Enantioselective addition of diorganozincs to aldehydes catalyzed by β-amino alcohols

Enantioselective addition of dialkylzincs to aldehydes promoted by chiral amino alcohols. Mechanism and nonlinear effect

1989 • 579 citations

Catalytic asymmetric induction. Highly enantioselective addition of dialkylzincs to aldehydes

1986 • 545 citations

Homogeneous asymmetric hydrogenation of functionalized ketones

1988 • 501 citations

Catalytic asymmetric induction. Highly enantioselective addition of dialkylzincs to aldehydes using chiral pyrrolidinylmethanols and their metal salts

1987 • 325 citations

Enantioselective addition of diethylzinc to benzaldehyde catalyzed by a small amount of chiral 2-amino-1-alcohols

1984 • 321 citations

Stereoselective syntheses. VIII. Retentive nucleophilic displacements of .alpha.-substituted alkylferrocenes

1972 • 282 citations

Herstellung von Hilfsstoffen für die asymmetrische Synthese aus Weinsäure. Addition von Butyllithium an Aldehyde in chiralem Medium

1977 • 271 citations

Asymmetric amplifying phenomena in enantioselective addition of diethylzinc to benzaldehyde

1988 • 259 citations

Enantioface-differentiating (asymmetric) addition of alkyllithium and dialkylmagnesium to aldehydes by using (2S,2'S)-2-hydroxymethyl-1-[(1-alkylpyrrolidin-2-yl)methyl]pyrrolidines as chiral ligands

1979 • 252 citations

Prostaglandin Syntheses by Three‐Component Coupling. New Synthetic Methods (49)

1984 • 236 citations

Asymmetric induction catalyzed by conjugate bases of chiral proton acids as ligands: Enantioselective addition of dialkylzinc-orthotitanate complex to benzaldehyde with catalytic ability of a remarkable high order

1989 • 213 citations

Chiral (.beta.-aminoalkyl)phosphines. Highly efficient phosphine ligands for catalytic asymmetric Grignard cross-coupling

1983 • 212 citations

Stereoselective Organic Reactions: Catalysts for Carbonyl Addition Processes

1988 • 172 citations

Asymmetric reductions with chiral reagents from lithium aluminum hydride and (+)-(2S,3R)-4-dimethylamino-3-methyl-1,2-diphenyl-2-butanol

1973 • 171 citations

Enantioselective alkylation of carbonyl compounds. From stoichiometric to catalytic asymmetric induction

1988 • 156 citations

Chiral catalysis of additions of alkyllithiums to aldehydes

1981 • 153 citations

Enantioselective addition of diethylzinc to aldehydes catalyzed by polymer-supported chiral amino alcohols. Evidence for a two zinc species mechanism

1987 • 146 citations

Enantioselective synthesis of sec-allylalcohols by catalytic asymmetric addition of divinylzinc to aldehydes.

1988 • 143 citations

Ab initio mechanisms for the addition of methyllithium, lithium hydride, and their dimers to formaldehyde

1985 • 131 citations

Asymmetric syntheses by means of (−)-sparteine modified organometallic reagents

1971 • 126 citations

Prostaglandin synthesis. 10. An extremely short way to prostaglandins

1985 • 125 citations

Preparation and resolution of N,N-dimethyl-o-ferrocenylethylamine. An advanced organic experiment

1972 • 119 citations

An organozinc aid in alkylation and acylation of lithium enolates

1989 • 111 citations

Asymmetric Reductions. VII. the Action of the Grignard Reagent from (+)-1-chloro-2-methylbutane on a Series of Alkyl Phenyl Ketones^1-3

1960 • 110 citations

Improvements in the osmium-catalyzed oxyamination of olefins by chloramine-T

1978 • 110 citations

Stereoselective addition reaction of diethylzinc to aldehydes, catalyzed by cinchona alkaloids

1987 • 108 citations

Chiral catalysts for the enantioselective addition of organometallic reagents to aldehydes

1987 • 93 citations

CVII.—Investigations on the dependence of rotatory power on chemical constitution. Part VI. The optical rotatory power of methyl-tert.-butyl-, methylbenzyl-, methylphenylethyl- and methyl-α-naphthyl-carbinols

1914 • 90 citations

Enantioselektive Addition von Arylgruppen an aromatische Aldehyde mit Aryltitan‐Binaphthol‐Derivaten

