Gauche effect. Stereochemical consequences of adjacent electron pairs and polar bonds

Stereochemistry of carbon compounds

1962 • 1,110 citations

The Magnitude of the Primary Kinetic Isotope Effect for Compounds of Hydrogen and Deuterium.

1961 • 740 citations

The Factors Determining Nucleophilic Reactivities

1962 • 677 citations

The electron-pair repulsion model for molecular geometry

1970 • 248 citations

Electronic Structure and Inversion Barrier of Ammonia

1970 • 213 citations

Origin of Rotational Barriers. I. Many-Electron Molecular Orbital Wavefunctions for Ethane, Methyl Alcohol, and Hydrogen Peroxide

1967 • 189 citations

Millimeter-Wave Rotational Spectrum of HSSH and DSSD. I. Q Branches

1968 • 170 citations

Conformational analysis in saturated heterocyclic compounds

1970 • 157 citations

Use of outer d orbitals in bonding

1969 • 153 citations

Energy component analysis of rotational barriers

1968 • 120 citations

A theoretical study of the Edward–Lemieux effect (the anomeric effect). The stereochemical requirements of adjacent electron pairs and polar bonds

1971 • 113 citations

An Electron Diffraction Investigation on the Molecular Structure of Hydrazine

1960 • 109 citations

Rotational isomerism. Part VII. Effect of substituents on vicinal coupling constants in XCH₂·CH₂Y fragments

1969 • 102 citations

The Mass and Microwave Spectra, Structures, and Dipole Moments of the Isomers of Sulfur Monofluoride

1964 • 100 citations

Internal Motions of Hydrazine

1963 • 93 citations

884. The microwave spectrum, structure, and dipole moment of dioxygen difluoride

1962 • 92 citations

The Cyclononatetraenyl Anion

1963 • 90 citations

Internal Rotation Barriers for Hydrazine and Hydroxylamine from Ab Initio LCAO—MO—SCF Wavefunctions

1967 • 90 citations

Olefin Alkylation in Biosynthesis

1968 • 74 citations

Langsame Inversion am pyramidal gebundenen Stickstoff: Isolierung und Epimerisierung diastereomerer N‐Methoxy‐3,3‐di‐methoxycarbonyl‐5‐cyan‐1, 2‐oxazolidine. Vorläufige Mitteilung

1969 • 71 citations

Stereochemistry of aminophosphines

1970 • 67 citations

Fluorophosphine Ligands. III. Syntheses Involving PF₂I. The Preparation and Characterization of μ-Oxo-bisdifluorophosphine, Cyanodifluorophosphine, and Tetrafluorodiphosphine¹

1966 • 66 citations

Conformational Isomerism in 1-Substituted Derivatives of 3,3-Dimethylbutane

1967 • 60 citations

Structure of an .alpha.-sulfonyl carbanion

1969 • 56 citations

Rotational isomerism. Part VIII. A calculation of the rotational barriers and rotamer energies of some halogenated compounds

1970 • 56 citations

3d-orbital resonance in divalent sulphides—IV

1964 • 55 citations

Distortional effects on the internal rotation in hydrogen peroxyde

1969 • 48 citations

The Infrared Spectrum of Biphosphine

1956 • 48 citations

A quantum mechanical study of proton exchange in sulfoxides with retention and inversion of configuration

1969 • 47 citations

Untersuchungen über Phosphorverbindungen. VIII. Das R<scp>AMAN</scp>‐Spektrum des Diphosphins

1957 • 46 citations

Studies in the Structure of Organic Peroxides.

1963 • 44 citations

Microwave Spectrum and Barrier to Internal Rotation in Methylsilylacetylene

1965 • 43 citations

Olefin-Forming Elimination Reactions

1969 • 42 citations

Vibrational Spectra and Structure of Dimethyl Diselenide and Dimethyl Diselenide-d6

1968 • 39 citations

The preparation and racemization of an optically active sulfonium ylide. (-)-Ethylmethylsulfonium phenacylide

1968 • 39 citations

Structures moléculaires de quelques composés aromatiques sulfurés

1945 • 36 citations

Studies in Magnetic Nonequivalence. A Model for Conformational Analysis of Acyclics from Spin-Coupling Constants

