Reaction of myoglobin with hydrogen peroxide forms a peroxyl radical which oxidizes substrates.

The measurement and mechanism of lipid peroxidation in biological systems

1990 • 1,273 citations

An optical method for measurement of dioxygen concentration based upon quenching of phosphorescence.

1987 • 592 citations

Peroxy radicals

1969 • 420 citations

The Mechanism of Metmyoglobin Oxidation

1963 • 261 citations

Reactions of the Protein Radical in Peroxide-treated Myoglobin

1989 • 183 citations

The myoglobin protein radical. Coupling of Tyr-103 to Tyr-151 in the H2O2-mediated cross-linking of sperm whale myoglobin.

1988 • 180 citations

Epoxidation of styrene by hemoglobin and myoglobin. Transfer of oxidizing equivalents to the protein surface.

1985 • 175 citations

Identification of a globin free radical in equine myoglobin treated with peroxides

1991 • 149 citations

Paramagnetic Resonance and Optical Absorption Spectra of<mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline"><mml:mrow><mml:msup><mml:mrow><mml:mi mathvariant="normal">Cr</mml:mi></mml:mrow><mml:mrow><mml:mn>3</mml:mn><mml:mo>+</mml:mo></mml:mrow></mml:msup></mml:mrow></mml:math>in MgO

1957 • 148 citations

Electron-nuclear double resonance of horseradish peroxidase compound I. Detection of the porphyrin pi-cation radical.

1981 • 141 citations

Free Radical produced in the Reaction of Metmyoglobin with Hydrogen Peroxide

1958 • 118 citations

Intramolecular translocation of the protein radical formed in the reaction of recombinant sperm whale myoglobin with H2O2.

1992 • 117 citations

The Formation and Structure of the Sulfoxyl Radicals RSO·, RSOO·, RSO₂·, and RSO₂OO· from the Reaction of Cysteine, Glutathione and Penicillamine Thiyl Radicals with Molecular Oxygen

1990 • 116 citations

Detection of Myoglobin-Derived Radicals On Reaction of Metmyoglobin With Hydrogen Peroxide and Other Peroxidic Compounds

1990 • 113 citations

The reactivity of thiols and disulfides with different redox states of myoglobin. Redox and addition reactions and formation of thiyl radical intermediates.

1992 • 107 citations

Myoglobin-catalyzed hydrogen peroxide dependent arachidonic acid peroxidation

1985 • 100 citations

Amino acid free radicals in oxidised metmyoglobin

1967 • 98 citations

Spectral analysis of the protein-derived tyrosyl radicals from prostaglandin H synthase.

1992 • 82 citations

Ferrylmyoglobin-catalyzed linoleic acid peroxidation

1990 • 77 citations

Electron spin resonance spectrum of Tyr-151 free radical formed in reactions of sperm whale metmyoglobin with ethyl hydroperoxide and potassium irridate

1989 • 73 citations

The roles of His-64, Tyr-103, Tyr-146, and Tyr-151 in the epoxidation of styrene and beta-methylstyrene by recombinant sperm whale myoglobin.

1993 • 62 citations

Hormonal regulation of Cl transport in polar airway epithelia measured by a fluorescent indicator

1992 • 41 citations

The Myoglobin-Derived Radical Formed on Reaction of Metmyoglobin with Hydrogen Peroxide is not a Tyrosine Peroxyl Radical

1992 • 37 citations

Least-squares analysis of ESR powder patterns with noncoincident principal axes of the g and hyperfine tensors

1982 • 35 citations

Electron Spin Resonance Spectra of Free Radicals Formed in the Reaction of Metmyoglobins with Ethylhydroperoxide1

1987 • 27 citations

ESR spin-trapping studies of free radicals generated by hydrogen peroxide activation of metmyoglobin

1990 • 21 citations

Reduction of sperm whale ferrylmyoglobin by endogenous reducing agents: Potential reducible loci of ferrylmyoglobin

1992 • 19 citations

Electron spin resonance of ¹⁷ O-labeled protein-peroxide radicals: Zein and edestin

1980 • 9 citations