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The lanthanide ions as structural probes in biological and model systems

Data up to Jan 2025

Published2007
Citations128
References213

Total Citations Per Year

Abstract

References (213)

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Hypersensitive pseudoquadrupole transitions in lanthanides

1964 • 888 citations

Molal volumes of electrolytes

1971 • 872 citations

Spectroscopic Properties of Rare Earths

1965 • 579 citations

Nuclear magnetic resonance shifts in solution due to lanthanide ions

1972 • 565 citations

Paramagnetic shifts in solutions of cholesterol and the dipyridine adduct of trisdipivalomethanatoeuropium(III). A shift reagent

1969 • 560 citations

The Covalent and Three-Dimensional Structure of Concanavalin A

1972 • 533 citations

Polarographic Techniques

1966 • 468 citations

Lanthanide shift reagents for nuclear magnetic resonance spectroscopy

1973 • 442 citations

The Coordination Chemistry of Yttrium and the Rare Earth Metal Ions

1965 • 407 citations

Cellular Pharmacology of Lanthanum

1974 • 398 citations

Electron-transfer and f-d absorption bands of some lanthanide and actinide complexes and the standard (II-III) oxidation potential for each member of the lanthanide and actinide series

1973 • 302 citations

Absorption Spectra of Octahedral Lanthanide Hexahalides

1966 • 301 citations

Electron transfer spectra of lanthanide complexes

1962 • 298 citations

Neutron Diffraction Study of Calcium Hydroxide

1957 • 284 citations

Molecular polyhedra of high co-ordination number

1967 • 266 citations

A High Resolution Structure of an Inhibitor Complex of the Extracellular Nuclease of Staphylococcus aureus

1971 • 264 citations

Complexes of lanthanide (III) ions with nitrogen donor ligands

1973 • 259 citations

Quantitative Determination of Mononucleotide Conformations in Solution using Lanthanide Ion Shift and Broadening NMR Probes

1971 • 253 citations

Study of the nature of the metal-binding sites and estimate of the distance between the metal-binding sites in transferrin using trivalent lanthanide ions as fluorescent probes

1971 • 242 citations

Magnetic Resonance in Biological Systems

1964 • 222 citations

Apparent Molal Volumes of Some Aqueous Rare Earth Chloride and Nitrate Solutions at 25°1

1966 • 210 citations

Magnetic resonance studies of membrane and model membrane systems. VI. Transbilayer asymmetry and surface homogeneity of mixed phospholipids in cosonicated vesicles

1973 • 195 citations

Energy Transfer between Trivalent Rare-Earth Ions in Inorganic Solids

1967 • 185 citations

Lanthanide shift reagents in nuclear magnetic resonance spectroscopy

1973 • 183 citations

Energy Transfer. A System with Relatively Fixed Donor-Acceptor Separation

1965 • 180 citations

Magnetic Resonance Studies of Manganese (II) Binding Sites of Pyruvate Kinase

1970 • 177 citations

Temperature Dependence of Proton Relaxation Times in Aqueous Solutions of Paramagnetic Ions

1959 • 176 citations

The Action of Certain Polyvalent Cations on the Voltage-Clamped Lobster Axon

1968 • 164 citations

Structure of Thermolysin

1972 • 163 citations

Physical Methods in Advanced Inorganic Chemistry

1968 • 162 citations

Coordination of trivalent lanthanide ions

1970 • 161 citations

NMR differentiation of the internal and external phospholipid membrane surfaces using paramagnetic Mn2+ and Eu3+ ions

1971 • 158 citations

On the Structure-Dependent Behavior of Ethylenediaminetetraacetato Complexes of the Rare Earth Ln3+ Ions1

1965 • 157 citations

Complexes of Trivalent Lanthanide and Actinide Ions. I. Outer-Sphere Ion Pairs

1965 • 155 citations

Calcium binding to the sarcoplasmic reticulum of rabbit skeletal muscle

1971 • 154 citations

Origin of lanthanide nuclear magnetic resonance shifts and their uses

1972 • 151 citations

Hypersensitive transitions of hydrated neodymium-(III)holmium-(III) and erbium-(III) ions

