Metal Atom Synthesis of Organometallic Compounds

Preparation and identification of intermediate carbonyls of nickel and tantalum by matrix isolation

1971 • 198 citations

The “Nickel Effect”

1973 • 192 citations

Low Temperature Condensation of High Temperature Species as a Synthetic Method

1972 • 134 citations

Binary transition metal dinitrogen complexes. I. Matrix infrared and Raman spectra, structure and bonding of Ni(N2)n and Pd(N2)m(n = 1-4 and m = 1-3)

1973 • 129 citations

Binary carbonyls of platinum, Pt(CO)n (where n = 1-4). Comparative study of the chemical and physical properties of M(CO)n (where M = nickel, palladium, or platinum; n = 1-4)

1973 • 124 citations

Binary copper carbonyls. Synthesis and characterization of tricarbonylcopper, dicarbonylcopper, monocarbonylcopper, and hexacarbonyldicopper

1975 • 123 citations

Stable Carbon Isotope Ratios within Carbonate Concretions: a Clue to Place and Time of Formation

1972 • 119 citations

Organic chemistry of metal vapors

1975 • 116 citations

Photochemistry of the group VI hexacarbonyls in low temperature matrices. Part I. The pentacarbonyls of chromium, molybdenum, and tungsten

1971 • 113 citations

Chemistry and the carbon arc

1973 • 113 citations

The formation of complexes from transition-metal vapours

1969 • 101 citations

Organometallic derivatives of the transition elements. I. Carbon-13 nuclear magnetic resonance studies of bis(arene)chromium(0) compounds

1976 • 99 citations

Chemical synthesis using metal atoms. Matrix infrared, Raman, ultraviolet-visible, and electron spin resonance studies of the binary carbonyls of cobalt, Co(CO)n (where n = 1-4), and the distortion problem in tetracarbonylcobalt

1975 • 96 citations

Phosphine chemistry of iron(0) and -(II)

1975 • 93 citations

Synthetic Reactions of Metal Atoms at Temperatures of 10 to 273°K

1975 • 90 citations

Solvated nickel atoms and their free cluster formation in organic media

1976 • 81 citations

Reactions of Transition Metal Atoms with Organic Substrates

1975 • 80 citations

Chromium atoms in organometallic synthesis

1973 • 79 citations

Reactions of iron atoms with unsaturated hydrocarbons

1972 • 77 citations

Synthesis of bis-π-benzene-titanium and -molybdenum using metal vapours

1973 • 75 citations

Peraparation of an extremely active magnesium slurry for Grignard reagent preparations by metal atom-solvent cocondensations

1974 • 73 citations

Synthesis using transition metal diatomic molecules. Dirhodium octacarbonyl and diiridium octacarbonyl

1974 • 69 citations

Syntheses of palladium(0) and platinum(0) olefin complexes; molecular structures of [Pt(C2F4)(C2H4)2] and tris(bicyclo[2.2.1]heptene)platinum

1975 • 69 citations

Modeling catalytic reactions with transition metal atoms. 1. Synthesis and characterization of reactive intermediates in the nickel-ethylene system, (C2H4)nNi (where n = 1, 2, or 3) in low temperature matrices

1976 • 68 citations

Infrared Spectrum, Structure, and Bonding of Lithium Nitroxide, LiON

1966 • 67 citations

Reactions of tungsten and molybdenum atoms with 1,3-butadiene. Tris (butadiene)tungsten and -molybdenum

1974 • 67 citations

Bis(2,6-dimethylpyridine)chromium. A .pi.-heterocyclic complex

1976 • 66 citations

Intermediate Binary Carbonyls of Palladium Pd(CO)_n where n = 1–3; Preparation, Identification, and Diffusion Kinetics by Matrix Isolation Infrared Spectroscopy

1972 • 64 citations

Photochemistry of the Group 6 hexacarbonyls in low-temperature matrixes. V. Two routes to square pyramidal matrix isolated chromium pentacarbonyl

1975 • 64 citations

Chemistry of transition-metal vapours. Part III. Formation of complexes with arenes, trifluorophosphine, and nitric oxide

1973 • 63 citations

Preparation of zerovalent di(η-arene)titanium compounds using titanium vapour

1975 • 63 citations

Infrared spectroscopic evidence for palladium tetracarbonyl

1972 • 62 citations

Bis(1,4-cyclohexadiyl)-1,2-dioxetane and bis(1,4-cyclohexadiyl)oxirane from photooxidation of 7,7'-binorbornylidene

1974 • 61 citations

Matrix isolation laser Raman spectroscopy: a Raman and infrared spectral study including Raman polarisation data for the co-condensation reaction of Pd

1972 • 60 citations

Crystal and molecular structure of tris(dibenzylideneacetone)dipalladium(0)

1974 • 59 citations

Di(cyclooctatetraene)titanium and Tri(cyclooctatetraene)dititanium

1966 • 57 citations

Reactions of monatomic and diatomic manganese with carbon monoxide. Matrix infrared spectroscopic evidence for pentacarbonylmanganese Mn(CO)5 and the binuclear carbonyls Mn2(CO)n (where n = 1 or 2)

