Patterns of organometallic reactions related to homogeneous catalysis

The preparation and properties of tris(triphenylphosphine)halogenorhodium(I) and some reactions thereof including catalytic homogeneous hydrogenation of olefins and acetylenes and their derivatives

1966 • 1,394 citations

CARBONYL AND HYDRIDO-CARBONYL COMPLEXES OF IRIDIUM BY REACTION WITH ALCOHOLS. HYDRIDO COMPLEXES BY REACTION WITH ACID

1961 • 268 citations

Kinetics of the Addition of Hydrogen, Oxygen, and Methyl Iodide to Some Square-Planar Iridium(I) Complexes¹

1966 • 249 citations

154. The tautomerism of arene and ditertiary phosphine complexes of ruthenium(0), and the preparation of new types of hydrido-complexes of ruthenium(II)

1965 • 231 citations

Selective formation of carbon-carbon bonds between unlike groups using organocopper reagents

1967 • 221 citations

Oxygen-Carrying Properties of a Simple Synthetic System

1963 • 198 citations

Activation of Hydrogen by a Transition Metal Complex at Normal Conditions Leading to a Stable Molecular Dihydride

1962 • 189 citations

Carbon monoxide insertion reactions V. The carbonylation of methylmanganese pentacarbonyl with 13CO

1967 • 163 citations

Acetylene Complexes of Iridium and Rhodium

1967 • 153 citations

Iridium complexes of molecular nitrogen

1968 • 140 citations

Nitrogen Fixation by Transition Metal Complexes

1966 • 139 citations

Olefin Coordination Compounds of Rhodium. II. The Mechanism of Ethylene Dimerization

1965 • 131 citations

Oxygen Complexes of Zerovalent Nickel, Palladium, and Platinum

1967 • 127 citations

The Polymerization of Acetylenes by Nickel-Carbonyl-Phosphine Complexes. IV. Kinetics and Polymerization Mechanisms¹

1962 • 126 citations

Preparation and Oxidative Addition Reactions of a Monomeric Ruthenium(0) Complex

1965 • 119 citations

Addition reactions of tris(triphenylphosphine)chlororhodium(I); hydrido-, alkyl, and acyl complexes; carbon monoxide insertion and decarbonylation reactions

1967 • 112 citations

Far-infrared spectra of complexes of rhodium and iridium with .pi.-bonding ligands

1967 • 98 citations

Homogeneous Catalytic Hydrogenation of Ethylene and Acetylene with Four-Coordinated Iridium and Rhodium Complexes. Reversible Catalyst-Substrate Adducts¹

1965 • 98 citations

Reactions with Molecular Oxygen

1967 • 91 citations

A New Series of Four-, Five-, and Six-Coordinated Iridium Complexes

1966 • 88 citations

Binuclear Ion Containing Nitrogen as a Bridging Group

1968 • 83 citations

Nucleophilicity of low-valent metal complexes. I. The reactions of platinum(0) complexes with alkyl and acyl halides

1967 • 79 citations

Stereochemistry of oxidative addition reactions of iridium(I) complexes

1968 • 72 citations

Formation of Ru(NH3)5N22+ in aqueous solution by direct action of molecular nitrogen

1967 • 70 citations

The Homogeneous Hydrogenation of Acetylenes by Dicyclopentadienyltitaniumdicarbonyl

1966 • 65 citations

Formation of Ammonia by Insertion of Molecular Nitrogen into Metal-Hydride Bonds. I. the Formation of Dimeric Dicyclopentadienyltitanium(III) Hydride as all Intermediate in the Vol'pin-Shur Nitrogen-Fixing System

1966 • 64 citations

Hydrido and Carbonylhydrido Complexes of Iridium Containing Stannous Chloride

1966 • 57 citations

Olefin Coordination Compounds of Rhodium. IV. The Mechanisms of the Synthesis of 1,4-Hexadiene from Ethylene and Butadiene and of Its Isomerization to 2,4-Hexadiene

1967 • 56 citations

Pentacoordinate iridium(I) and rhodium(I) complexes derived from metal carbonyl anions

1968 • 51 citations

Synthesis and Oxidative Addition Reactions of a Phosphine Carbonyl Complex of Osmium(0)¹

1966 • 50 citations

Stereospecific Addition of Hydrogen Halides to Tetragonal d⁸ Complexes

1966 • 49 citations

992. Metal–metal bonds. Part IV. Formation of iridium–mercury bonds by oxidation with mercury halides

1965 • 48 citations

The Mechanism of the Formation of an Iridium Complex of Molecular Nitrogen via Organic Azides

1967 • 46 citations

Molecular Structure of the Synthetic Molecular Oxygen Carrier O ₂ IrCl(CO)(P[C ₆ H ₅ ] ₃ ) ₂

1964 • 41 citations

Reverisble combination of molecular nitrogen wiith a cobalt complex.Exchange reactions of nitrogen-tris(triphenylphosphine)cobalt with hydrogen, ethylene, and ammonia

1967 • 39 citations

1008. Triphenylgermylplatinum complexes

1965 • 30 citations

Homogeneous catalytic hydrogenation of unsaturated fats: Iron Pentacarbonyl

1964 • 29 citations

Halogenocarbonyl complexes of iridium(I) containing tertiary phosphines and tertiary arsines

1967 • 28 citations

Incorporation of molecular nitrogen into an organic molecule

1967 • 27 citations

Carbonyl compounds of trivalent rhodium with aromatic phosphines, arsines and stibines

1958 • 21 citations

Characterization of a methyl linoleate‐iron carbonyl complex

1964 • 12 citations

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