Organonitrile complexes of transition metals

The trans-influence: its measurement and significance

1973 • 1,271 citations

Coördination Compounds of Palladous Chloride¹

1938 • 420 citations

Vibrational Spectra and Bonding in Metal Carbonyls. III. Force Constants and Assignments of CO Stretching Modes in Various Molecules; Evaluation of CO Bond Orders

1964 • 320 citations

Studies of the Bonding in Acetonitrile Adducts¹

1966 • 245 citations

Organometallic Chemistry of the Transition Metals. XV. New Olefinic and Acetylenic Derivatives of Tungsten

1966 • 232 citations

Approach to the separation of inductive and mesomeric effects in complexes of the types LMn(CO)5 and LMo(CO)5

1968 • 231 citations

The reactions of metal halides with alkyl cyanides

1965 • 198 citations

Benzonitrile and acetonitrile complexes of ruthenium ammines

1970 • 133 citations

Coordination of organonitriles through CN .pi. systems

1970 • 120 citations

Some new π-cyclopentadienylruthenium complexes

1971 • 116 citations

Properties and reactions of ruthenium(II) amine complexes

1970 • 115 citations

The preparation and reactions of trihaolgeno(alkanonitrile)bis(triphenylphosphine)rhenium(III) complexes

1967 • 109 citations

Nature of the donor-acceptor bond in acetonitrile-boron trihalides. The structures of the boron trifluoride and boron trichloride complexes of acetonitrile

1969 • 109 citations

Complexes with ligands containing nitrile groups. Part III. Infrared spectra of coordinated methyl cyanide

1967 • 106 citations

Octahedral metal carbonyls. XXI. Carbonyl and metal-carbon stretching spectra of monosubstituted group VIB metal carbonyls

1972 • 104 citations

Metal-Catalyzed Hydration of Phenanthroline Nitrile

1967 • 102 citations

Preparation and reactions of tetrahydridotris(triphenylphosphine)ruthenium(IV)

1973 • 100 citations

Copper(I) tetraacetonitrile perchlorate

1975 • 98 citations

Ru(CO)2(PPh3)3 and Os(CO)2(PPh3)3. An ethylene complex of ruthenium and a dioxygen complex of osmium

1972 • 97 citations

Ruthenium promoted oxidation of amines

1975 • 93 citations

Preparative use of blue solutions of ruthenium(II): ruthenium-(II) and -(III) complexes with amines, nitriles, phosphines, etc.

1970 • 91 citations

Base hydrolysis of coordinated acetonitrile

1973 • 85 citations

Nature of the donor-acceptor interaction in boron trihalide complexes. Vibrational spectra and vibrational analysis of acetonitrile-boron trichloride and acetonitrile-boron tribromide

1971 • 82 citations

Stereochemically nonrigid six-coordinate molecules. II. Preparations and reactions of tetrakis(organophosphorus)metal dihydride complexes

1972 • 80 citations

Base hydrolysis of coordinated organonitriles. Reactons of ruthenium(III) and rhodium(III) complexes

1975 • 80 citations

Homogeneously catalyzed hydration of nitriles to carboxamides

1973 • 79 citations

Vibrational spectra, vibrational analysis and bonding in acetonitrile-boron trifluoride

1970 • 77 citations

Synthesis, spectral properties, and reactions of manganese and rhenium pentacarbonyl phosphine and phosphite cation derivatives and related complexes

1975 • 75 citations

Dihydrido(dinitrogen)tris(triphenylphosphine)ruthenium. Dinitrogen bridging ruthenium and boron

1972 • 73 citations

Carbon-13 nuclear magnetic resonance studies. 35. Carbon-13 nuclear magnetic resonance studies of organometallic compounds. I. trans-Methylplatinum(II) derivatives

1973 • 72 citations

Carbon-13 nuclear magnetic resonance studies of organometallic compounds. II. trans-Phenylplatinum(II) derivatives

1974 • 69 citations

An Investigation into the Source of C[UNK]N Vibrational Frequency Shifts

1967 • 67 citations

Preparation and properties of dinitrogen-molybdenum complexes. II. Dinitrogen(organonitrile) complexes of molybdenum

