The reaction coordinate and its limitations: an experimental perspective

The Activated Complex in Chemical Reactions

1935 • 5,261 citations

Zur Quantentheorie der Molekeln

1927 • 4,387 citations

Development of transition-state theory

1983 • 943 citations

Unimolecular Dissociations and Free Radical Recombination Reactions

1952 • 885 citations

Absolute Rate Theory for Isolated Systems and the Mass Spectra of Polyatomic Molecules

1952 • 761 citations

On Detailed Balancing and Statistical Theories of Chemical Kinetics

1965 • 624 citations

Reformulation of the quasiequilibrium theory of ionic fragmentation

1971 • 294 citations

The Theoretical Treatment of Chemical Reactions Produced by Ionization Processes Part I. The Ortho-Para Hydrogen Conversion by Alpha-Particles

1936 • 239 citations

Transition state theory for collision complexes: product translational energy distributions

1972 • 224 citations

Statistical phase space theory of polyatomic systems: Rigorous energy and angular momentum conservation in reactions involving symmetric polyatomic species

1977 • 213 citations

The evaporative ensemble

1987 • 192 citations

Multiple transition states in unimolecular reactions: A transition state switching model. Application to the C4H8 +⋅ system

1981 • 183 citations

On transition-state theory and the classical mechanics of collinear collisions

1973 • 180 citations

Statistical mechanics of neocortical interactions

1982 • 175 citations

Thermochemical and kinetic information from metastable decompositions of ions

1973 • 174 citations

Kinetic energy distributions from unimolecular decay: Predictions of the Langevin model

1976 • 154 citations

On the theory of energy distributions of products of molecular beam reactions involving transient complexes

1975 • 148 citations

Rate constants for unimolecular decomposition at threshold

1976 • 139 citations

Temperatures of evaporating clusters

1987 • 136 citations

Statistical phase space theory of polyatomic systems. Application to the cross section and product kinetic energy distribution of the reaction C2H4.cntdot.+ + C2H4 .fwdarw. C3H5+ + CH3

1976 • 108 citations

Statistical phase space theory of polyatomic systems. Application to the unimolecular reactions C6H5CN.cntdot.+ .fwdarw. C6H4.cntdot.+ + HCN and C4H6.cntdot.+ .fwdarw. C3H3+ + .cntdot.CH3

1977 • 107 citations

The dynamics of ethylene dimer infrared photodissociation in pulsed molecular beamsa)

1983 • 104 citations

Vibrational predissociation of benzene dimers and trimers by the crossed laser-molecular beam technique

1981 • 81 citations

Accuracy of transition state theory for the threshold of chemical reactions with activation energy. Collinear and three-dimensional atomic hydrogen + molecular hydrogen

1975 • 64 citations

Beam studies of energy and lifetime dependence of unimolecular decay: the extent of internal equilibration

1972 • 59 citations

Ionization in Rydberg-atom–<mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline"><mml:mrow><mml:msub><mml:mrow><mml:mi mathvariant="normal">SF</mml:mi></mml:mrow><mml:mrow><mml:mn>6</mml:mn></mml:mrow></mml:msub></mml:mrow></mml:math>collisions at highn

1985 • 51 citations

Infrared photodissociation of benzene dimers in the 1000 cm−1 frequency region

1986 • 44 citations

Fragmentation of metastable methane radical ions(1+) and isotopic analogs. Kinetic energy release distributions and tunneling through a rotational barrier: experiment and theory

1982 • 42 citations

Role of angular momentum in unimolecular kinetics: Kinetic energy release in fragmentation of C4H6+

1977 • 37 citations

Kinetic energy release distributions in the dissociation of CH + 4 and CD + 4 ions

1979 • 32 citations

The dynamics of infrared photodissociation of van der Waals molecules containing ethylene: An experimental study

1983 • 29 citations

Ionic fragmentation through centrifugal barriers

1971 • 27 citations

Energy distribution in the nitric oxide fragments from the ν7 vibrational predissociation of NO–C2H4

1985 • 22 citations

Dissociation of state-selected nitrogen trifluoride cations

1981 • 14 citations

On the energy dependence of unimolecular rate constants

1986 • 4 citations

Ion-Molecule Collision Complexes: Summary of the Panel Discussion

1979 • 2 citations