Matrix‐Isolation Applied to High‐Temperature and Interstellar Molecules: A Review

Large Molecules in Carbon Vapor

1959 • 407 citations

Thermodynamic Study of SiC Utilizing a Mass Spectrometer

1958 • 363 citations

Gauge invariance of the g tensor

1963 • 274 citations

Analysis of the 4050-Å Group of the C_{3} Molecule.

1965 • 273 citations

The ethynyl radical C2H - A new interstellar molecule

1974 • 265 citations

The relationship between electron spin rotation coupling constants andg-tensor components

1965 • 252 citations

Laboratory Microwave Spectrum of HC<mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline"><mml:mrow><mml:msup><mml:mrow><mml:mi mathvariant="normal">O</mml:mi></mml:mrow><mml:mrow><mml:mo>+</mml:mo></mml:mrow></mml:msup></mml:mrow></mml:math>

1975 • 239 citations

Spectroscopic Study of the Vacuum-Ultraviolet Photolysis of Matrix-Isolated HCN and Halogen Cyanides. Infrared Spectra of the Species CN and XNC

1967 • 216 citations

ESR Study of Ethynyl and Vinyl Free Radicals

1964 • 212 citations

On Graphite Particles as Interstellar Grains

1962 • 193 citations

A new spectrum associated with diatomic carbon

1968 • 159 citations

Polymeric Gaseous Species in the Sublimation of Molybdenum Trioxide

1957 • 139 citations

Vacuum-Ultraviolet Photolysis of Acetylene in Inert Matrices. Spectroscopic Study of the Species C2

1967 • 136 citations

Mass-Spectrometric Study of the Oxidation of Tungsten

1965 • 127 citations

Infrared and Ultraviolet Spectra of the Products of the Vacuum-Ultraviolet Photolysis of Silane Isolated in an Argon Matrix

1970 • 127 citations

The A'^{3}Σ_{g} - Χ'^{3}Π_{u} Band System of the C_{2} Molecule.

1963 • 124 citations

Carbonylsilene, diazasilene, and dicarbonylsilene molecules: electron spin resonance and optical spectra at 4 K

1977 • 121 citations

Spectroscopy of carbon molecules. IV. C4, C5, C6 (and C9)

1971 • 119 citations

ESR of Cu(NO3)2 and CuF2 Molecules Oriented in Neon and Argon Matrices at 4°K

1966 • 115 citations

Tentative Detection of the C3N Radical

1977 • 113 citations

ESR of the CN Radical in Inert Matrices

1970 • 112 citations

Microwave Absorption Spectrum of the C<mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline"><mml:mrow><mml:msup><mml:mrow><mml:mi mathvariant="normal">O</mml:mi></mml:mrow><mml:mrow><mml:mo>+</mml:mo></mml:mrow></mml:msup></mml:mrow></mml:math>Ion

1975 • 108 citations

B atoms, B2 and H2BO molecules: ESR and optical spectra at 4 °K

1976 • 107 citations

Matrix isolation study of the vacuum ultraviolet photolysis of allene and methylacetylene. Vibrational and electronic spectra of the species C3, C3H, C3H2, and C3H3

1974 • 107 citations

Laboratory Excitation of the Blue-Green Bands Observed in the Spectra of N-Type Stars.

1956 • 102 citations

C2H radical: 13C hyperfine interaction and optical spectrum

1974 • 102 citations

The c4 Molecule

1976 • 102 citations

Chemiluminescence and photoluminescence of diatomic iron oxide

1975 • 98 citations

The Band System of the CCO Molecule

1971 • 97 citations

Spectroscopy of titanium oxide and titanium dioxide molecules in inert matrices at 4.deg.K

1971 • 97 citations

A THERMODYNAMIC STUDY OF THE TUNGSTEN-OXYGEN SYSTEM AT HIGH TEMPERATURES¹

1963 • 94 citations

Laboratory Microwave Spectrum and Rest Frequencies of the N2H(+) Ion

1976 • 93 citations

Spectroscopy of Silicon Carbide and Silicon Vapors Trapped in Neon and Argon Matrices at 4° and 20°K

1964 • 93 citations

Studies of the Photoproduction of Electrons in Inert Solid Matrices. The Electronic Spectrum of the Species C2−

1969 • 92 citations

Infrared Spectroscopic Evidence for the Species HNC

1963 • 91 citations

Bond Angles and Bonding in Group IIa Metal Dihalides^1a

1966 • 89 citations

Laser photoelectron spectrometry of FeO−: Electron affinity, electronic state separations, and ground state vibrations of iron oxide, and a new ground state assignment

1977 • 87 citations

Polymeric Gaseous Species in the Sublimation of Tungsten Trioxide

1957 • 85 citations

Spectroscopy of TaO and TaO2 in Neon and Argon Matrices at 4° and 20°K

1965 • 81 citations

Wavefunctions and Binding Energies of the Titanium Monoxide Molecule

1964 • 81 citations

The structure of inorganic radicals : an application of electron spin resonance to the study of molecular structure

1967 • 79 citations

Spectroscopy of Titanium, Zirconium, and Hafnium Oxides in Neon and Argon Matrices at 4 and 20°K.