1975 • 60 citations

Trifluoromethylplatinum complexes and the nature of the platinum-trifluoromethyl bond

1972 • 60 citations

Crystal Structure of Cu2Cl4(CH3CN)2, Cu3Cl6(CH3CN)2, and Cu5Cl10(C3H7OH)2

1964 • 56 citations

Komplexchemie von vierzentren-π-systemen IV. Synthese und eigenschaften hochsubstituierter molybdän-carbonyl-derivate

1971 • 55 citations

Cyanopyridine complexes of pentaammineruthenium(II)

1970 • 54 citations

Metal-promoted reactions of 2-cyanopyridine: iron(II), cobalt(II), nickel(II), and copper(II) complexes of O-methylpyridine-2-carboximidate

1969 • 54 citations

Nuclear quadrupole resonance spectra of chlorine in some d 8-transition-metal complexes

1970 • 53 citations

Photochemical reaction pathways of ruthenium(II) complexes. III. Metal-to-ligand charge-transfer excitation of the pentaamminepyridineruthenium(II) cation and related species

1972 • 53 citations

The chemistry of rhenium–nitrile complexes

1968 • 51 citations

Vibrational spectra and bonding in acetonitrile complexes of Group Va pentahalides

1974 • 51 citations

Reactivity of co-ordinated ligands. Part XVIII. Cationic ruthenium(<scp>II</scp>) and osmium(<scp>II</scp>) complexes by electrophilic attack on a π-allyl ligand

1974 • 50 citations

Cationic hydride complexes of iron, ruthenium, and osmium, including a triad of molecular nitrogen complexes

1970 • 50 citations

Hydrolysis of coordinated nitriles to carboxamide complexes of pentaamminecobalt(III)

1972 • 49 citations

Chemical and Structural Studies of Rhenium(V) Oxyhalide Complexes. III. The Crystal and Molecular Structure of Tetraphenylarsonium Oxotetrabromoacetonitrilerhenate(V)

1966 • 48 citations

Cationic organometallic complexes with unsaturated systems. I. Methylplatinum(II)-nitrile and -imino ether complexes

1971 • 44 citations

The crystal structure of diammine bis(acetamidine)platinum(II) chloride monohydrate, Pt(NH3)2[CH3.C.(NH2).NH]2Cl2.H2O

1962 • 43 citations

Reaktionen von Metall(0)‐Verbindungen mit Stickstoff‐π‐Systemen, II. Nickel(0)‐dialkylcyanamid‐carbonyle

1966 • 43 citations

New cationic hydrido and hydrido-dinitrogen complexes of iron

1972 • 41 citations

Reactions of metal carbonyls. Part VI. Formation of cationic carbonyl salts of manganese-(I) and -(II)

1974 • 40 citations

Novel iron carbonyl complex containing arsenic. Crystal structure of .pi.,.sigma.-[1,dimethylarsino-3,3,4,4-tetrafluorinocyclobut-1-en-2-yl] dimethylarsinononacarbonyltriiron

1971 • 40 citations

Synthesis of diiminosuccinonitrile complexes. Preparation and structure of bis(diiminosuccinonitrilo) platinum(II) trans-dichlorobis(benzonitrile)platinum(II)

1975 • 39 citations

Additions of alcohols to simple nitriles coordinated to the cationic pentachlorophenylnickel(II) moiety. Isolation of imidate complexes

1976 • 38 citations

Complexes of alkyl and aryl cyanides—IV Cyanopyridine complexes of nickel (II), palladium (II) and platinum (II) halides

1966 • 37 citations

A π-bonded trifluoroacetonitrile complex of platinum(<scp>0</scp>)

1973 • 37 citations

Infrared and Raman spectra of acetonitrile-antimony pentafluoride

1973 • 36 citations

Bonding of molecular nitrogen in trans-hydrido(dinitrogen)bis(phosphine)iron(II) tetraphenylborate. Moessbauer study

1972 • 36 citations

Nuclear magnetic resonance studies of organonitrile ligands coordinated to rhodium(III) and to ruthenium(II). Demonstration of metal .pi.-orbital electron density delocalization into unsaturated ligands having extended .pi. conjugation

