Detection of the Silyl Radical Si<mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline"><mml:mrow><mml:msub><mml:mrow><mml:mi mathvariant="normal">H</mml:mi></mml:mrow><mml:mrow><mml:mn>3</mml:mn></mml:mrow></mml:msub></mml:mrow></mml:math>by Infrared Diode-Laser Spectroscopy

Semiconductors and semimetals

1973 • 1,166 citations

Diode laser study of the ν2 band of the methyl radical

1981 • 277 citations

ESR of Free Radicals Trapped in Inert Matrices at Low Temperature: CH3, SiH3, GeH3, and SnH3

1966 • 141 citations

Infrared and Ultraviolet Spectra of the Products of the Vacuum-Ultraviolet Photolysis of Silane Isolated in an Argon Matrix

1970 • 127 citations

Silane in IRC +10216

1984 • 111 citations

Electron Spin Resonance of Free Radicals Formed from Group-IV and Group-V Hydrides in Inert Matrices at Low Temperature

1968 • 107 citations

Infrared spectrum of CO2 in the region of the bending fundamental ν2

1980 • 88 citations

Experimental Determination of the Ground-State Inversion Splitting in<mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline"><mml:mrow><mml:msub><mml:mrow><mml:mi mathvariant="normal">H</mml:mi></mml:mrow><mml:mrow><mml:mn>3</mml:mn></mml:mrow></mml:msub></mml:mrow></mml:math><mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline"><mml:mrow><mml:msup><mml:mrow><mml:mi mathvariant="normal">O</mml:mi></mml:mrow><mml:mrow><mml:mo>+</mml:mo></mml:mrow></mml:msup…

1985 • 86 citations

Observation of the ν2 (1−←0+) inversion mode band in H3O+ by high resolution infrared spectroscopy

1984 • 86 citations

Diode laser absorption spectroscopy of D3O+: Determination of the equilibrium structure and potential function of the oxonium ion

1985 • 80 citations

Matrix isolation studies of the reactions of silicon atoms with molecular hydrogen. The infrared spectrum of silylene

1985 • 79 citations

Infrared spectrum of the ν2 vibration-inversion band of H3O+

1985 • 65 citations

A b i n i t i o study of the vibrational dependence of hyperfine coupling constants in the methyl, silyl, and formaldehyde anion radicals

1980 • 64 citations

Diode laser spectroscopy of the CCl radical

1981 • 61 citations

Vacuum ultraviolet photoelectron spectroscopy of transient species. XVII. The SiH3(X 2A1) radical

1983 • 54 citations

Thev₂spectrum of NH₃

1984 • 53 citations

Infrared spectroscopy of molecular ions in a magnetically confined glow discharge

1984 • 38 citations

Infrared laser spectroscopy of H_3O^+ between 510 and 1150 cm^−1

1985 • 35 citations

Laboratory measurement of the P(2,1) submillimeter transition frequency of H3O+

1985 • 33 citations

An SCF–CI study of the structures, inversion barriers, and inversion frequencies of SiH3, PH3+, and SH3++

1981 • 31 citations

Infrared spectrum of isotopic carbon dioxide in the region of bending fundamental ν2

1985 • 27 citations

An ab initio calculation of the potential surface and rotation—vibration energies of the silyl radical

1984 • 25 citations