Synthesis and determination of enantiomeric excesses of non-racemic tert-thiols derived from chiral secondary α-mercaptocarboxylic acids

Methodology for the construction of quaternary carbon centers

1980 • 374 citations

(α-Alkylation of α-heterosubstituted carboxylic acids without racemization

1984 • 284 citations

The stereoselective α-alkylation of chiral β-hydroxy esters and some applications thereof

1984 • 257 citations

Asymmetric syntheses of amino acids via metalated bis-lactim ethers of 2,5-diketopiperazines

1983 • 207 citations

Thiolactomycin, a new antibiotic. I. Taxonomy of the producing organism, fermentation and biological properties.

1982 • 176 citations

Synthetic control leading to chiral compounds

1984 • 168 citations

Synthesis of (racemization prone) optically active thiols by SN2 substitution using cesium thiocarboxylates

1986 • 124 citations

Thiolactomycin, a new antibiotic. IV. Biological properties and chemotherapeutic activity in mice.

1982 • 116 citations

Asymmetric addition of organometallics to chiral ketooxazolines. Preparation of enantiomerically enriched .alpha.-hydroxy acids

1980 • 91 citations

Simple phosphorus-31 NMR method for the determination of enantiomeric purity of alcohols not requiring any chiral auxiliary compounds

1985 • 86 citations

1,3‐Dioxanone Derivatives from β‐Hydroxy‐carboxylic Acids and Pivalaldehyde. Versatile Building Blocks for Syntheses of Enantiomerically Pure Compounds. A Chiral Acetoacetic Acid Derivative Preliminary Communication

1986 • 82 citations

Synthesis of enantiomerically enriched atrolactic acid and other α-hydroxy acids

1981 • 81 citations

Thiolactomycin, a new antibiotic. II. Structure elucidation.

1982 • 77 citations

Total ssynthesis of (±) thiolactomycin

1984 • 64 citations

Conjugate and direct addition of ester enolates to cyclohexenone. Selective control of reaction composition

1976 • 58 citations

A method for the preparation of stereochemically defined .psi.[CH2O] pseudodipeptides

1987 • 55 citations

An asymmetric synthesis of enantiomerically pure (S)-(+)-linalool (3,7-dimethyl-1,6-octadien-3-ol) and a formal synthesis of (R)-(-)-linalool

1986 • 39 citations

Methylphosphonic dichloride as reagent for the determination of the enantiomeric excess of chiral thiols. scope and limitations

1987 • 33 citations

Molecular requirements of the recognition site of cholinergic receptors. 22. Resolution, absolute configuration, and cholinergic enantioselectivity of (+)- and (-)-cis-2-methyl-5-[(dimethylamino)methyl]-1,3-oxathiolane methiodide

1986 • 33 citations

Enantiomeric excess determination without chiral auxiliary compounds. A new phosphorus-31 NMR method for amino acid esters and primary amines

1986 • 31 citations

Alkylphosphonic dichlorides, new reagents for the enantiomeric excess determination of chiral alcohols and thiols by 31P NMR

1986 • 26 citations

Neighboring group participation of halo and aryl groups in the stoichiometric and catalytic reactions of olefins with transition-metal hydrides and a new route to arene complexes

1984 • 25 citations

Flash vacuum pyrolysis of 1,3-oxathiolan-5-ones

1980 • 23 citations

Peptide-gap inhibitors. 2. Stereoselective synthesis of enantiomeric dipeptide analogs of glycylleucine which contain methylene thioether groups substituted for peptide linkages

1978 • 22 citations

Synthesis of N-acyl-.alpha.-mercaptoalanine derivatives

1973 • 18 citations

1,3‐Dioxolan‐4‐ones and 1,3‐oxathiolan‐5‐ones. Configuration of cis and trans isomers

1977 • 15 citations

Peptidic cyclols. Synthesis, and crystal and molecular structure of a tricyclic thia-cyclol

1980 • 15 citations

Syntheses and biological activities of thiotetromycin analogs.

1983 • 14 citations

Über die konfigurativen Beziehungen der aus den optischen Isomeren des Isoleucins und des Alloisoleucins gewinnbaren α-Bromsäuren zu den aus diesen bei der Aminierung hervorgehenden Aminosäuren. Ein Beitrag zum Problem der Waldenschen Umkehrung.

1931 • 10 citations

Sulfur-Extrusive Rearrangement of α-Acylthio Ester by Lithium Amide

1985 • 5 citations

Sulphur in the Strategy of Natural Products Synthesis

1985 • 3 citations