1972 • 36 citations

The mild selective conversion of nitriles to amides

1974 • 35 citations

.pi.-Coordinated nitrile derivatives of halopentacarbonylmanganese(I) and rhenium(I)

1973 • 34 citations

Complexes with ligands containing nitrile groups: Part VII. Metal‐ligand vibrations in methyl cyanide solvates

1968 • 34 citations

Cyanoalkyl complexes of platinum(II)

1976 • 34 citations

Übergangsmetallkomplexe mit N‐haltigen Liganden, III. Donator‐Akzeptor‐Eigenschaften organischer Nitrile im System C₅H₅Mn(CO)₂L

1970 • 33 citations

Cyanoalkyl complexes of platinum(II)

1975 • 33 citations

Strongly catalyzed ligand-ligand reaction within a mixed metal complex

1971 • 32 citations

Übergangsmetallkomplexe mit N‐haltigen Liganden, II. Koordinationsverbindungen des Typs C₅H₅Mn(CO)₂ L mit organischen Nitrilen

1970 • 32 citations

The Preparation and Properties of Some Pentaamminecobalt(III) Complexes

1966 • 31 citations

Reactions of coordinated nucleophiles. Formation of an amide from a nitrile

1972 • 30 citations

Reduction of acetylene and nitrogen by a cobalt-porphyrin system

1972 • 30 citations

Crystal and molecular structure and vibrational spectrum of the vanadium(V) oxide trinitrate-acetonitrile complex, VO(NO3)3.CH3CN

1971 • 30 citations

Synthese von Carbonsäureamiden durch partielle Hydrolyse von PdCI₂-Nitril-Komplexen

1974 • 30 citations

Etude structurale de CuBr.CH3CN

1971 • 29 citations

Preparation and spectral properties of some organonitrile complexes of pentaamminerhodium(III)

1972 • 29 citations

Complexes of alkyl and aryl cyanides. Part VI. The vibrational spectra of MX_2•2RCN, where M = Pd or Pt, X = Cl or Br, and R = Me or Ph, and the assignment of the metal–nitrogen stretching frequency

1968 • 29 citations

σ‐oder π‐Bindung bifunktioneller Donatoren in monosubstituierten Metallcarbonylen

1967 • 28 citations

Preparation and properties of complexes of osmium(II) with carbonyl, nitrosyl, organic cyanide and organic isocyanide ligands

1971 • 28 citations

Rhenium(I) complexes of (2-cyanoethyl)diphenylphosphine

1972 • 27 citations

Computer Analysis of Potentiometric and Thenoyltrifluoroacetone (TTA) Solvent Extraction Studies on the Fluoride Complexes of Hafnium

1963 • 27 citations

The molecular dynamics of fluxional organometallic molecules in the solid state: tetracarbonylbis(cyclooctatetraene)triruthenium(0)

1972 • 27 citations

Spectroscopic characterization of pentaammineruthenium complexes of acrylonitrile

1970 • 27 citations

Studies of Organic Catalytic Reactions. V. The Function of the Chelates formed in the Hydrolysis of 2-Cyanopyridine with Metal Oxide Catalysts

1967 • 26 citations

Étude cristallographique du tétrachloroferrate(III) d'hexaacétonitrile-fer(II)

1972 • 26 citations

Preparation and characterization of some methyl cyanide complexes of Cu(I), Cu(II), and Zn(II) fluorosulfates

1970 • 26 citations

Cyanoalkyl complexes of platinum(II)

1976 • 26 citations

Chemical evolution of a nitrogenase model. VI. Reduction of cyanide ion, azide ion, nitrous oxide, molecular nitrogen, and other substrates by molybdocysteine catalysts in the presence of nucleoside phosphates

1973 • 26 citations

Reduction of new .pi.-bound molybdenocene-nitrile complexes via isolatable iminium intermediates

