Discovering and understanding multiple metal-to-metal bonds

The Nature of the Chemical Bond

1939 • 13,296 citations

The ester enolate Claisen rearrangement. Stereochemical control through stereoselective enolate formation

1976 • 798 citations

Metal-Metal Bonding in [Re₂X₈]^2- Ions and Other Metal Atom Clusters

1965 • 255 citations

The crystal and molecular structures of dichromium tetraacetate dihydrate and dirhodium tetraacetate dihydrate

1971 • 190 citations

The probable existence of a triple bond between two vanadium atoms

1977 • 176 citations

Centenary Lecture. Quadruple bonds and other multiple metal to metal bonds

1975 • 157 citations

487. Molybdenum(II) carboxylates

1964 • 132 citations

The molybdenum-molybdenum triple bond. 1. Hexakis(dimethylamido)dimolybdenum and some homologs: preparation, structure, and properties

1976 • 109 citations

Sensitivity of the chromium-chromium quadruple bond in dichromium tetracarboxylates to axial coordination and changes in inductive effects

1978 • 101 citations

The tungsten-tungsten triple bond. 1. Preparation, properties, and structural characterization of hexakis(dimethylamido)ditungsten(III) and some homologs

1976 • 97 citations

The molybdenum-molybdenum triple bond. 2. Hexakis(alkoxy)dimolybdenum compounds: preparation, properties and structural characterization of hexakis(neopentoxy)dimolybdenum

1977 • 95 citations

Electronic structure of dimolybdenum tetraformate, dimolybdenum(4+) ion, and dimolybdenum

1977 • 95 citations

Electronic and vibrational spectroscopy in a nematic liquid crystal solvent. Band polarizations of binuclear metal carbonyls

1970 • 94 citations

Multiple chromium(II)-chromium(II) and rhodium(II)-rhodium(II) bonds

1970 • 93 citations

The Metal-Metal Bonded, Polynuclear Complex Anion in CsReCl₄

1963 • 89 citations

The structure of crystalline chromous acetate revealing paired chromium atoms

1953 • 88 citations

Electronic structure of octachlorodimolybdate(II)

1975 • 76 citations

Insensitivity of the molybdenum-to-molybdenum quadruple bond in the dimolybdenum tetracarboxylates to axial coordination and changes in inductive effects

1978 • 74 citations

Crystal structure of hexakis(trimethylsilylmethyl)dimolybdenum

1971 • 60 citations

Crystal and molecular structure of anhydrous tetraacetatodichromium

1977 • 59 citations

A Multiple Bond between Technetium Atoms in an Octachloroditechnetate Ion¹

1965 • 52 citations

Magnetic and electrochemical properties of transition metal complexes with multiple metal-to-metal bonds. I. Octachloroditechnetate(n-) and octachlorodirhenate(n-) with n = 2 and 3

1975 • 51 citations

THE PREPARATION AND CRYSTAL STRUCTURE OF DIMOLYBDENUM TETRAFORMATE; PHOTOELECTRON SPECTRA OF THIS AND SEVERAL OTHER DIMOLYBDENUM TETRACARBOXYLATES

1976 • 50 citations

The crystal structure of La₄[Re₂]O₁₀, a fluorite-related structure containing rhenium doublets

1976 • 44 citations

Characterization of the trinegative octachloroditechnetate ion

1970 • 43 citations

Stereochemistry of transition metal cyclooctatetraenyl complexes. Tris(cyclooctatetraene)dichromium, a novel stereochemistry for a compound containing a quadruple metal-metal bond

1976 • 43 citations

Existence of direct metal-to-metal bonds in dichromium tetracarboxylates

1977 • 41 citations

The nature of the metalmetal interaction in tetra-μ-carboxylatochromium(II) systems

1976 • 40 citations

Bonding implications of the resistance of dimolybdenum(II) to attach axial ligands. Structures of two polypyrazolylborate complexes

1976 • 40 citations

Spectroscopic study of the octachloroditechnetate(3-) ion

1977 • 40 citations

The tungsten-to-tungsten triple bond. 7. Replacement of dimethylamido by chloro groups in hexakis(dimethylamido)ditungsten and -dimolybdenum compounds. Preparation, properties, and structure of dichlorotetrakis(dimethylamido) ditungsten and -dimolybdenum

1977 • 39 citations

The tungsten-tungsten triple bond. 6. Hexakis(N,N-dimethylcarbamato)ditungsten and dimethyltetrakis(N,N-diethylcarbamato)ditungsten. Structures and dynamical solution behavior

