The high temperature pyrolysis of 1,3‐butadiene: heat of formation and rate of dissociation of vinyl radical

Thermochemical kinetics

1970 • 3,579 citations

Hydrocarbon Bond Dissociation Energies

1982 • 1,961 citations

Additivity rules for the estimation of thermochemical properties

1969 • 1,378 citations

Bond Dissociation Energies by Kinetic Methods

1966 • 934 citations

Predictive possibilities of unimolecular rate theory

1979 • 808 citations

Theory of thermal unimolecular reactions at low pressures. II. Strong collision rate constants. Applications

1977 • 650 citations

Molecular orbital theory of the electronic structure of organic compounds. X. Systematic study of geometries and energies of AHn molecules and cations

1971 • 450 citations

Molecular orbital theory of the electronic structure of organic compounds. VI. Geometries and energies of small hydrocarbons

1971 • 253 citations

Refractivity of combustion gases

1981 • 243 citations

Soot formation in shock-tube pyrolysis of acetylene, allene, and 1,3-butadiene☆

1983 • 178 citations

Kinetics of diene reactions at high temperatures

1951 • 157 citations

Mechanisms for some high-temperature gas-phase reactions of ethylene, acetylene, and butadiene

1967 • 115 citations

Application of RRKM theory to the reactions OH + NO₂+ N₂→ HONO₂+ N₂(1) and ClO + NO₂+ N₂→ ClONO₂+ N₂(2); a modified gorin model transition state

1978 • 94 citations

Examination of Possible Non-Arrhenius Behavior in the reactions

1973 • 92 citations

Ground states of molecules. 58. The C4H4 potential surface

1981 • 90 citations

Kinetics and mechanism of the pyrolysis of 1,4-cyclohexadiene

1967 • 64 citations

The very high temperature pyrolysis of ethylene and the subsequent reactions of product acetylene

1983 • 64 citations

SHOCK TUBE EXPERIMENTS ON THE PYROLYSIS OF ETHYLENE

1960 • 60 citations

Refractive index change and curvature in shock waves by angled beam refraction

1981 • 60 citations

Kinetics of oxygen atom formation during the oxidation of methane behind shock waves

1974 • 59 citations

Evidence for strongly temperature‐dependent A factors in alkane decomposition and high heats of formation for alkyl radicals

1978 • 58 citations

The Polymerization of Gaseous Butadiene

1939 • 56 citations

Thermal decomposition of ethylene

1980 • 56 citations

Ab initio calculation of the transition-state properties and addition rate constants for atomic hydrogen + acetylene and selected isotopic analogs

1982 • 55 citations

Free Radicals by Mass Spectrometry. XVII. Ionization Potential and Heat of Formation of Vinyl Radical

1960 • 53 citations

A shock tube, laser-schlieren study of propene pyrolysis at high temperatures

1982 • 49 citations

The thermal unimolecular isomerisation of bicyclo[3,1,0]hex-2-ene and decomposition of cyclohexa-1,4-diene

1966 • 42 citations

Mass-spectrometric studies of rate constants for addition reactions of hydrogen and of deuterium atoms with olefins in a discharge-flow system at 300.deg.K

1971 • 41 citations

Shock-tube study of propane pyrolysis. Rate of initial dissociation from 1400 to 2300 K

1983 • 41 citations

SOME KINETICS OF THE CARBONIZATION OF BENZENE, ACETYLENE AND DIACETYLENE AT 1200°

1961 • 37 citations

Pyrolysis of benzene behind reflected shock waves☆

1983 • 35 citations

Kinetics of the reaction: 2C₂H₄ → C₂H₅ + C₂H₃· heat of formation of the vinyl radical

1983 • 35 citations

IODINATION IN LIQUID AMMONIA

1932 • 33 citations

Application of RRKM theory using a hindered rotational Gorin model transition state to the reaction peroxynitric acid + nitrogen .dblarw. hydroperoxo + nitrogen dioxide + nitrogen

1978 • 31 citations

Product profiles observed during the pyrolyses of toluene, benzene, butadiene, and acetylene

1982 • 28 citations

Kinetics of decomposition and interconversion of 3-methylbut-1-yne and 3-methylbuta-1,2-diene. Resonance stabilization energies of propargylic radicals

1981 • 22 citations

The Rate Constants for H and D-Atom Additions to O2, NO, Acetylene, and 1,3-Butadiene

1979 • 16 citations

Very low‐pressure pyrolysis (VLPP) of pentynes. I. Kinetics of the retro‐ene decomposition of pent‐1‐yne

1981 • 14 citations

Isotope effects in the hydrogen-atom addition to olefins at low temperatures

1970 • 14 citations

Very low‐pressure pyrolysis (VLPP) of pentynes. II. 4‐methylpent‐2‐yne and 4,4‐dimethylpent‐2‐yne. Heats of formation and resonance stabilization energies of methyl‐substituted propargyl radicals

1981 • 13 citations

860. The formation of aromatic hydrocarbons at high temperatures. Part XI. The pyrolysis of buta-1,3-diene and of buta-1,3-diene with pyrene

1960 • 12 citations

Reaction of hydrogen and carbon dioxide behind reflected shock waves

1976 • 11 citations

Secondary Reactions of Olefins in Pyrolysis of Petroleum Hydrocarbons

1970 • 9 citations

The Gaseous-Ion Sensitized Formation of Hydrogen Atoms

1960 • 6 citations

Comparative rates of exchange behind reflected shock waves. 1. Carbon monoxide (oxygen-18) + carbon dioxide vs. carbon-13 monoxide + carbon dioxide

1978 • 3 citations

Nonrandom isomerization of c i s-3-methyl-1,3-pentadiene-1,2-d2. Internal energy relaxation

1979 • 1 citations