1968 • 150 citations

New nuclear magnetic resonance shift reagents

1973 • 149 citations

Structure and Bonding in a Ten-Coordinate Lanthanum(III) Chelate of Ethylenediaminetetraacetic Acid1

1965 • 147 citations

The Crystal and Molecular Structure of DIP-inhibited Bovine Trypsin at 2.7A Resolution

1972 • 147 citations

Lanthanide shift reagents. Survey

1971 • 145 citations

Structure and thermodynamics of lanthanide and actinide complexes in solution

1971 • 138 citations

Crystal structure of the praseodymium β-diketonate of 2,2,6,6-tetramethyl-3,5-heptanedione, Pr2(thd)6

1970 • 132 citations

Nuclear Magnetic Resonance Studies of Solutions of the Rare-Earth Ions and Their Complexes. III. Oxygen-17 and Proton Shifts in Aqueous Solutions and the Nature of Aquo and Mixed Complexes

1969 • 130 citations

The Casparian Strip as a Barrier to the Movement of Lanthanum in Corn Roots

1974 • 127 citations

Structure of the Fe-S Complex in a Bacterial Ferredoxin

1972 • 126 citations

Electron Paramagnetic Resonance Spectra of Manganese(II)-Protein Complexes

1970 • 126 citations

Enhancement of Fluorescence Yield of Rare-Earth Ions by Heavy Water

1963 • 113 citations

Lanthanum Inhibition of 45Ca Efflux from the Squid Giant Axon

1970 • 110 citations

Acetate Complexes of the Rare Earth and Several Transition Metal Ions

1962 • 106 citations

Gadolinium(III) as a paramagnetic probe for proton relaxation studies of biological macromolecules. Binding to bovine serum albumin

1971 • 106 citations

Free-energy Relationships in Coordination Chemistry. III. A Comprehensive Index to Complex Stability

1973 • 103 citations

Nuclear Relaxation Induced by Paramagnetic Ions Having Anisotropic g Factors

1965 • 102 citations

Differential Interaction of Cholesterol with Phosphatidylcholine on the Inner and Outer Surfaces of Lipid Bilayer Vesicles

1974 • 99 citations

The interaction of La3+ with mitochondria in relation to respiration-coupled Ca2+ transport

1971 • 97 citations

Structural Studies on the Rare Earth Carboxylates. 1. The Crystal and Molecular Structure of Na3[M(OCOCH2OCH2OCO)3].2NaClO4.6H2O, M = Nd, Gd, and Yb.

1968 • 96 citations

The crystal structure of calcium thymidylate

1961 • 94 citations

Structure of the ethylenediaminetetracetatoaquomagnesate(II) ion in a crystalline sodium salt. Comparative stereochemistry of the seven-coordinate chelates of magnesium(II), manganese(II), and iron(III)

1973 • 93 citations

Conformations of carp muscle calcium binding parvalbumin

1974 • 93 citations

Quantitative determination of conformations of flexible molecules in solution using lanthanide ions as nuclear magnetic resonance probes: Application to adenosine-5′-monophosphate

1974 • 92 citations

Enhancement of terbium(III) and europium(III) fluorescence in complexes with Escherichia coli tRNA

1974 • 90 citations

Rare Earth Metal Ions as Probes of Calcium Ion Binding Sites in Proteins

1970 • 90 citations

Complexes of Trivalent Lanthanide and Actinide Ions. II. Inner-Sphere Complexes

1965 • 90 citations

Binding of lanthanides and of divalent metal to porcine trypsin

1974 • 88 citations

Lanthanide Complexes as Nuclear Magnetic Resonance Structural Probes: Paramagnetic Anisotropy of Shift Reagent Adducts

1972 • 88 citations

Specificity of metal ion interaction with concanavalin A

1973 • 87 citations

Nuclear relaxation and kinetic studies of the role of Mn2+in the mechanism of enolase

1973 • 85 citations

Rare earth metal ions as probes of electrostatic binding sites in proteins

1970 • 84 citations

Treatise on analytical chemistry

1961 • 84 citations

The Lanthanide Cations as Probes in Biological Systems. Proton Relaxation Enhancement Studies for Model Systems and Lysozyme

1971 • 83 citations

Analysis of Rare Earth Mixtures by Recording Spectrophotometer

1958 • 81 citations

Rare earth metal ions as substitutes for the calcium ion in Bacillus subtilis .alpha.-amylase

1971 • 81 citations

Chemical effects on the isomer shift in 151Eu

1968 • 80 citations

Structural Studies on the Rare Earth Carboxylates. 6. A Reinvestigation of Trisodium-tris(oxydiacetato)lanthanoidate(III) Di(sodium Perchlorate) Hexahydrate.