1977 • 38 citations

Synthesis and structure of dilithium octamethyldirhenate(III)

1976 • 38 citations

A structural and magnetic study of pentachloro-bis(1,5-dithiahexane)dirhenium

1968 • 37 citations

Self-consistent field X.alpha. scattered-wave treatment of the electronic structures of octachlorodimetalate anions of technetium and tungsten

1977 • 36 citations

Exceedingly short metal-to-metal multiple bonds

1977 • 34 citations

1032. Carboxylic acid complexes of rhenium

1963 • 33 citations

Magnetic Evidence for d3s Bond Hybridization in Chromium (II) Acetate. The Oxidation State of Chromium in a Reported Tris(8-Hydroxyquinoline) Chromium (II)

1950 • 30 citations

The molybdenum-molybdenum triple bond. 3. A triple bond between two four-coordinated molybdenum(III) atoms. Structural characterization of the bis(dimethylamine) adduct of dimolybdenum hexatrimethylsiloxide

1978 • 28 citations

Polarized infrared spectroscopy of molecules orientated in a nematic liquid crystal. Application to decacarbonyldimanganese (0) and decacarbonyldirhenium (0)

1969 • 27 citations

Preparation and characterization of compounds containing the octamethylditungsten(II) anion and partially chlorinated analogs

1977 • 27 citations

Detailed electronic description of triple bonds between transition metal atoms and verification by photoelectron spectroscopy

1977 • 27 citations

Cesium octachlorodirhenate(III) hydrate. The correct structure and its significance with respect to the nature of metal-metal multiple bonding

1977 • 26 citations

Preparation and structure of a quadruply bonded dimolybdenum compound containing the 7-azaindolyl ligand

1978 • 26 citations

Darstellung und Eigenschaften einiger Chrom(II)‐n‐alkanate. I Chrom(II)‐acetat und höhere Homologe

1964 • 25 citations

A quadruple bond between tungsten atoms in an air-stable compound

1977 • 25 citations

The tungsten-tungsten triple bond. 2. Preparation, structure, and dynamical behavior of dichlorotetrakis(diethylamido)ditungsten

1976 • 25 citations

Preparative and structural studies of halodimolybdates(II). I. Preparation and crystal structure of (picH)₂Mo₂Br₆(H₂O)₂

1976 • 24 citations

Crystal and molecular structure of bis-.mu.-(benzoato)-1,2-dibromo-1,2-bis(tri-n-butylphosphine)dimolybdenum(II), [(n-C4H9)3P]2(C6H5CO2)2Mo2Br2

1976 • 24 citations

Identification and properties of dinegative octachloroditechnetate(III)

1977 • 24 citations

Interaction of magnesium dialkyls with binuclear transition metal acetates: crystal structure of bis(trimethylsilylmethyl)bis(trimethylphosphine) bis(µ-trimethylsilymethyl)-dichromium(<scp>II</scp>)

1977 • 23 citations

Crystallographic proof of the stability of a quadruple bond between tungsten atoms

1977 • 22 citations

The tungsten-tungsten triple bond. 3. Dimethyltetrakis(diethylamido)ditungsten. Structure and dynamical solution behavior

1976 • 22 citations

Preparation and structure of a multiply bonded dirhenium(5+) species bridged by two diphosphinomethane ligands

1976 • 22 citations

Tetrakis(glycine)dimolybdenum disulfate tetrahydrate

1976 • 21 citations

The tungsten-tungsten triple bond. 5. Chlorine atom substitution reactions involving dichlorotetrakis(diethylamido)ditungsten. Preparation, properties, structures, and dynamical solution behavior of bis(trimethylsilylmethyl)-, dibromo- and diiodotetrakis(diethylamido)ditungsten

1977 • 21 citations

Structure of tetrakis(benzoato)dimolybdenum(II)

1976 • 19 citations

Darstellung und Eigenschaften einiger Chrom(II)‐n‐alkanate; II. Hydrate des Chrom(II)‐formiats [1]

1964 • 15 citations

Preparation and Properties of Some Tungsten Carboxylates

1971 • 14 citations

Insertion reactions of carbon dioxide with triply bonded ditungsten dialkylamido compounds. Structures and dynamic properties of the resulting carbamato complexes

1976 • 13 citations

The metal-metal bond in the trinegative octachloroditechnetate ion

1974 • 7 citations