Catalytic Oxidations in Organic Synthesis

The first practical method for asymmetric epoxidation

1980 • 2,522 citations

Metal-catalyzed Oxidations of Organic Compounds

1981 • 1,670 citations

A greatly improved procedure for ruthenium tetroxide catalyzed oxidations of organic compounds

1981 • 1,558 citations

Hydroxylation and epoxidation catalyzed by iron-porphine complexes. Oxygen transfer from iodosylbenzene

1979 • 799 citations

Osmium tetraoxide cis hydroxylation of unsaturated substrates

1980 • 576 citations

Aliphatic hydroxylation by highly purified liver microsomal cytochrome P-450. Evidence for a carbon radical intermediate

1978 • 531 citations

Allylic oxidation of olefins by catalytic and stoichiometric selenium dioxide with tert-butyl hydroperoxide

1977 • 525 citations

Catalytic asymmetric epoxidations with chiral iron porphyrins

1983 • 470 citations

A new, effective catalytic system for epoxidation of olefins by hydrogen peroxide under phase-transfer conditions

1983 • 406 citations

Hydrocarbon oxidations with oxometalloporphinates. Isolation and reactions of a (porphinato)manganese(V) complex

1980 • 382 citations

Aliphatic hydroxylation catalyzed by iron porphyrin complexes

1983 • 369 citations

Sodium hypochlorite: a convenient oxygen source for olefin epoxidation catalyzed by (porphyrinato)manganese complexes

1984 • 233 citations

Oxygen Transfer from Inorganic and Organic Peroxides to Organic Substrates: A Common Mechanism?

1982 • 222 citations

Hydroxylation by cytochrome P-450 and metalloporphyrin models. Evidence for allylic rearrangement

1984 • 219 citations

Preparation and characterization of an oxoporphinatochromium(V) complex

1979 • 183 citations

Epoxidation of olefins by cytochrome P-450 model compounds: kinetics and stereochemistry of oxygen atom transfer and origin of shape selectivity

1985 • 174 citations

Ruthenium catalyzed oxidation of alcohols to aldehydes and ketones by amine-n-oxides

1976 • 155 citations

Catalyzed oxidation of alcohols and aldehydes with iodosylbenzene

1981 • 137 citations

Chemoselectivity in molybdenum catalyzed alcohol and aldehyde oxidations

1984 • 134 citations

A very efficient system for alkene epoxidation by hydrogen peroxide: catalysis by manganese-porphyrins in the presence of imidazole

1985 • 131 citations

Ruthenium-catalysed oxidation of secondary amines to imines using t-butyl hydroperoxide

1985 • 119 citations

Ruthenium trichloride-catalysed hypochlorite oxidation of organic compounds

1970 • 105 citations

Oxo complexes of ruthenium(<scp>VI</scp>) and (<scp>VII</scp>) as organic oxidants

1984 • 100 citations

Mechanism of cytochrome P-450 catalysis. Mechanism of N-dealkylation and amine oxide deoxygenation

1985 • 99 citations

Mechanism of oxygen transfer from peroxo species

1982 • 98 citations

Isolation and molecular structure of unusual oxochromium(V) cations for the catalytic epoxidation of alkenes

1983 • 88 citations

Model systems for cytochrome P450 dependent mono-oxygenases. Part 1. Oxidation of alkenes and aromatic compounds by tetraphenylporphinatoiron(III) chloride and lodosylbenzene

1982 • 76 citations

Ruthenium Tetroxide Oxidation of Simple Ethers: A Systematic Study

1980 • 75 citations

A new catalytic route for the epoxidation of styrene with sodium hypochlorite activated by transition metal complexes

1980 • 75 citations

In the presence of imidazole, iron-and manganese-porphyrins catalyse the epoxidation of alkenes by alkyl hydroperoxides

1984 • 74 citations

Study of (tetraphenylporphinato)manganese(III)-catalyzed epoxidation and demethylation using p-cyano-N,N-dimethylaniline N-oxide as oxygen donor in a homogeneous system. Kinetics, radiochemical ligation studies, and reaction mechanism for a model of cytochrome P-450

1984 • 73 citations

Oxidation of cyclic amines with ruthenium tetroxide

1974 • 67 citations

Highly selective oxidation of secondary hydroxyl functions using the VO(acac)2-tBuOOH SYSTEM

1983 • 66 citations

Ruthenium-catalyzed oxidation of alcohols and catechols using t-butyl hydroperoxide

1984 • 65 citations

Metal Ion Activation of Dioxygen

1981 • 62 citations

Use of the N-oxide of p-cyano-N,N-dimethylaniline as an "oxygen" donor in a cytochrome P-450 model system

1982 • 62 citations

The stereospecific epoxidation of olefins catalysed by ruthenium

1984 • 61 citations

Ruthenium catalyzed oxidation of cyanohydrins to acyl cyanides useful reagents for selective N-benzoylation of aminoalcohols

1985 • 60 citations

Ruthenium tetroxide oxidation of alkynes. A new one step synthesis of α-diketones

1971 • 59 citations

Synergetic combination of catalysis of the phase transfer-electron transfer type for the oxidation of alcohols or hydrocarbons

1979 • 59 citations

Copper ion mediated epoxidation of olefins by iodosylbenzene

1984 • 59 citations

Role of pyridine in the catalytic activation of sodium hypochlorite in the presence of manganese porphyrin

1982 • 57 citations

Cr(III) or Ce(IV) impregnated perfluorinated resin-sulfonic acid catalyst for the oxidation of alcohols

1984 • 55 citations

New catalytic methods for selective oxidation

1983 • 53 citations

Chemoselective oxidation with molybdenum catalyst-t-butyl hydroperoxide

1984 • 53 citations

Potassium ruthenate: a catalytic oxidant for organic substrates

1979 • 52 citations

Ruthenium-catalyzed oxidation of alcohols with sodium bromate

1985 • 51 citations

Oxidation of alkenes with use of phase transfer catalysis

1977 • 50 citations

Oxidation of unsaturated fatty acids with ruthenium and osmium tetroxide

1977 • 42 citations

Ru-catalyzed oxidation of substituted acetylenes to α-keto esters and α-keto amides with iodosylbenzene

1982 • 40 citations

Catalytic epoxidation of aliphatic terminal olefins with sodium hypochlorite

1984 • 40 citations

Aspects of Homogeneous Catalysis

1981 • 40 citations

Mild and selective oxygen atom transfer:nBu4NIO4 with metalloporphyrins

1983 • 38 citations

Ruthenium Catalysed Oxidations of Organic Compounds

1983 • 36 citations

Zr-CATALYZED OXIDATION OF ALCOHOLS TO ALDEHYDES IN THE PRESENCE OF tBuOOH. HIGH REACTIVITY FOR PRIMARY AND ALLYLIC HYDROXYL FUNCTIONS

1984 • 35 citations

Mechanism of olefin epoxidation by a mono-oxygenase model

1984 • 34 citations

Shape-selective alkane hydroxylation

1985 • 31 citations

E.s.r. evidence for chromium (V) porphyrinates

1981 • 31 citations

Stereochemical arguments against a possible chlorohydrin route in the catalytic epoxidation of olefins with NaOCl/Mn-porphyrins

1983 • 28 citations

Definitive evidence for a proximal effect of pyridine in the NaOCl/Mn(porphyrin)x / pyridine catalytic oxygenation system

1984 • 27 citations

Preparation of gem-Dibromocyclopropyl Aldehydes and Acids from Conjugated Dienes.

1978 • 11 citations