1970 • 79 citations

Paramagnetic lanthanide shift reagents in NMR spectroscopy: Principles, methodology and applications

1973 • 78 citations

Lanthanide shift reagents. X-ray structure of the eight-coordinate bis(4-picoline) adduct of 2,2,6,6-tetramethylheptane-3,5-dionatoholmium, Ho(dpm)3(4-pic)2

1971 • 77 citations

Lanthanide complexes of amino acids

1974 • 76 citations

Crystal and molecular structure of diaquotris(acetylacetonato)lanthanum(III)

1968 • 75 citations

Hydration thermodynamics of the lanthanide ions

1969 • 74 citations

Lanthanum inhibits Ca inward current but not Na-Ca exchange in cardiac muscle

1973 • 74 citations

Absorption and Fluorescence of Europium(III) in Aqueous Solutions

1964 • 72 citations

Ultrasonic absorption in aqueous salts of the lanthanides

1969 • 72 citations

Crystal and molecular structure of trinitratobis(bipyridyl)lanthanum(III)

1972 • 72 citations

Note on the Distinction between Transverse and Longitudinal Electron Relaxation Times Obtained from Nuclear Relaxation Studies

1970 • 70 citations

Structural Studies on the Rare Earth Carboxylates. 10. The Crystal and Molecular Structure of Monoclinic Trisodium Tris(pyridine-2,6-dicarboxylato)ytterbate(III) 13-Hydrate.

1972 • 70 citations

Assignment of aromatic amino acid PMR resonances of horse ferricytochrome c

1975 • 67 citations

Calcium and the Control of Contraction and Relaxation in a Molluscan Catch Muscle

1973 • 66 citations

Magnetic resonance studies of enzymesubstrate complexes with paramagnetic probes as illustrated by creatine kinase

1970 • 64 citations

Fluorescence of nucleic acid — Terbium(III) complexes

1973 • 63 citations

The lanthanide cations as nuclear magnetic resonance probes of biological systems

1970 • 61 citations

Lanthanide shift reagents. Model which accounts for the apparent axial symmetry of shift reagent adducts in solution

1974 • 61 citations

Electron spin relaxation in aqueous solutions of gadolinium(III). Aquo, cacodylate, and bovine serum albumin complexes

1971 • 61 citations

Cation requirements of isoleucyl-tRNA synthetase from Escherichiacoli

1972 • 59 citations

Technique of inorganic chemistry

1963 • 59 citations

Quantitative determination of the conformation of cyclic 3′,5′-adenosine monophosphate in solution using lanthanide ions as nuclear magnetic resonance probes

1974 • 59 citations

The classification of acceptors and donors in inorganic reactions

2008 • 58 citations

31 P Nuclear Magnetic Resonance Spectroscopy of Native and Recombined Lipoproteins

1974 • 57 citations

Lanthanide ions activate α-amylase

1973 • 57 citations

Effects of paramagnetic lanthanide shift reagents on the proton magnetic resonance spectra of quinoline and pyridine

1972 • 57 citations

Rare earths as isomorphous calcium replacements for protein crystallography

1972 • 57 citations

Fluorescence Quantum Efficiency of Rare-Earth Chelates*

1964 • 55 citations

Some Aspects of the Structure of Staphylococcal Nuclease: PART I. CRYSTALLOGRAPHIC STUDIES

