ligand chelates of ruthenium(II). Quantum yield and decay time measurements

1981 • 89 citations

Resonance raman investigation of electronically excited ru(bipyridine)2+3 using a cw laser

1981 • 87 citations

Dynamics of intersystem crossing processes in solution for six-coordinate d5, d6, and d7 spin-equilibrium metal complexes of iron(III), iron(II), and cobalt(II)

1978 • 81 citations

On the frequency factor in electron transfer reactions and its role in the highly exothermic regime

1981 • 80 citations

Structure of hexaaquairon(III) nitrate trihydrate. Comparison of iron(II) and iron(III) bond lengths in high-spin octahedral environments

1977 • 79 citations

The hexaamminecobalt electron-exchange reaction

1979 • 74 citations

Intersystem crossing observed by ultrasonic relaxation of the singlet-quintet spin equilibrium of iron(II) complexes in solution

1978 • 73 citations

ESR of the reduction products of [Fe(bpy)3]2+ and [Ru(bpy)3]2+

1981 • 72 citations

Crystal structure and molecular geometry of bis[hydrotris(1-pyrazolyl)borato]cobalt(II)

1970 • 64 citations

The nonadiabaticity problem of outer-sphere electron-transfer reactions. Reduction and oxidation of europium ions

1981 • 49 citations

Rate of intersystem crossing between 1A and 5Aa states of an iron(II) complex in solutions

1973 • 48 citations

THE RATE OF ELECTRON TRANSFER BETWEEN THE TRIS- (ETHYLENEDIAMINE)-COBALT(II) AND COBALT(III) IONS

1961 • 44 citations

Intramolecular electron transfer. 3. Bis(4-pyridyl)methane as bridging group

1977 • 42 citations

Intersystem-crossing dynamics and coordination geometry changes observed by ultrasonic and laser temperature-jump relaxation of the 2T .dblharw. 6A spin equilibrium of hexadentate iron(III) complexes in solution

1980 • 41 citations

Application of electron-transfer theory to excited-state redox processes

1979 • 37 citations

Dynamic multiphonon processes

1979 • 32 citations

Electron-transfer reactions in the "abnormal" free-energy region

1979 • 31 citations

Comparison of observed and calculated barriers for optical electron transfer in a binuclear ruthenium(II)-ruthenium(III) complex

1978 • 28 citations

Activationless electron transfer processes in biological systems

1980 • 27 citations

Electron Delocalization, Structure and Dynamics in Mixed-Valence Systems

1980 • 27 citations

Intersystem crossing observed by ultrasonic relaxation of the 2T .dblharw. 6A spin equilibrium of hexadentate iron(III) complexes in solution

1978 • 27 citations

Compounds with intermediate spin. 5. X-ray study of tris(N,N-dimethyldithiocarbamato)iron(III) at the two extreme temperatures 25 and 400 K

1981 • 16 citations

Electron transfer reactions in frozen media

1979 • 12 citations

The Oxidation of n-Butylboron Oxide¹

1942 • 11 citations

Theory of electron transfer reactions of solvated electrons

1980 • 8 citations