1975 • 56 citations

Metal atom reactions with fluorocarbons. VI. Complexes of halogenated benzenes with vanadium(0) and chromium(0). Effects of strongly electron-withdrawing substituents, particularly trifluoromethyl groups

1975 • 54 citations

Reactions of Metal Atoms with Fluorocarbons

1975 • 53 citations

Synthesis employing oxidative insertion of palladium atoms into aryl, alkyl, and acyl carbon-halogen bonds. Properties of and phosphine trapping of the nonligand stabilizer RPdX and PCOPdX intermediates

1974 • 53 citations

Metal atom reactions with fluorocarbons. I. Nonsolvated fluoroorganic zinc compounds

1972 • 51 citations

Synthesis of Uranium Carbonyls Using Matrix Isolation

1971 • 51 citations

Transition Metal Atoms in the Synthesis of Binuclear Complexes

1975 • 51 citations

π‐Allylhydridonickel Compounds

1970 • 50 citations

Transition metal atom inorganic synthesis in matrixes

1973 • 50 citations

Die Kristallstruktur vonbis-Cyclooctadien-(1,5)-Nickel(0)

1965 • 49 citations

Spectral Evidence for Lanthanoid and Actinoid Carbonyl Compounds

1975 • 48 citations

Reactions of ground-state magnesium atoms

1972 • 47 citations

Reactivity of co-ordinated ligands. Part XX. Preparation and reactions of cyclo-octadiene complexes of iron, ruthenium, and osmium

1974 • 47 citations

Transition metal vapors in chemical synthesis. The direct preparation of dibenzene chromium as an undergraduate experiment

1972 • 45 citations

Direct synthesis with vanadium atoms. 1. Synthesis of hexacarbonylvanadium and dodecacarbonyldivanadium

1976 • 44 citations

Metal atom reactions with fluorocarbons. IV. Nickel(0) and other transition metal zero-valent complexes with hexafluorobenzene and benzene

1974 • 42 citations

Synthesis and ¹⁹F Nuclear Magnetic Resonance Spectra of Fluorosubstituted Bis(arene)chromium Complexes

1974 • 41 citations

Reaction of metal atoms with solutions; preparation of bis(cyclo-octa-1,5-diene)iron(0)

1974 • 41 citations

The Laser‐Evaporation of Metals and Its Application to Organometallic Synthesis

1975 • 41 citations

Chemistry of transition-metal vapours. Part I. Reactions with trifluorophosphine and related compounds

1970 • 41 citations

Reactions of molybdenum and tungsten atoms. Syntheses of bisarene sandwich compounds

1974 • 41 citations

Chemical Syntheses with Metal Atoms: Preparation of Bis(butadiene)iron Complexes and Butadienetetracarbonlychromium

1972 • 41 citations

Crystal and molecular structure of a novel asymmetrical neodymium-cyclooctatetraene compound, cyclooctatetraenylbis(tetrahydrofuran)neodymium(III) bis(cyclooctatetraenyl)neodymate(III)

1976 • 41 citations

Preparation of di-.pi.-cyclooctatetraene complexes of uranium, thorium, and plutonium by direct reaction of the metals with cyclooctatetraene

1973 • 40 citations

Synthesis and infrared spectroscopic detection of rhenium pentacarbonyl

1974 • 40 citations

Trigonal bipyramidal chromium pentacarbonyl and its implications to structure and bonding considerations of pentacarbonyls and pentacarbonyl anions

1974 • 38 citations

Catalytic oligomerisation of butadiene using catalysts derived directly from metal atoms or di(η-arene)titanium compounds

1975 • 38 citations

Synthesis with tungsten and molybdenum atoms. Reactions with cyclopentadiene and cycloheptatriene

1975 • 37 citations

Übergansmetall‐π‐Komplexe mit siebengliedrigen cyclischen Liganden

1972 • 36 citations

Direct synthesis using gold atoms: synthesis, infrared and ultraviolet-visible spectra and molecular orbital investigations of monoethylene gold(0), (C2H4Au

1976 • 36 citations

Reaction of lithium atoms at 800 °C with chlorocarbons; a new route to polylithium compounds

1972 • 35 citations

Chemistry of atomic silicon. III. Reactions of electron bombardment produced silicon vapor with silanes

1972 • 34 citations

Binary Mixed Dinitrogen–Carbonyl Complexes of Nickel(0), Ni(N₂)_m(CO)_4−m (where m = 1–3)

1973 • 33 citations

Synthesis of bis(triethylphosphine)organonickel and organopalladium complexes employing nickel and palladium atoms as synthetic reagents

1974 • 32 citations

Platinum. Noble metal, "base" atoms

1971 • 32 citations

Stereochemistry of bis(1,4-difluorobenzene)vanadium(0)

1976 • 31 citations

Metal atom reactions with fluorocarbons III. Insertion of palladium atoms into aryl carbonhalogen bonds

1973 • 31 citations

Reactions of nickel atoms with unsaturated hydrocarbons

1972 • 31 citations

ChemInform Abstract: PREPARATION OF DI-PI-CYCLOOCTATETRAENE COMPLEXES OF URANIUM, THORIUM AND PLUTONIUM BY DIRECT REACTION OF THE METALS WITH CYCLOOCTATETRAENE

1973 • 31 citations

Übergangsmetall-π-Komplexe mit ungesättigten und aromatischen Heterocyclen, IV π-Komplexe methylsubstituierter Pyridinderivate mit Chrom(0).