1972 • 54 citations

Complexes of Trivalent Lanthanide Ions. III. Bidentate Chelates

1966 • 53 citations

Weak or unstable iodo complexes. I. Hexaiodo complexes of the lanthanides

1969 • 51 citations

Treatise on analytical chemistry, part II, vol. 14

1971 • 50 citations

The Interaction of the Lanthanide Ions with Staphylococcal Nuclease

1973 • 49 citations

Optical activity of terbium ions bound to transferrin and conalbumin studied by circular polarization of luminescence

1974 • 48 citations

Isomer shifts of 151Eu in divalent europium compounds

1969 • 48 citations

The crystal structure of tris-(2,2′,6′,2″-terpyridyl)europium(<scp>III</scp>) perchlorate

1969 • 48 citations

Aequorin: Its ionic specificity

1972 • 48 citations

Synthesis and structure of the six-coordinate hexaisothiocyanatolanthanide(III) complexes

1968 • 48 citations

High-resolution visible spectroscopy of two europium (III) ethylenediaminetetra-acetates differing in one molecule of ligated water

1971 • 47 citations

Observations on the rare earths. LXXXII. Nuclear magnetic resonance and calorimetric studies of complexes of the tripositive ions with substituted pyridine molecules

1969 • 46 citations

Lanthanide and actinide complexes of glycine. Determination of stability constants and thermodynamic parameters by a solvent extraction method

1968 • 46 citations

The crystal and molecular structure of the hydrated praseodymium chelate of 1,1,1,2,2,3,3-heptafluoro-7,7-dimethyl-4,6-octanedione, Pr2(fod)6.2H2O

1971 • 46 citations

The lanthanides as spectroscopic and magnetic resonance probes in biological systems

1975 • 44 citations

Entropy and Volume Changes on Ionization of Aqueous Acids

1965 • 43 citations

The inner mechanism of rare earths elucidated by photo-electron spectra

1973 • 43 citations

Nuclear magnetic resonance study of the interaction of neodymium(III) with amino acids and carboxylic acids. Aqueous shift reagent

1973 • 43 citations

Separation of contact and pseudo-contact contributions to shifts induced by lanthanide(III) ions in nuclear magnetic resonance spectra

1973 • 43 citations

Calcium carrier and the “high affinity calcium binding site” in mitochondria

1969 • 42 citations

Enzyme action: views derived from metalloenzyme studies.

1968 • 41 citations

The Mechanism of Water‐Proton Relaxation in Enzyme · Paramagnetic‐Ion Complexes

1974 • 41 citations

Crystal and molecular structure of tris (2,2,6,6-tetramethyl-3,5-heptanedionato) aquodysprosium(III), Dy(thd)3H2O

1971 • 41 citations

The formation kinetics of some lanthanide oxalate complexes

1968 • 39 citations

Third ionization potentials and sublimation energies of the lanthanides

1969 • 39 citations

The crystal structure of CaCl2.glycylglycylglycine.3H2O

1969 • 38 citations

Structural investigations of calcium binding molecules. III. Calcium-oxydiacetic acid system. Crystal and molecular structures of calcium oxydiacetate hexahydrate and Raman spectroscopic comparison with species in aqueous solution

1973 • 37 citations

Koordinationszahl und nephelauxetischer Effekt von Komplexen der Lanthaniden

1969 • 37 citations

Proton relaxation enhancement probes

1972 • 37 citations

Stereochemistry of decacoordination. The molecular structure of bis(bipyridyl)lanthanum nitrate

1968 • 36 citations

Europium ions as probes for excited molecules in aqueous solution

1971 • 36 citations

Nuclear magnetic resonance shift reagents

1973 • 36 citations

Binding of Calcium, Yttrium and Thorium to a Glycoprotein form Bovine Cortical Bone

1966 • 35 citations

Abortive complexes of α-amylases with lanthanides

1973 • 35 citations

Mössbauer effect studies of transferrin

1973 • 35 citations

739. Stability constants and spectra of some lanthanide complexes

1964 • 34 citations

Crystal and molecular structure of 3-methylpyridinetris(2,2,6,6-tetramethyl-3,5-heptanedionato)lutetium(III)

1973 • 34 citations

Inhibition of yeast phosphoglycerate kinase by lanthanide—ATP complexes

1974 • 33 citations

Kinetic investigation of lanthanide(III) complexation. II. Deuterium isotope effects and activation parameters for the lanthanide(III)-anthranilate reaction