1985 • 89 citations

ENANTIOSELECTIVE ADDITION OF DIETHYLZINC TO ARYLALDEHYDES CATALYZED BY CHIRAL COBALT(II) AND PALLADIUM(II) COMPLEXES

1983 • 88 citations

Zinc complexes of chiral phenols as catalysts for enantioselective addition of organozinc reagents to aldehydes

1987 • 88 citations

Enantioselective addition of diethylzinc to benzaldehyde in the presence of ephedrine derivatives

1987 • 82 citations

Three New Chiral Aminoethers from Tartaric Acid for Improved Asymmetric Syntheses with Organolithium Reactions. Preliminary communication

1979 • 77 citations

Enantioselektive 1,2‐Additionen von Li‐, Mg‐, Zn‐ und Cu‐organischen Verbindungen und von Li‐Enolaten an Carbonylverbindungen im chiralen Medium DDB

1979 • 73 citations

Use of alkaloids and aminoalcohols in catalytic asymmetric induction:Temperature effect on the addition of diethylzinc to benzaldehyde

1987 • 71 citations

A convenient preparation of β-amino alcohols from epoxides and halomagnesium alkylamides

1985 • 70 citations

Preparation of optically active 2-thienylcarbinols by kinetic resolution using the Sharpless reagent

1989 • 69 citations

REACTIONS OF GRIGNARD REAGENTS IN OPTICALLY ACTIVE SOLVENTS¹

1953 • 66 citations

Optical Resolution of 2-Amino-1,2-diphenylethanol by Preferential Crystallization and Its Utilization in Fractional Crystallization and Enantioselective Reduction of Prochiral Ketones

1982 • 65 citations

Asymmetric reduction of α,β-unsaturated ketones with chiral hydride reagents prepared from lithium aluminum hydride and (S)-4-anilino- and (S)-4-(2,6-xylidino)-3-methylamino-1-butanol

1983 • 65 citations

Preparation of optically active 2-furylcarbinols by kinetic resolution using the Sharpless reagent

1988 • 64 citations

A new access to chiral 2-furylcarbinols by enantioselective hydrolysis with penicillin acylase

1989 • 63 citations

Complementary catalytic asymmetric induction in the enantioselective addition of diethylzinc to aldehydes

1987 • 59 citations

9 : 10-Dihydrophenanthrenes. Part III. Optically active 9 : 10-dihydro-3 : 4-5 : 6-dibenzophenanthrene

1955 • 58 citations

Asymmetric carbinol synthesis by means of (−)-sparteine-modified organometallic reagents

1968 • 54 citations

Resolution of S-(1-ferrocenylethyl)thioglycolic acid. A new method of preparation of optically active 1-ferrocenylethanol

1975 • 52 citations

Asymmetric synthesis. Part IV. The stereoselectivity of grignard-carbonyl reactions in solvents that contain carbohydrates

1969 • 47 citations

Enantioselective addition of chirally modified methyltitanium reagents to aromatic aldehydes

1986 • 42 citations

Effets electroniques en stereochimie—III

1979 • 40 citations

Investigations on organozinc compounds X. Coordination chemistry of organozinc compounds RZnX: organozincoxygen derivatives of potentially bidentate ligands

1968 • 28 citations

The Absolute Configurations of the α- and β-Methylcholine Isomers and Their Acetyl and Succinyl Esters

1963 • 26 citations

Aminobicyclo[2,2,1]heptanes. Part II. Diastereoisomeric dimethylaminobornyl acetates

1970 • 25 citations

OPTICAL INTERCONVERSION OF ENANTIOMERIC SECONDARY ALCOHOLS USING 2-FLUOROBENZOTHIAZOLIUM SALT

1976 • 25 citations

A Highly Efficient Synthesis of Prostaglandin ω-Chain Precursors

1987 • 22 citations

The stereochemistry of 2-hydroxy-3-aminobornanes

1969 • 20 citations

Catalytic Asymmetric Synthesis of Optically Active Alkynyl Alcohols

1989 • 20 citations

Nucleophilic ring opening of optically pure (R)-(+)-1,2-epoxybutane. Synthesis of new (R)-2-butanol derivatives

1973 • 18 citations

Preparation and Activity of β-Substituted Acetylcholine Iodides

1971 • 11 citations

Steric influence on the chemical reactions and NMR spectra of 2,3-disubstituted bornanes

1969 • 8 citations