Chiral Methyl Groups

Methods of Enzymatic Analysis

1974 • 6,512 citations

Stereochemistry of carbon compounds

1962 • 1,110 citations

Applications of the Sequence Rule. I. Naming the Paired Ligands g,g at a Tetrahedral Atom Xggij. II. Naming the Two Faces of a Trigonal Atom Yghi

1966 • 367 citations

[137] Preparation and assay of acyl coenzyme A and other thiol esters; use of hydroxylamine

1957 • 354 citations

Applications of biochemical systems in organic chemistry

1976 • 243 citations

Synthese von S‐β‐Oxybutyryl‐ und S‐Acetacetyl‐Coenzym A

1953 • 208 citations

Substrate Stereochemistry in Squalene Biosynthesis

1966 • 170 citations

Asymmetric Methyl Groups: Preparation and Detection of Chiral Methyl Groups

1969 • 165 citations

Interpretations of enzyme reaction stereospecificity

1975 • 160 citations

[97] Acetate kinase of bacteria (acetokinase)

1955 • 160 citations

[39] Preparation and assay of acetyl phosphate

1957 • 144 citations

Asymmetric Methyl Groups: Asymmetric Methyl Groups, and the Mechanism of Malate Synthase

1969 • 133 citations

Molecular asymmetry in biology

1969 • 129 citations

Mechanisms of Enzyme Action

1966 • 117 citations

Stereochemistry of the 3-Deoxy-d-arabino-heptulosonate 7-Phosphate Synthetase Reaction and the Chorismate Synthetase Reaction

1972 • 113 citations

Oxydations par le carbonate d'argent sur celite—XIII

1975 • 112 citations

Stereochemistry of tris(triphenylphosphine)rhodium chloride decarbonylation of aldehydes

1971 • 104 citations

Stereochemical Aspects of Pyridoxal Phosphate Catalysis

1971 • 101 citations

Synthesis and Configurational Assay of Asymmetric Methyl Groups

1970 • 94 citations

Kinetic studies on catechol O-methyltransferase, Product inhibition and the nature of the catechol binding site

1973 • 92 citations

Stereochemistry of Pyruvate Kinase, Pyruvate Carboxylase, and Malate Enzyme Reactions

1970 • 90 citations

Stereochemical Evidence for the Evolution of Pyridoxal-phosphate Enzymes of Various Function from a Common Ancestor

1974 • 86 citations

2 Pyridoxal-Linked Elimination and Replacement Reactions

1972 • 80 citations

The Proton Transfer Reactions of Muscle Pyruvate Kinase

1972 • 77 citations

Synthesis of Glutamate and Citrate by Clostridium kluyveri. A New Type of Citrate Synthase^*

1966 • 74 citations

Stereochemistry of the dTDP-glucose oxidoreductase reaction.

1977 • 72 citations

Studies in the metabolism of the strict anaerobes (genus Clostridium)

1935 • 71 citations

Catechol O-methyltransferase. 1. Kinetics of tropolone inhibition

1973 • 70 citations

Nuclear magnetic resonance assignment of the vinyl hydrogens of phosphoenolpyruvate. Stereochemistry of the enolase reaction

1970 • 68 citations

Stereochemistry and mechanism of reactions catalyzed by tryptophanase Escherichia coli

1978 • 64 citations

Bestimmung der Isotopenverteilung in markierten Verbindungen

1967 • 64 citations

Biosynthesis of the antibiotic granaticin

1979 • 62 citations

A direct, selective, and general method for reductive deamination of primary amines

1978 • 61 citations

Partial Purification and Some Properties of Oxalacetase from Aspergillus niger

1976 • 59 citations

[86] Malate synthetase from baker's yeast

1962 • 58 citations

Determination by Neutron and X-Ray Diffraction of the Absolute Configuration of an Enzymatically Formed α-Monodeuterioglycolate¹

1965 • 58 citations

Stereochemistry of Enzymic Citrate Synthesis and Cleavage

1970 • 58 citations

Stereochemistry and its application in biochemistry

1972 • 57 citations

Chiral [16O, 17O, 18O]phosphate monoesters. 1. Asymmetric synthesis and stereochemical analysis of [1(R)-16O, 17O, 18O]phospho-(S)-propane-1,2-diol

1978 • 53 citations

SN2-like transition for methyl transfer catalyzed by catechol-O-methyltransferase

1976 • 53 citations

Stereochemistry of si‐Citrate Synthase and ATP‐Citrate‐Lyase Reactions

1971 • 53 citations

THE STEREOCHEMISTRY OF THE SUCCINIC DEHYDROGENASE REACTION¹

1960 • 53 citations

Kinetics of purified catechol

1970 • 51 citations

Stereochemistry and mechanism of reactions catalyzed by tryptophan synthetase and its beta2 subunit

1978 • 49 citations

The Biosynthesis of Long-Chain Fatty Acids. Stereochemical Differentiation in the Enzymic Incorporation of Chiral Acetates

1977 • 48 citations

The Biosynthesis of Long-Chain Fatty Acids. Incorporation of Radioactivity from Stereospecifically Tritiated Malonyl Thiol Esters, and the Stereochemistry of the Acetyl-CoA Carboxylase Reaction

1977 • 47 citations

Robert Robinson Lecture. The logic of working with enzymes

1973 • 41 citations

Stereochemistry of the oxidation at the α carbon of butyryl‐CoA and of the enzymic hydrogen exchange

1970 • 41 citations

The Enzymatic Carboxylation of Propionyl Coenzyme A

1968 • 41 citations

Stereospecific synthesis of isotopically labeled serine at carbon 3 and stereochemical analysis of D-serine dehydrase reaction

1976 • 40 citations

Fate of Chiral Acetates in the Citric Acid Cycle

1970 • 40 citations

Biological Mechanisms Involved in the Formation of Deoxy Sugars: Enzymatic Hydrogen Mediation

1973 • 40 citations

Enzyme Reaction Stereospecificity: A Critical Revie

1972 • 39 citations

Studies on the mechanism and stereochemical properties of the oxalacetate decarboxylase activity of pyruvate kinase.