1976 • 31 citations

Atomic silicon. Reaction with trimethylsilane

1967 • 30 citations

The preparation of palladium–olefin complexes from palladium vapour

1975 • 30 citations

Aluminum atom-ethylene molecular complex. Matrix isolation electron spin resonance study

1975 • 29 citations

Reaction of bis(cyclo-octa-1,5-diene)iron with trimethyl phosphite, phosphorus trifluoride, t-butyl isocyanide, carbon monoxide, and bis-1,2-(diphenylphosphino)ethane; the synthesis of [Fe(N2)(diphos)2]

1976 • 29 citations

Metal atom reactions with fluorocarbons viii. Silver vapor with -alkyl iodides with formation of -alkylsilver compounds

1976 • 28 citations

Reactions of free aluminum atoms. Direct syntheses of organoaluminum compounds

1972 • 28 citations

Reaction of carbon vapor with lithium atoms. Direct synthesis of polylithium compounds

1973 • 27 citations

Oligomerisationskatalysatoren - I Bis-cyclooctatetraen-eisen: Eine neue, katalytisch aktive, organische eisen-verbindung

1967 • 27 citations

Infrared spectroscopic evidence for aluminium dicarbonyl

1972 • 27 citations

Reactions of transition-metal vapours with cycloheptatriene and cyclo-octatetraene

1976 • 27 citations

Metal atom reactions with fluorocarbons. II. Defluorination by calcium atoms1, 2

1972 • 27 citations

Infrared spectroscopic evidence for copper and silver carbonyls

1971 • 26 citations

1,1′-Tetramethylethyleneferrocene : a direct synthesis from fulvenes and iron vapour

1975 • 26 citations

Preparation of (η5-C5H5)2MH2 (M = Mo, W) by metal vaporation techniques

1974 • 25 citations

Reactions of organosulphur compounds with metal atoms

1976 • 25 citations

Infrared spectroscopic evidence for germanium and tin carbonyls

1972 • 24 citations

アルミニウム‐エチレン分子錯体。マトリックス分離電子スピン共鳴による研究

1975 • 23 citations

Chemical synthesis with metal atoms: the reaction of chromium and nickel atoms with styrene

1976 • 23 citations

Chemical syntheses with metal atoms

1976 • 23 citations

Silver atom-ethylene molecular complex. Matrix isolation electron spin resonance study

1975 • 23 citations

Cycloheptatrienylcycloheptadienyltitanium

1971 • 22 citations

Metal atom evaporation synthesis and intramolecular exchange: (1,3-COD)FeL3 complexes from 1,5-COD

1976 • 22 citations

Boron-fluorine chemistry. III. Silicon-boron fluorides

1969 • 21 citations

Cryogenic Inorganic Chemistry: A Review of Metal‐Gas Reactions as Studied by Matrix‐Isolation Infrared and Raman Spectroscopic Techniques

1975 • 21 citations

Tricarbonyl-(penta- and 2,4,6-tri-methylpyridine)chromium(0)-True Pyridine π-Complexes

1975 • 21 citations

Synthesis of benzylpalladium chloride employing palladium atoms

1975 • 20 citations

Direct synthesis and characterization of dibenzenechromium(O) in an argon matrix at 14°K

1974 • 20 citations

Transition metal atoms as catalysts: oligomerisation of butadiene using atoms of Ti, V, Cr, Mn, Fe, Co, or Ni

1974 • 17 citations

The preparation of π-allyl nickel halides from nickel vapour

1972 • 16 citations

Vapour synthesis of polylithium compounds: the effect of halogens in activating the carbon–hydrogen bond

1975 • 16 citations

Cycloheptatrienyl-chrom(-I)-cycloheptadien-(1,3)

1968 • 15 citations

Mass spectroscopic detection of Ni(CS)4

1973 • 14 citations

Germanium atoms in synthesis

1975 • 14 citations

Synthesis and some reactions of π-cyclo-octatrienyl-π-cyclo-octatetraenecobalt

1971 • 13 citations

PF2 Bridges in Metal Complexes

1967 • 13 citations

Synthesis and ready metallation of (η-benzene)-(η-pentafluorobenzene)chromium

1976 • 10 citations

Chemical synthesis with metal atoms: preparation and X-ray structure of (η⁵-cycloheptadienyl)-(η⁵-cycloheptatrienyl) iron. A bifluxional molecule

1976 • 10 citations

Komplexchemie mit nackten Metallatomen

1976 • 9 citations

A low-temperature source for the generation of uranium vapor

1976 • 9 citations

The reaction of germanium atoms with trimethylsilane

1975 • 5 citations

Chemische Synthesen mit Metallionen

1973 • 4 citations