1965 • 79 citations

Electronic Structure of the B2 Molecule

1967 • 79 citations

The laboratory microwave spectrum of the cyanide radical in its X 2Σ+ ground state

1977 • 77 citations

Theoretical prediction of the vertical electronic spectrum of the C2H radical

1977 • 76 citations

The identification of UN in Ar matrices

1976 • 74 citations

Mass Spectrometric Investigation of the Sublimation of Molybdenum Dioxide

1960 • 72 citations

Hyperfine Interaction, Chemical Bonding, and Isotope Effect in ZnH, CdH, and HgH Molecules

1971 • 71 citations

The microwave spectrum of hydrogen isocyanide

1976 • 68 citations

The formation of interstellar molecules

1976 • 68 citations

The Spectroscopy of Diatomic Transition Element Molecules

1967 • 67 citations

Titanium difluoride and titanium trifluoride molecules: electron spin resonance spectra in rare-gas matrices at 4 K

1977 • 66 citations

Spectroscopy of tungsten oxide molecules in neon and argon matrices at 4° and 20°K

1965 • 66 citations

Mass-Spectrometric Investigation of the Oxidation of Molybdenum and Tungsten

1963 • 66 citations

DETECTION OF SEVERAL NEW INTERSTELLAR MOLECULES

1972 • 65 citations

SPECTROSCOPIC EVIDENCE OF THE B₂ MOLECULE AND DETERMINATION OF ITS STRUCTURE

1940 • 61 citations

Optical spectra of Be atoms and Be2 molecules in rare gas matrices

1975 • 60 citations

On the Formation of Graphite Grains in Cool Stars

1968 • 60 citations

Natural Orbital Valence Shell CI Studies of Diatomic Molecules. II. Potential Energy Curves and Spectra of Boron Carbide

1970 • 56 citations

Spin-dependent interactions for linear molecules in Σ states of quartet and higher multiplicity

1976 • 55 citations

ESR of VO in Argon Matrix at 4°K; Establishment of Its Electronic Ground State

1968 • 53 citations

Absorption and Laser-Excited Fluorescence of Matrix-Isolated CuO

1970 • 53 citations

Optical absorption spectra of PtO and Pt2 in rare-gas matrices

1976 • 52 citations

Diatomic hydride and deuteride spectra of the second row transition metals

1973 • 52 citations

ESR and Optical Spectroscopy of the RhC Molecule at 4°K

1972 • 50 citations

Hyperfine interaction and chemical bonding in the PdH molecule

1971 • 49 citations

Molecular ions and electron transport in rare gas lattices: C−2 formation mechanism and X 2Σ+g↔B 2Σ+u spectroscopy

1975 • 48 citations

Lowest 5Σ+ state of FeO: An ab initio investigation

1973 • 47 citations

Theoretical study of the butadiynyl and cyanoethynyl radicals - Support for the identification of C3N in IRC + 10216

1977 • 46 citations

Rotational analysis of the red electronic emission system of titanium nitride

1970 • 46 citations

ESR of the triplet molecules CCO and CNN in rare-gas matrices; isotope and matrix effects

1975 • 45 citations

The Spectrum of FeH: Laboratory and Solar Identification

1972 • 45 citations

On the Spin-Doubling Constant, γ, and g Tensor in 2Σ Molecules*

1970 • 45 citations

Thermochemical properties of gaseous ZrO and ZrO2

1975 • 44 citations

Absorption spectra of molybdenum oxide molecules and molybdenum atoms in neon and argon matrices at 4.deg.K

1975 • 44 citations

Optical and ESR spectra of the C4H radical in rare gas matrices at 4 K

1975 • 43 citations

Electronic States in the C₄ Molecule^1a

1961 • 43 citations

Rotational Structure in the A²Σ⁺, B²Σ⁺, and a⁴Σ⁻ – X²Π Transitions of GeF

1973 • 42 citations

LCAO-MO SCF Study of B2

1959 • 42 citations

Stellar and Other High-Temperature Molecules

1967 • 42 citations

Interstellar CN at radio wavelengths

1975 • 42 citations

The Matrix-Isolation Technique Applied to High Temperature Molecules

1969 • 40 citations

ESR of the BC2 Molecule in Inert Matrices at 4°K

1970 • 39 citations

NbO molecule: ESR and optical spectra in inert matrices at 4 °K; establishment of its ground electronic state as 4Σ