1976 • 39 citations

Stereochemistry of the 1,3-proton loss from a chiral methyl group in the biosynthesis of cycloartenol as determined by tritium nuclear magnetic resonance spectroscopy

1978 • 37 citations

Stereochemistry of methylene transfer involving 5,10-methylenetetrahydrofolate

1977 • 35 citations

Concepts and Perspectives in Enzyme Stereochemistry

1976 • 35 citations

Stereochemical Course of the Isocitrate Lyase Reaction

1964 • 35 citations

Stereochemistry of propionyl-coenzyme A and pyruvate carboxylations catalyzed by transcarboxylase

1975 • 35 citations

Mechanism of the enzymatic cleavage of the 9β,19-cyclopropane ring of cycloeucalenol

1977 • 34 citations

Stereochemical Studies of the Exchange and Abstraction of Succinate Hydrogen on Succinate Dehydrogenase

1970 • 33 citations

Stereochemistry of the formation of cysteine by O-acetylserine sulfhydrase.

1976 • 33 citations

The Stereochemistry of the Reaction Catalyzed by Ethanolamine AmmoniaLyase, an Adenosylcobalamindependent Enzyme

1974 • 32 citations

Stereochemistry and mechanism of reactions catalyzed by tryptophanase and tryptophan synthetase

1976 • 32 citations

Enzymic Generation of Chiral Acetates. A Quantitative Evaluation of Their Configurational Assay

1976 • 30 citations

Substrate Stereochemistry of the Hydroxymethylglutaryl-CoA Lyase and Methylglutaconyl-CoA Hydratase Reactions

1975 • 30 citations

Purification and kinetic properties of aconitate isomerase from Pseudomonas putida

1971 • 30 citations

Stereochemistry of the tryptophan synthetase reaction

1974 • 30 citations

Pedler Lecture. Exploration of enzyme mechanisms by asymmetric labelling

1969 • 27 citations

Stereochemistry of isopentenyl pyrophosphate isomerase

1972 • 26 citations

Stereochemistry of the interconversions of citrate and acetate catalyzed by citrate synthase, adenosine triphosphate citrate lyase, and citrate lyase

1971 • 26 citations

Mechanism of the aconitate isomerase reaction

1971 • 25 citations

Preparative scale synthesis of (1R) [1-2H1] or [1-3H1] primary alcohols of high optical purity

1977 • 24 citations

Stereochemistry of ketonization of enolpyruvate by pyruvate kinase. Evidence for its role as an intermediate

1978 • 23 citations

Identification of 7α-hydroxylated androgens as the metabolites of androstenedione by testicular microsomal fraction of rats

1970 • 22 citations

16 Dehydration in Nucleotide-Linked Deoxysugar Synthesis

1971 • 22 citations

Substrate Stereochemistry of 3‐Hydroxy‐3‐Methylglutaryl‐Coenzyme A Synthase

1974 • 22 citations

Proton transfer reactions of methylglyoxal synthase

1977 • 20 citations

Enzyme Symmetry and Enzyme Stereospecificity

1972 • 19 citations

Formation of enolpyruvate in the phosphoenolpyruvate carboxytransphosphorylase reaction

1973 • 18 citations

The sterochemistry at carbon 3 of pyruvate lyase condensation products. 2-Keto-3-deoxygluconate 6-phosphate and 2-keto-3-deoxygalactonate-6-phosphate aldolase of Pseudomonas saccharophila.

1975 • 18 citations

Substrate Stereochemistry of the Acetyl‐CoA Acetyltransferase Reaction

1975 • 17 citations

Stereochemistry of the β-cyanoalanine synthetase and S-alkylcysteine lyase reactions

1978 • 16 citations

Stereochemistry of the re‐Citrate‐Synthase Reaction

1971 • 15 citations

Stereochemistry of a Methyl-Group Rearrangement during the Biosynthesis of Lanosterol

1976 • 15 citations

The Stereochemistry at Carbon 3 of Pyruvate Lyase Condensation Products

1973 • 15 citations

Stereochemistry of the Citrate‐Lyase Reaction

1971 • 13 citations

Stereochemical Course of Decarboxylation of S‐Malate on Malic Enzyme

1972 • 11 citations

Further Studies on the Biosynthesis of the Antibiotic Indolmycin in Streptomyces griseus

1975 • 11 citations

On the Mechanism and Stereochemistry of the Malate-Lactate Fermentation ofLeuconostoc mesenteroides^[1]

1976 • 10 citations

An apparent lack of stereospecificity in the reaction catalysed by deoxyribose 5-phosphate aldolase due to methyl-group rotation and enolization before product release

1976 • 10 citations

Prochirality in biochemistry.

1973 • 10 citations

The stereochemistry at carbon 3 of pyruvate lyase condensation products. 2-Keto-3-deoxygluconate-6-phosphate aldolase.

1975 • 9 citations

Silver oxide oxidation of an aldehyde with carbon tritium bonds vicinal to the carbonyl carbon

1975 • 5 citations

Stereochemistry of enzyme reactions at prochiral centers

1970 • 3 citations

Substrate Stereochemistry of the Cleavage Reaction in Citramalate Lyase

1975 • 3 citations