1975 • 26 citations

COMPLEXES OF ALKYL AND ARYL CYANIDES. PART III. THE FAR-INFRARED SPECTRA (500–200 CM⁻¹) AND ASSIGNMENT OF THE METAL-NITROGEN STRETCHING FREQUENCY IN COMPLEXES WITH PALLADIUM (II), PLATINUM (II), AND RHODIUM (III) HALIDES

1966 • 25 citations

Nitrosyl complexes of rhenium. Crystal and molecular structures of the tetraethylammonium salts of tetrabromo(ethanol)nitrosylrhenate-(II) and of acetonitriletetrabromonitrosylrhenate(II)

1975 • 25 citations

Crystal structure of tetrachloro(trichloro-acetonitrile)pentachloroethylnitrido-tungsten(VI)

1971 • 25 citations

Thermochemistry of metalcarbonyl compounds I. Complexes W(CO)6−n(CH3CN)n(n = 1,2,3)

1976 • 24 citations

Rhenium(I) complexes of (o-cyanophenyl)diphenylphosphine

1974 • 24 citations

The redox nature of the reaction of β-rhenium(<scp>IV</scp>) chloride with triphenylphosphine in acetonitrile, and the crystal structure of the reduction product trichloro(acetonitrile)bis(triphenylphosphine)rhenium(<scp>III</scp>)

1970 • 24 citations

Elektronenreiche übergangsmetallkomplexe

1975 • 24 citations

Hydration of 2-Cyanopyridine with Metal Chelates

1971 • 23 citations

Preparation and spectral studies of a series of rhodium(III)-acetonitrile complexes

1969 • 23 citations

Stereodirection of nucleophilic addition to five-coordinated complexes of iridium

1970 • 23 citations

Kinetics studies of the hydrolysis of coordinated nitriles

1974 • 23 citations

Chemical evolution of a nitrogenase model. V. Reduction of nitriles

1972 • 23 citations

The crystal structure of the 1:2 copper(II) nitrate–methyl cyanide complex

1968 • 23 citations

Some π complexes involving metal carbonyls and the triple bond of diethylaminoacetonitrile

1969 • 23 citations

Reactions of co-ordinated nitriles. Part I. Reactions of cis-(aminoacetonitrile)bis(ethylenediamine)halogenocobalt(III) complexes in aqueous solution

1974 • 23 citations

Organo-nitrile analogues of the nitrogen complex of cobalt, CoHN2(PPh3)3

1969 • 22 citations

Preparation and Characterization of Nitrogen Bonded Nitrile and Amide Complexes of Pentaamminecobalt(III)-Linkage Isomers of Cyanopyridines

1974 • 22 citations

The crystal structure of bis(succinodinitrile)copper(I) perchlorate

1969 • 21 citations

Low frequency infrared spectra of acetonitrile and acrylonitrile derivatives of chromium, molybdenum and tungsten hexacarbonyls

1967 • 20 citations

Reactions of coordinated nucleophiles. Formation and structure of a novel tridentate complex

1972 • 20 citations

Chlorure et bromure de cuivre(I)-benzonitrile

1976 • 20 citations

X-ray crystal structure of racemic bis(ethyl fumarate) (acetonitrile)nickel(0)

1976 • 20 citations

Reactions of manganese and rhenium pentacarbonyl halides with acetonitrile

1971 • 20 citations

Isocyanide, carbene, diethyldithiocarbamate, and cyclo-octa-1,5-diene complexes of platinum(II)

1974 • 19 citations

Crystal Structure of Carbonyl‐(piperidine‐N‐carbonitrile)nickel(0)

1966 • 19 citations

55Mn NQR and infrared intensities of the carbonyl stretching vibrations in group V and olefin derivatives of cyclopentadienylmanganese tricarbonyl

1972 • 19 citations

Reactions of co-ordinated nitriles. Part II. Nickel(II)- and cobalt(II)-promoted hydrolysis of 2-cyano-8-hydroxyquinoline

1974 • 19 citations

Etude cristallographique du diacétonitriletrichloromonooxoniobium(V)

1975 • 17 citations

Hexakisamine-and benzonitrilepentakisamine-complexes of ruthenium(II). The ruthenium induced activation of amines to oxidation