1974 • 38 citations

C2 and C2− Spectra Produced by the X Irradiation of Acetylene in Rare-Gas Matrices

1971 • 38 citations

Phosphorescent Decay Time of Matrix-Isolated GeO, GeS, SnO, and SnS, and the Lifetime of the Cameron Bands of CO-Type Diatomics

1970 • 38 citations

THE ROTATIONAL ENERGY LEVELS OF DIATOMIC MOLECULES IN ⁴Σ ELECTRONIC STATES

1962 • 38 citations

Laser Excited Fluorescence Studies of Matrix Isolated C2−

1972 • 37 citations

Guidelines for interpreting electron spin resonance spectra of paramagnetic species adsorbed on surfaces

1968 • 36 citations

Electronic Structure of Molecules of High Temperature Interest

1967 • 36 citations

On the low-lying electronic states of ScH

1974 • 35 citations

ESR and optical spectra of C2− in various ion pairs trapped at 4°K in solid argon

1974 • 33 citations

On the low-lying electronic states of TiH

1974 • 31 citations

MOLECULAR ORBITAL CALCULATIONS OF THE LOW-LYING ELECTRONIC STATES OF THE TITANIUM MONOXIDE MOLECULE^1,2

1963 • 31 citations

Absorption Spectrum of the SiC₂ Radical in the Gaseous Phase

1974 • 30 citations

Ground State of Gaseous FeO

1969 • 30 citations

High Temperature Chemistry: Stabilities and Structures of High Temperature Species

1970 • 29 citations

Millimeter wave spectrum of CaO

1977 • 28 citations

Flame spectroscopy of TiO

1977 • 28 citations

Hyperfine Splittings in the Optical Spectrum of NbO+

1969 • 27 citations

Hyperfine Structure of the CN Radical Determined from Astronomical Observations

1974 • 26 citations

A Microwave Spectrometer with an Internal Glow Discharge

1973 • 26 citations

Silicon carbide - Its ground state and predicted spectrum

1974 • 25 citations

Spectroscopy and Franck-Condon Factors of Scandium Fluoride in Neon Matrices at 4°K

1966 • 25 citations

The electronic (yellow and violet) emission spectra of zirconium nitride

1976 • 24 citations

Electron resonance of gaseous free radicals

1968 • 21 citations

On the band spectrum of IrO in the region 4200–6400 Å

1972 • 21 citations

Singlet Electronic States of the TiO Molecule.

1950 • 20 citations

g-tensor and spin doubling constant in the 2Σ molecules CN and C2H

1976 • 20 citations

Multiconfiguration studies of some low-lying bound states of VH

1975 • 20 citations

The Structure of the X⁷ State of MnH and MnD

1957 • 19 citations

The emission spectrum of RuO between 5000 and 6800 Å

1975 • 19 citations

Nuclear Hyperfine Structure in the Electronic Spectra of Diatomic Molecules

1972 • 18 citations

Laser photoluminescence of TiO in Ne at 4 °K

1975 • 16 citations

Spectra of matrix isolated transition metal monoxides. Manganese(II) and copper(II) oxides. Evidence for a 2.PI. ground state for copper(II) oxide

1973 • 16 citations

Rotational structure of the 5300 AA band of titanium hydride, TiH

1974 • 15 citations

On the ligand field effect of the H atom in TiH and VH

1974 • 15 citations

Laser photoluminescence of zirconium oxide at 4 K

1976 • 14 citations

Ground State of Zirconium Monoxide from Neon Matrix Investigations at 4° K

1965 • 13 citations

A computer controlled microwave spectrometer system

1974 • 13 citations

Dust Particles and Molecules in the Extended Atmospheres of Carbon Stars

1973 • 11 citations

Reply to Comment by D. P. Gilra on ’’C2H radical: 13C hyperfine interaction and optical spectrum’’ [J. Chem. Phys. 60, 3817 (1974)]

1975 • 10 citations

A comment on the optical spectrum of C2H

1975 • 8 citations

Oпpeдeлehиe othocиteлъhoгo pacпoлoжehия heкomБиhиpyющиx элeкtpohhъix coctoяhий дbyxatomhъix moлeкyл. Ochobhoe элeкtpohhoe coctoяhиe ZrO

1974 • 7 citations

Microwave Spectroscopy of High Temperature Gases**The opinions expressed in this article are those of the authors and do not necessarily reflect the official position of the National Bureau of Standards.

1971 • 5 citations