1966 • 36 citations

Barrier to internal rotation in hydrogen persulphide

1970 • 36 citations

Langsame Inversion am pyramidal gebundenen Stickstoff: Kristallstrukturanalyse destrans-N-Methoxy-3, 3-di-methoxycarbonyl-5-cyan-1, 2-oxazolidins

1969 • 35 citations

Microwave Spectrum, Internal Barrier, Molecular Structure, and Dipole Moment of Disilanyl Fluoride

1966 • 35 citations

SECTION OF CHEMICAL SCIENCES: NITROGEN INVERSION IN AZIRIDINES*

1969 • 32 citations

Steric Effects in Elimination Reactions. VII. The Effect of the Steric Requirements of Alkoxide Bases on the Direction of Bimolecular Elimination

1956 • 31 citations

Assignments of configuration by nuclear Overhauser effects in some dibenzthiepin derivatives

1970 • 30 citations

91. Absorption spectra and structure of organic sulphur compounds. Part II. Disulphides and polysulphides

1949 • 29 citations

The Crystal Structure of Hydrogen Peroxide Dihydrate.

1960 • 29 citations

Fatty peroxides: Synthesis, analysis, and reactions

1962 • 27 citations

Ab initio calculation of the barrier to internal rotation in propylene using a Guassian basis self-consistent field wave function

1969 • 27 citations

Stereochemistry and transannular reactions of 7,12-dihydropleiadenes

1969 • 26 citations

Kinetic isotope effects as guides to transition-state structures in deprotonation reactions

1971 • 26 citations

Barriers to rotation and nitrogen inversion in hydrazines

1970 • 25 citations

Stereochemical consequences of adjacent electron pairs. Theoretical study of rotation-inversion in ethylene dicarbanion

1972 • 25 citations

The Electric Moments of Some Aliphatic Peroxides, Disulfides and Diselenides

1952 • 25 citations

Ab Initio versus CNDO barrier calculations

1971 • 23 citations

Methylenebis(dialkylsulfonium) Salts

1966 • 23 citations

The Electric Moments of Crganic Peroxides. II. Aliphatic Peracids¹

1958 • 21 citations

Conformation of non-aromatic ring compounds. Part 41. Dipole moments and NMR spectra of 1,1,2-trihalogeno-cyclo-hexanes and -cyclopentanes

1967 • 21 citations

Structure and stereochemical behavior of asymmetric .alpha.-sulfonyl carbanions

1970 • 21 citations

Nitrogen inversion barriers and electronic structure of fluoramine and cyanamide: ab initio SCF–LCAO–MO study

1970 • 20 citations

Orbital symmetry control in the rearrangements of allylic sulphonium ylides

1969 • 16 citations

Stereochemistry of base-catalyzed .beta.-elimination from 2-bromobutane

1971 • 16 citations

Three types of base-initiated .beta.-elimination reactions involving carbanion intermediates

1970 • 15 citations

Base‐Catalysed H‐D Exchange in 1 ‐Methylthiolanium Iodide

1971 • 15 citations

On stabilization of pyramidal carbanionic centres by an adjacent sulphur 3d-orbital

1970 • 14 citations

.alpha.,.alpha.-Dichloroazoalkanes. II. Mechanism of stereospecific synthesis and substitution

1970 • 13 citations

Preferential Formation of the cis Olefin in an E2 Elimination

1965 • 12 citations

Conformation of 2,3-dicyano-2,3-dimethylbutane by electric dipole moment and Kerr effect measurements

1969 • 10 citations

Hofmann elimination. I. An example of a cis E2 mechanism

1967 • 9 citations

Barriers to nitrogen inversion in acyclic chloramines

1971 • 9 citations

Zur reaktivität diastereotoper substituenten am konformativ starren tetraphenyltribenzocycloheptatrien-system

1970 • 6 citations

Dipole moments and conformation of sulphinic acid esters

1970 • 6 citations

elimination in 2-phenylethyl derivatives

1971 • 3 citations

Reaction of 2-butyl halides with sodium ethoxide and 2,2,2-trifluoroethoxide. Evidence that orientation is not determined by the steric requirements of alkoxide bases.

1970 • 3 citations