1969 • 33 citations

Les hypovanadates MV3O7 (M = Ca, Sr, Cd). Structure cristalline de CaV3O7

1973 • 32 citations

The crystal structure of monocalcium phosphate monohydrate, Ca(H2PO4)2.H2O

1956 • 32 citations

Normal coordinate treatment of lanthanide hexahalide anions (lnx3-6)

1974 • 31 citations

Approximate calculations of the heats and entropies of hydration according to various models

1972 • 31 citations

Changes in the register of members

1970 • 30 citations

Absorption and circular dichroic spectral studies of europium(III) complexes with sugar acids and amino acids, with remarks on hypersensitivity

1969 • 30 citations

Thermodynamic Properties of Rare Earth Complexes. I. Stability Constants for the Rare Earth Diglycolate Complexes.

1963 • 30 citations

Relations between softness, covalent bonding, ionicity and electric polarizability

2008 • 28 citations

Crystal and molecular structure of a nuclear magnetic resonance shift reagent, the dipyridine adduct of tris-[(2,2,6,6-tetramethylheptane-3,5-dionato)europium(III), Eu(dpm)3(py)2]

1972 • 28 citations

Ethylenediaminetetra-acetato-lanthanate(<scp>III</scp>), -praesodimate(<scp>III</scp>), -europate(<scp>III</scp>), and -gadolinate(<scp>III</scp>) complexes as nuclear magnetic resonance probes of the molecular conformations of adenosine 5′- monophosphate and cytidine 5′-monophosphate in solution

1974 • 28 citations

A specific spectrofluorimetric determination of terbium as its EDTA-sulphosalicylic acid complex

1967 • 28 citations

Interaction of lanthanide and nitrate ions in solutions. I. Inner- and outer-sphere coordination in aqueous solutions

1967 • 28 citations

Komplexone VL. Reaktionsenthalpie und ‐entropie bei der Bildung der 1 : 1‐Komplexe der Seltenen Erdionen mit 1,3‐Diaminopropan‐N, N, N′, N′‐tetraacetat

1971 • 28 citations

A fluorescent terbium chelate system in water solution

1966 • 26 citations

Lanthanide Ion-Induced Isotropic Shifts and Broadening for Nuclear Magnetic Resonance Structural Analysis of Model Membranes

1973 • 26 citations

Electromechanical uncoupling of frog skeletal muscle by possible change in sarcoplasmic reticulum content

1973 • 25 citations

Calcium binding to carbohydrates: crystal structure of a hydrated calcium bromide salt of lactobionic acid

1973 • 24 citations

Ca(H2PO4)2, a crystal structure containing unusual hydrogen bonding

1973 • 24 citations

250-MHz Proton magnetic resonance spectrum of a sonicated lecithin dispersion in water: The effect of ferricyanide, manganese (II), europium (III), and gadolinium (III) ions on the choline methyl resonance

1972 • 24 citations

Study of the thermal decomposition of europium(III) oxalate using the Moessbauer effect

1970 • 23 citations

The application of ultrasound absorption to reaction kinetics

1973 • 23 citations

Organic chemistry, series one

1974 • 22 citations

Structural Studies on the Rare Earth Carboxylates. 8. The Crystal and Molecular Structure of Monoclinic Tris(hydroxyacetato)europium(III), Eu(HOCH2COO)3.

1971 • 21 citations

The space group of calcium peroxide oxtahydrate

1951 • 20 citations

Structural Studies on the Rare Earth Carboxylates. 14. A Structural Study of the Orthorhombic Trishydroxyacetates of Lanthanum(III) and Gadolinium(III).

