Singlet methylene kinetics: Direct measurements of removal rates of ã1A1 and b̃1B1 CH2 and CD2

Molecular Spectra and Molecular Structure

1979 • 15,902 citations

Molecular Spectra and Molecular Structure

1929 • 1,910 citations

The Bakerian Lecture, The spectra and structures of free methyl and free methylene

1961 • 485 citations

The spectrum and structure of singlet CH ₂

1966 • 278 citations

Flash Photolysis of Ketene and Diazomethane: The Production and Reaction Kinetics of Triplet and Singlet Methylene

1970 • 195 citations

The role of intermolecular potential well depths in collision-induced state changes

1979 • 173 citations

Intramolecular perturbations and the quenching of luminescence in small molecules

1973 • 147 citations

Laser photoelectron spectrometry of methylene(1-). Singlet-triplet splitting and electron affinity of methylene

1976 • 142 citations

Rate constants for the gaseous interaction of O(21D2) and O(21S0 - a critical evaluation

1978 • 137 citations

Laser induced fluorescence from NH2(2A1). State selected radiative lifetimes and collisional de-excitation rates

1975 • 124 citations

Experimental determination of the singlet-triplet splitting in methylene

1978 • 117 citations

Laser-Excited Electronic Fluorescence: Collision-Induced Radiationless Transitions in Propynal

1972 • 105 citations

The Photochemistry of Hydrocarbons in the Jovian Atmosphere

1973 • 97 citations

Collision-induced predissociation by van der Waals' interaction

1969 • 92 citations

The kinetics of free radicals generated by IR laser photolysis. II. Reactions of C2(X 1Σ+g), C2(a 3Πu), C3(X̄ 1Σ+g) and CN(X 2Σ+) with O2

1980 • 85 citations

The kinetics of free radicals generated by IR laser photolysis. I. Reactions of C2(a 3Πu) with NO, vinyl cyanide, and ethylene

1979 • 76 citations

Reactions of C2(a 3πu) with CH4, C2H2, C2H4, C2H6, and O2 using multiphoton UV excimer laser photolysis

1979 • 71 citations

Absolute rate constant for the reaction of CH with O2

1979 • 63 citations

A method to estimate intermolecular potential well depths for species in both ground and excited electronic states

1979 • 59 citations

Laser induced fluorescence of CH2 (ã1A1) produced in the photodissociation of ketene at 337 nm. The CH2 (ã1A1-X̃3B1)energy separation

1978 • 57 citations

Laser induced fluorescence spectrum of singlet methylene. Spectroscopy of the a~1A1 state

1978 • 56 citations

Laser induced production of excited states of PH and PH2 from phosphine

1978 • 56 citations

Rate constants for reactions of methylene with carbon monoxide, oxygen, nitric oxide, and acetylene

1974 • 55 citations

The Reactions of Methylene. VI. The Addition of Methylene to Hydrogen and Methane

1962 • 51 citations

The threshold for photodissociation of ketene into CH2(a1A1) and the CH2(a1A1—X3B1) energy separation

1978 • 51 citations

The kinetics of free radicals generated by IR laser photolysis. III. Intersystem crossing between C2(X 1Σg+) and C2(a 3Πu) induced by collisions with oxygen

1980 • 44 citations

Rate constants for the deactivation of O(1D) by Xe, Kr, and Ar over the range 110–330 K

1978 • 43 citations

Effect of Pressure in the Radiolysis and Photolysis of Methane

1964 • 42 citations

Collisional deactivation of the electronically excited atoms, S(31 D 2) and S(31 S 0), by the noble gases

1970 • 41 citations

Quenching of C2(a 3Πu) produced in an intense infrared laser field

1979 • 40 citations

Lifetimes of the vibronic Ã2A1 states of H2S+

1975 • 40 citations

Collision-Induced Singlet→Triplet Intersystem Crossing of Methylene and Methylene-d2

1970 • 39 citations

New vibronic bands of CH2 observed in a pulsed supersonic jet

1980 • 39 citations

Austausch von Schwingungs- und Translationsenergie zwischen angeregten Jodmolek�len und Edelgasen

1935 • 39 citations

Direct measurements of ã 1A1 CH2 removal rates

1980 • 35 citations

Energy transfer in the 1A u state of glyoxal. III. Deuterium effects

1977 • 26 citations

The asymmetric rotor in electronic spectroscopy: Centrifugal distortion and electron spin coupling effects in the spectra of NH2 and CH2

1968 • 26 citations

Laser excited fluorescence of CH in a low pressure flame

1978 • 26 citations

Rotational relaxation in mixtures of methane with helium, argon and xenon

1972 • 26 citations

Collision induced singlet to triplet transition of methylene. 2. Numerical tests of two theories

1976 • 24 citations

Oxirene intermediate in the reaction of singlet methylene with carbon monoxide

1971 • 23 citations

Multiple-photon dissociation of CH 2 CO, C 2 H 4 and C 4 H 6 O 3 , fluence dependence of the production of CH 2 (ã) and C 2 (a)

1979 • 22 citations

Methylene reaction rates. Quantum yields in the diazomethane-propane photolysis system: effects of photolysis time, reactant ratios, and added gases

1971 • 20 citations

Laser induced fluorescence of the PH2 radical

1978 • 19 citations

Collisional deactivation of singlet methylene in the photolysis of ketene

1969 • 18 citations

Rotational relaxation in mixtures of tetradeuteromethane with helium, neon, argon and xenon

1974 • 17 citations

Laser intensity effects in the rotational distributions of CN radicals formed by IR multiple photon dissociation of C2H3CN

1980 • 16 citations

Reaction of Methylene Radicals with Acetylene in the Gas Phase

1963 • 15 citations

Comment on collision induced electronic relaxation

1972 • 15 citations

Photolysis of ketene in the presence of carbon monoxide

1967 • 13 citations

Measurements of the radiative lifetime of CH2(b1B1) and absolute CH2(b1B1) → a1A1) emission cross sections for electrons (0–2000 eV) on CH4

1976 • 10 citations

Reactions of methylene with ethers. Part 2.—With ethyl methyl ether

1968 • 9 citations

Photolysis of ketene in the presence of carbon monoxide

1967 • 6 citations