1973 • 17 citations

Spectroscopic studies of perpendicular nitrile-metal interactions

1976 • 16 citations

Preparation of (Ph₃P)₄Ru(π-MeCN)·MeCN

1976 • 16 citations

Base hydrolysis of coordinated benzonitrile. Reactions of rhodium(III) and iridium(III) complexes

1975 • 16 citations

Solid-state interaction of anions and the interaction of solvents with cations of the type [Ru(NH₃)₅(XY)]²⁺

1971 • 16 citations

Synthesis of new platinum isocyanide complexes from [Pt(NCCH3)(CNCH3){P(C6H5)3}2](BF4)2 by facile replacement of acetonitrile by anionic and uncharged ligands

1972 • 15 citations

The bonding of aliphatic dinitriles in halogeno(dinitrile)tricarbonyl-manganses(I) and -rhenium(I) complexes

1971 • 15 citations

Nitrile complexes of zerovalent nickel

1971 • 15 citations

¹³C Nuclear Magnetic Resonance Studies of Organometallic Compounds. V. Di- and Trimethylplatinum(IV) Derivatives

1974 • 15 citations

Catalytic Function of Metal Chelates in the Hydration of 2-Pyridinecarbonitrile

1973 • 15 citations

Klassifizierungen der π-Donatorstärke am Metall in monosubstituierten Metallcarbonylen

1967 • 14 citations

THE TRANSFORMATION OF NITRILES INTO AMIDES BY THE USE OF TiCl₄

1973 • 14 citations

The Preparation, Properties, and some Complexes of Anhydrous Manganese(III) Nitrate

1972 • 13 citations

Synthesis and properties of cobalt(I) compounds. 3. Hydridoacetonitriletris(triaryl phosphite)cobalt complexes

1976 • 12 citations

Complexes of Alkyl and Aryl Cyanides. VIII.^1,2Thecis-andtrans-Isomers of Tetrachlorobis(acetonitrile)rhenium(IV)

1974 • 12 citations

Organonitriles as ligands in low-spin di[1,2-bis(diethylphosphino)ethane]iron complexes

1975 • 11 citations

The Reaction of Bis(2-cyanopyridine)copper(II) Chloride with Amines in Methanol

1971 • 11 citations

Hexacoordinated pentakis(isocyanide)iron(II) compounds

1970 • 11 citations

Activation of co-ordinated nitriles - reduction and carbanion addition

1975 • 10 citations

Etude cristallographique du monoacétonitriletrichloromonooxovanadium(V)

1975 • 10 citations

Pi complexes of 2-cyanophenyldiphenylphosphine with halopentacarbonylmanganese(I)

1973 • 9 citations

Vibrational spectra and structures of the 1:1 complexes of niobium and tantalum, pentachlorides and tantalum pentabromide with aceto-, perdeuterioaceto-, and propio-nitriles in the solid and solution states and a vibrational analysis of the species MX₅,NC·CY₃(Y = H or D)

1970 • 9 citations

Reactions of manganese and rhenium halogenopentacarbonyls with 1,2-dicyanobenzene

1975 • 9 citations

Synthesis and reactions of cationic perfluoropropyliron carbonyl acetonitrile complexes

1976 • 9 citations

The crystal structure of catena-tri-μ₂-(1,12-dodecanedinitrile)copper(II) hexachloroantimonate(V) Cu(C₁₂H₂₀N₂)₃(SbCl₆)₂

1976 • 8 citations

THE CRYSTAL STRUCTURE OF DI-μ-CHLORO-HEXACHLORO-BIS (ETHYL-CYANOFORMATE-N) DITITANIUM (IV)

1974 • 5 citations

Stereospecific exchange reactions of the nitrosyl cations cis-[M(NO)2(MeCN)4]2+(M = Mo or W)

1974 • 5 citations

I.R. spectroscopic evidence for π-bonding of simple nitriles to paramagnetic cobalt-trialkylphosphine species

1975 • 4 citations

Zinc(II)-catalyzed reaction of malononitrile with ethyl alcohol

1971 • 4 citations

C ≡ N Frequency Shifts in Dinitrilo Complexes of Cd²⁺

1974 • 3 citations