1972 • 20 citations

Calcium ion binding to uncharged sugars: crystal structures of calcium bromide complexes of lactose, galactose, and inositol

1972 • 20 citations

The Active Site of Staphylococcal Nuclease: Paramagnetic Relaxation of Bound Nucleotide Inhibitor Nuclei by Lanthanide Ions

1974 • 20 citations

Conformational studies of lanthanide complexes with carboxylate ligands

1974 • 19 citations

The crystal structure of calcium nitrilotriacetate dihydrate

1972 • 19 citations

A Nuclear Magnetic Resonance Study of Histidine-Neodymium (III) Complexes

1972 • 18 citations

Thermodynamic Properties of Rare Earth Complexes. XVII. The Partial Molar Heat Capacities of Rare Earth Perchlorates and Oxydiacetate Complexes.

1973 • 17 citations

INTERACTIONS OF NUCLEOPHILES WITH LANTHANIDE SHIFT REAGENTS

1973 • 17 citations

Thermodynamic considerations in co-ordination. Part VIII. A calorimetric and potentiometric study of complex formation between some lanthanide(III) ions and histidine

1970 • 16 citations

HYPERSENSITIVITY IN COMPLEXES OF Nd(III) AND Ho(III) WITH MONOBASIC LIGANDS

1974 • 16 citations

Energy Transfer between p-Benzoylbenzoate and Europium Ethylenediaminetetraacetate in Water Solution

1966 • 15 citations

Thermodynamic Properties of Rare Earth Complexes. XI. Stability Constants and Free Energy Changes for the Formation of Rare Earth Diglycolate Complexes at 5, 20, 35, and 50 degrees C.

1972 • 14 citations

THE STRUCTURE OF A CHOLESTEROL: SHIFT REAGENT COMPLEX IN SOLUTION

1973 • 13 citations

Free-energy relationships in coordination chemistry. II. Requirements for linear relationships

1970 • 13 citations

THE THERMODYNAMICS OF LANTHANIDE COMPLEXING BY ACETYLACETONATE

1972 • 13 citations

Structural Studies on the Rare Earth Carboxylates. 3. The Crystal and Molecular Structure of Tris-hydroxyacetato-gadolinium(III), Gd(HOCH2COO)3.

1969 • 13 citations

MAGNETIC ANISOTROPY AND DIPOLAR SHIFTS IN SHIFT REAGENT SYSTEMS

1973 • 13 citations

Oscillator strengths of f-f transitions in hexachloroneodymium(III) anion

1974 • 12 citations

Solvent and temperature effects on fluorescence emission of europium β-diketonates

1966 • 12 citations

Nuclear magnetic resonance study of the solvation of europium(III) ions in water-acetonitrile mixtures

1972 • 12 citations

The Active Site of Phosphoglycerate Kinase Studied by Nuclear Magnetic Resonance

1974 • 11 citations

Note on the Distinction between Transverse and Longitudinal Relaxation Times Obtained from Nuclear Relaxation Studies

1972 • 10 citations

Possible sequentia analysis of small oligopeptides (penta to hepta) with proton nuclear magnetic resonance spectroscopy at 300 MHz

1973 • 9 citations

On the Standard Potential of the Europium(II,III) Couple.

1969 • 9 citations

Thermodynamic Properties of Rare Earth Complexes. XV. Enthalpy and Heat Capacity Changes for the Formation of Rare Earth EDTA Complexes from MgEDTA2- at 10, 20, 30 and 40 degrees C.

1973 • 9 citations

Yeast inorganic pyrophosphatase v. binding of Eu3+

1972 • 8 citations

Faraday effect spectra of Nd(III) complexes

1974 • 8 citations

Proton magnetic resonance spectroscopic studies using paramagnetics of primary and tertiary structure of proteins

1974 • 8 citations

Studies of Oxygen Exchange Between Trivalent Lanthanide – EDTA Complexes and Solvent Water: Evidence for a Structural Change Within the Series

1973 • 7 citations

Controlled-Potential Coulometric Determination of Europium

1959 • 7 citations

Thermodynamic Properties of Rare Earth Complexes. XVI. Thermodynamic Model for the Description of Hydration Equilibria among Rare Earth EDTA and Oxydiacetate Complexes.

1973 • 5 citations

Proton chemical shifts in aqueous solutions of the rare-earth ions as an indicator of complex formations

1967 • 5 citations

Determination of Europium(II) and Total Europium in Europium-Activated Lithium Iodide Scintillation Crystals.

1964 • 1 citations

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